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RESEARCH PAPER · Structure and bonding · 2014

MOFs of Uranium and the Actinides

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MOFs of Uranium and the ActinidesOriginalSolvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates21Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39Synthesis, structures, and photoluminescent properties of two uranium complexes constructed by a flexible zwitterion ligand18From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)46Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Tetrahydrofurantetracarboxylic Acid: An Isomerizable Framework-Forming Ligand in Homo- and Heterometallic Complexes with UO22+, Ag+, and Pb2+23Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates15Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93The crystalline α,ω-dicarboxylate metal complex with the longest aliphatic chain to date: uranyl 1,15-pentadecanedioate10Coordination Polymers and Cage-Containing Frameworks in Uranyl Ion Complexes with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylates: Consequences of Chirality38Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes34AgI and PbII as Additional Assembling Cations in Uranyl Coordination Polymers and Frameworks44Tetrahedral and Cuboidal Clusters in Complexes of Uranyl and Alkali or Alkaline-Earth Metal Ions with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylate29Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Porous Uranium Diphosphonate Frameworks with Trinuclear Units Templated by Organic Ammonium Hydrolyzed from Amine Solvents23Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Mg, Ca and Ba glutaratouranylates – Synthesis and structure9Uranyl Ion Complexes with Chiral Malic and Citramalic, and Prochiral Citric and Tricarballylic Acids: Influence of Coligands and Additional Metal Cations19Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Uranyl–Organic Coordination Polymers with trans-1,2-, trans-1,4-, and cis-1,4-Cyclohexanedicarboxylates: Effects of Bulky PPh4+ and PPh3Me+ Counterions26Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis-1,3-, cis-1,2-, and trans-1,2-Cyclohexanedicarboxylates34Stepwise ortho Chlorination of Carboxyl Groups for Promoting Structure Variance of Heterometallic Uranyl–Silver Coordination Polymers of Isonicotinate29Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties48Counterion-Controlled Formation of an Octanuclear Uranyl Cage with cis-1,2-Cyclohexanedicarboxylate Ligands31Closed Uranyl–Dicarboxylate Oligomers: A Tetranuclear Metallatricycle with Uranyl Bridgeheads and 1,3-Adamantanediacetate Linkers22[Ni(cyclam)]2+ and [Ni(R,S-Me6cyclam)]2+ as Linkers or Counterions In Uranyl–Organic Species with cis- and trans-1,2-Cyclohexanedicarboxylate Ligands38Three Different Modes of Association between Metal Cations in Heterometallic Uranyl–CoIII and Uranyl–MnII Species7Chiral Discrete and Polymeric Uranyl Ion Complexes with (1R,3S)-(+)-Camphorate Ligands: Counterion-Dependent Formation of a Hexanuclear Cage26Structure-Directing Effects of Counterions in Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates: 1D to Polycatenated 3D Species31In situ nitroso formation induced structural diversity of uranyl coordination polymers21The sulfonate group as a ligand: a fine balance between hydrogen bonding and metal ion coordination in uranyl ion complexes29Novel Heterometallic Uranyl-Transition Metal Materials: Structure, Topology, and Solid State Photoluminescence Properties45Tubelike Uranyl–Phenylenediacetate Assemblies from Screening of Ligand Isomers and Structure-Directing Counterions28Favoring Framework Formation through Structure-Directing Effects in Uranyl Ion Complexes with 1,2,3,4-(Cyclo)butanetetracarboxylate Ligands9The effect of organic cations on the structure of uranyl glutarate complexes1Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”971,2-, 1,3-, and 1,4-Phenylenediacetate Complexes of the Uranyl Ion with Additional Metal Cations and/or Ancillary N-Donor Ligands: Confronting Ligand Geometrical Proclivities161,3‐Adamantanedicarboxylate and 1,3‐Adamantanediacetate as Uranyl Ion Linkers: Effect of Counterions, Solvents and Differences in Flexibility11Graphdiyne-actinyl complexes as potential catalytic materials: A DFT perspective from their structural, bonding, electronic and redox properties6Two uranium coordination polymers constructed by a polycarboxylic acid: Structural variation, photoluminescent and photocatalysis properties18Uranyl Ion-Containing Polymeric Assemblies with cis/trans Isomers of 1,2-, 1,3-, and 1,4-Cyclohexanedicarboxylates, Including a Helical Chain and a 6-Fold-Interpenetrated Framework19Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential U VI chelation11Formation of uranyl phthalate coordination polymers with unusual 2D net topologies in the presence of organic cations16Structure-Directing Effects of Coordinating Solvents, Ammonium and Phosphonium Counterions in Uranyl Ion Complexes with 1,2-, 1,3-, and 1,4-Phenylenediacetates25A Redox-Innocent Uranium(IV)-Quinoid Metal-Organic Framework8Functionalized Aromatic Dicarboxylate Ligands in Uranyl–Organic Assemblies: The Cases of Carboxycinnamate and 1,2-/1,3-Phenylenedioxydiacetate26Uranyl Ion Complexes of Polycarboxylates: Steps towards Isolated Photoactive Cavities15Uranyl Tricarballylate Triperiodic and Nanotubular Species. Counterion Control of Nanotube Diameter13Counterion-Controlled Formation of Layered Honeycomb and Polythreading Uranyl Networks and the Highly Sensitive and Selective Detection of Fe3+ in Aqueous Media14Metal-organic frameworks as a versatile platform for radionuclide management163Isomerism in Benzenetricarboxylates: Variations in the Formation of Coordination Polymers with Uranyl Ion12Optimizing Photoluminescence Quantum Yields in Uranyl Dicarboxylate Complexes: Further Investigations of 2,5‐, 2,6‐ and 3,5‐Pyridinedicarboxylates and 2,3‐Pyrazinedicarboxylate13Auxiliary Ligand-Dependent Adaptive Regulation of Uranyl Coordination in Mixed-Ligand Uranyl Compounds of Flexible Biphenyltetracarboxylic Acid16Isoreticular 2D uranyl coordination polymers based on the mixed oxalate-succinate linkers2A chiral uranyl-Kemp's tricarboxylate cubic framework: structure-directing effect of counterions with three-fold rotational symmetry1Uranyl ion complexes with 2,2′:6′,2′′-terpyridine-4′-carboxylate. Interpenetration of networks involving “expanded ligands”10Cavity Formation in Uranyl Ion Complexes with Kemp’s Tricarboxylate: Grooved Diperiodic Nets and Polynuclear Cages14Contrasting Structure-Directing Effects in the Uranyl–Phthalate/Isophthalate Isomer Systems19Stepwise Introduction of Flexibility into Aromatic Dicarboxylates Forming Uranyl Ion Coordination Polymers: a Comparison of 2‐Carboxyphenylacetate and 1,2‐Phenylenediacetate112,5-Thiophenedicarboxylate: An Interpenetration-Inducing Ligand in Uranyl Chemistry15Chain, Network and Framework Formation in Uranyl Ion Complexes with 1,1′‐Biphenyl‐3,3′,4,4′‐Tetracarboxylate1Metal-organic frameworks as superior porous adsorbents for radionuclide sequestration: Current status and perspectives52Uranyl Ion Coordination by Benzene‐1,2,3‐tricarboxylate: Building Chains and Networks from Binuclear Bricks1Varied role of organic carboxylate dizwitterions and anionic donors in mixed-ligand uranyl ion coordination polymers14Contrasting Networks and Entanglements in Uranyl Ion Complexes with Adipic and trans,trans-Muconic Acids7Multiple aspects of chirality in coordination polymers formed by the uranyl ion with (1R,3S)-(+)-camphorate ligands1Varying Structure‐Directing Anions in Uranyl Ion Complexes with Ni(2,2′ : 6′,2′′‐terpyridine‐4′‐carboxylate)212Reticular chemistry of uranyl phosphonates: synthesis, design, and beyond10Energy–structure–property relationships in uranium metal–organic frameworks32Ligand competition on uranyl ion: further examples of zwitterionic vs. anionic carboxylate coordination9Nanotubule inclusion in the channels formed by a six-fold interpenetrated, triperiodic framework7Triple-armed aliphatic tricarboxylic acids as sources of ligands for uranyl ion: influence of bridgehead functionalization4Flexible Aliphatic Diammonioacetates as Zwitterionic Ligands in UO22+ Complexes: Diverse Topologies and Interpenetrated Structures15Unveiling Structural Diversity of Uranyl Compounds of Aprotic 4,4′-Bipyridine N,N′-Dioxide Bearing O-Donors8New Barium Fluorosuccinato and Fluoroglutarato Uranylates2New Barium Fluorosuccinato and Fluoroglutarato Uranylates2New Uranyl Succinate-Containing Polymers: Synthesis and Structure0New Uranyl Succinate-Containing Polymers: Synthesis and Structure0Ultrastarke Elektron‐Phonon‐Kopplung in Uran‐organischen Gerüstverbindungen führt zu einer inversen Temperaturabhängigkeit der Lumineszenz0Ultrastrong Electron‐Phonon Coupling in Uranium‐Organic Frameworks Leading to Inverse Luminescence Temperature Dependence13Uranyl ion coordination polymers with the dibenzobarrelene-based rac - and ( R , R )- trans -9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands41,1ʹ-Dimethyl-4,4ʹ-bipyridinium as a multivalent structure-directing counterion to anionic uranyl ion polycarboxylate complexes9Bifunctional ligands in uranyl chemistry: Metalloligands and zwitterions26Perrhenate anion encapsulation in a uranyl ion–zwitterionic dicarboxylate coordination polymer4High photoluminescence quantum yield of a uranyl ion complex with the hemi-zwitterion 1,3-bis(carboxylatomethyl)-1H-benzimidazol-3-ium2Uranyl‐Nickel(II) Cation‐Cation Interaction in a Triperiodic Framework with cis‐1,2‐Cyclohexanedicarboxylate and Isonicotinate Ligands1

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  1. Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate

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  2. Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates

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  3. Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies

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  4. Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

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  5. Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks

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  6. Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres

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  7. Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate

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  8. Synthesis, structures, and photoluminescent properties of two uranium complexes constructed by a flexible zwitterion ligand

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  9. From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates

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  10. Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions

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  11. Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes

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  12. Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)

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  13. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

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  14. Tetrahydrofurantetracarboxylic Acid: An Isomerizable Framework-Forming Ligand in Homo- and Heterometallic Complexes with UO22+, Ag+, and Pb2+

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  15. Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates

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  16. Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

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  17. The crystalline α,ω-dicarboxylate metal complex with the longest aliphatic chain to date: uranyl 1,15-pentadecanedioate

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  18. Coordination Polymers and Cage-Containing Frameworks in Uranyl Ion Complexes with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylates: Consequences of Chirality

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  19. Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes

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  20. AgI and PbII as Additional Assembling Cations in Uranyl Coordination Polymers and Frameworks

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  21. Tetrahedral and Cuboidal Clusters in Complexes of Uranyl and Alkali or Alkaline-Earth Metal Ions with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylate

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  22. Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex

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  23. Porous Uranium Diphosphonate Frameworks with Trinuclear Units Templated by Organic Ammonium Hydrolyzed from Amine Solvents

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  24. Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets

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  25. Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions

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  26. Mg, Ca and Ba glutaratouranylates – Synthesis and structure

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  27. Uranyl Ion Complexes with Chiral Malic and Citramalic, and Prochiral Citric and Tricarballylic Acids: Influence of Coligands and Additional Metal Cations

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  28. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

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  29. Uranyl–Organic Coordination Polymers with trans-1,2-, trans-1,4-, and cis-1,4-Cyclohexanedicarboxylates: Effects of Bulky PPh4+ and PPh3Me+ Counterions

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  30. Crown Ethers and Their Alkali Metal Ion Complexes as Assembler Groups in Uranyl–Organic Coordination Polymers with cis-1,3-, cis-1,2-, and trans-1,2-Cyclohexanedicarboxylates

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  31. Stepwise ortho Chlorination of Carboxyl Groups for Promoting Structure Variance of Heterometallic Uranyl–Silver Coordination Polymers of Isonicotinate

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  32. Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties

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  33. Counterion-Controlled Formation of an Octanuclear Uranyl Cage with cis-1,2-Cyclohexanedicarboxylate Ligands

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  34. Closed Uranyl–Dicarboxylate Oligomers: A Tetranuclear Metallatricycle with Uranyl Bridgeheads and 1,3-Adamantanediacetate Linkers

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  35. [Ni(cyclam)]2+ and [Ni(R,S-Me6cyclam)]2+ as Linkers or Counterions In Uranyl–Organic Species with cis- and trans-1,2-Cyclohexanedicarboxylate Ligands

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  36. Three Different Modes of Association between Metal Cations in Heterometallic Uranyl–CoIII and Uranyl–MnII Species

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  37. Chiral Discrete and Polymeric Uranyl Ion Complexes with (1R,3S)-(+)-Camphorate Ligands: Counterion-Dependent Formation of a Hexanuclear Cage

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  38. Structure-Directing Effects of Counterions in Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates: 1D to Polycatenated 3D Species

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  39. In situ nitroso formation induced structural diversity of uranyl coordination polymers

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  40. The sulfonate group as a ligand: a fine balance between hydrogen bonding and metal ion coordination in uranyl ion complexes

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  41. Novel Heterometallic Uranyl-Transition Metal Materials: Structure, Topology, and Solid State Photoluminescence Properties

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  42. Tubelike Uranyl–Phenylenediacetate Assemblies from Screening of Ligand Isomers and Structure-Directing Counterions

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  43. Favoring Framework Formation through Structure-Directing Effects in Uranyl Ion Complexes with 1,2,3,4-(Cyclo)butanetetracarboxylate Ligands

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  44. The effect of organic cations on the structure of uranyl glutarate complexes

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  45. Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”

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  46. 1,2-, 1,3-, and 1,4-Phenylenediacetate Complexes of the Uranyl Ion with Additional Metal Cations and/or Ancillary N-Donor Ligands: Confronting Ligand Geometrical Proclivities

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  47. 1,3‐Adamantanedicarboxylate and 1,3‐Adamantanediacetate as Uranyl Ion Linkers: Effect of Counterions, Solvents and Differences in Flexibility

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  48. Graphdiyne-actinyl complexes as potential catalytic materials: A DFT perspective from their structural, bonding, electronic and redox properties

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  49. Two uranium coordination polymers constructed by a polycarboxylic acid: Structural variation, photoluminescent and photocatalysis properties

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  50. Uranyl Ion-Containing Polymeric Assemblies with cis/trans Isomers of 1,2-, 1,3-, and 1,4-Cyclohexanedicarboxylates, Including a Helical Chain and a 6-Fold-Interpenetrated Framework

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