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RESEARCH PAPER · Inorganic Chemistry · 2007

High-Nuclearity Ce/Mn and Th/Mn Cluster Chemistry: Preparation of Complexes with [Ce4Mn10O10(OMe)6]18+ and [Th6Mn10O22(OH)2]18+ Cores

Abhudaya Mishra, Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Khalil A. Abboud, George Christou

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High-Nuclearity Ce/Mn and Th/Mn Cluster Chemistry: Preparation of Complexes with [Ce4Mn10O10(OMe)6]18+ and [Th6Mn10O22(OH)2]18+ CoresOriginal“Switching On” the Properties of Single-Molecule Magnetism in Triangular Manganese(III) Complexes220A Mixed‐valent Heterometallic [Mn4Co4] Complex from Reductive Rearrangement of a [Mn4] Single‐Molecule Magnet4Mixed Transition Metal−Lanthanide Complexes at High Oxidation States: Heteronuclear Ce IV Mn IV Clusters60Dual Shell-like Magnetic Clusters Containing Ni II and Ln III (Ln = La, Pr, and Nd) Ions84Single-Molecule Magnets: A Family of MnIII/CeIV Complexes with a [Mn8CeO8]12+ Core64Exchange Coupling and Energy-Level Crossing in a Magnetic Chain [Dy2Cu2]n Evaluated by High-Frequency Electron Paramagnetic Resonance77High-Spin Mn4 and Mn10 Molecules: Large Spin Changes with Structure in Mixed-Valence MnII4MnIII6 Clusters with Azide and Alkoxide-Based Ligands88Large Mn25 Single-Molecule Magnet with Spin S = 51/2: Magnetic and High-Frequency Electron Paramagnetic Resonance Spectroscopic Characterization of a Giant Spin State68High Nuclearity Single-Molecule Magnets: a Mixed-Valence Mn26 Cluster Containing the Di-2-pyridylketone Diolate Dianion64Synthesis, Magnetism, and High-Frequency EPR Spectroscopy of a Family of Mixed-Valent Cuboctahedral Mn13 Complexes with 1,8-Naphthalenedicarboxylate Ligands23Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII2MnIII6 complexes41Structures of cerium manganese pivalates9Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N═CH−C6H3-2-OH-3-OMe]3]: A 3d−4f Family of Single-Molecule Magnets186Heterotetranuclear Oxalato-Bridged Re IV 3 M II (M = Mn, Fe, Co, Ni, Cu) Complexes: A New Example of a Single-Molecule Magnet (M = Ni)61Tridecanuclear [MnIII5LnIII8] Complexes Derived from N-tButyl-diethanolamine: Synthesis, Structures, and Magnetic Properties75Substitution reactions of thorium(IV) acetate to synthesize nano-sized carboxylate complexes14Spin Maximization from S = 11 to S = 16 in Mn7 Disk-Like Clusters: Spin Frustration Effects and Their Computational Rationalization48Homo‐ and Heterovalent Polynuclear Cerium and Cerium/Manganese Aggregates85Cerium(IV)−Lanthanide(III)−Pyridine-2,6-dicarboxylic Acid System: Coordination Salts, Chains, and Rings59Mn7 and Mn12 Clusters From Use of 2-(Pyridine-2-yl)propan-2-ol: A New Half-Integer Single-Molecule Magnet50Structural motifs and topological representation of Mn coordination clusters261Structure and magnetic properties of a decanuclear MnII2MnIII2Dy6 aggregate26The use of phosphonates for constructing 3d–4f clusters at high oxidation states: synthesis and characterization of two unusual heterometallic CeMn complexes63Experimental Evidence for Magnetic Exchange in Di- and Trinuclear Uranium(IV) Ethynylbenzene Complexes74The first pentanuclear heterobimetallic coordination cation with CeIII, CeIV and MnII45Inducing Single-Molecule Magnetism in a Family of Loop-of-Loops Aggregates: Heterometallic Mn40Na4 Clusters and the Homometallic Mn44 Analogue124Combining Azide, Carboxylate, and 2-Pyridyloximate Ligands in Transition-Metal Chemistry: Ferromagnetic NiII5 Clusters with a Bowtie Skeleton80A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet behaviour198Synthesis, structure and properties of a heterometallic 4f-5d complex [Sm(Hinic)3(H2O)2]n·(1.5nHgCl4)·(2nH2O)2A new dodecanuclear manganese single-molecule magnet from the arrangement of manganese triangles9Heterobimetallic hexanuclear [Mn ΙΙΙ 4 Ln ΙΙΙ 2 ] clusters: A rare Mn ΙΙΙ 4 Nd ΙΙΙ 2 example exhibiting slow relaxation of magnetization56Using the flexible ligand bis(2-hydroxyethyl)amino–tris (hydroxymethyl)methane (“bis–tris”) to access a family of 3d–4f MnIII4Ln4 complexes18Periodic Trends in Hexanuclear Actinide Clusters42X-ray Magnetic Circular Dichroism (XMCD) Study of a Methoxide-Bridged DyIII–CrIII Cluster Obtained by Fluoride Abstraction from cis-[CrIIIF2(phen)2]+26Heterometallic FeIII–CeIV complexes from the use of aliphatic aminoalcohol ligands13Mn/Ce clusters from the use of pivalate and chelate ligands: MnIII8CeIV, MnIII2CeIV2, and MnIII4CeIII2 products22Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges344{Ce10Mn8}: Cerium Analogues of the Decavanadate Archetype16Magnetic anisotropy and exchange coupling in a family of isostructural FeIII2LnIII2 complexes57Dinuclear and heptanuclear nickel(II) complexes: Anion coordination induced ligand arm hydrolysis and aggregation around a nickel(II) core20Rare nuclearities, new structural motifs, and slow magnetization relaxation phenomena in manganese cluster chemistry: A Mn15Na2 cage from the use of triethanolamine/pivalate/azide “blend”5Tris-dipicolinate Cerium Complexes Bearing Dications of Arginine, Histidine, and Ornithine4A family of novel Mn 3 Ln 4 clusters displaying single-molecule magnet behavior16The multiple core–shell structure in Cu24Ln6 cluster with magnetocaloric effect and slow magnetization relaxation47Tuning the magnetic behaviors in [Fe III 12 Ln III 4 ] clusters with aromatic carboxylate ligands41Tetranuclear Lanthanide(III) Complexes with a Zigzag Topology from the Use of Pyridine-2,6-dimethanol: Synthetic, Structural, Spectroscopic, Magnetic and Photoluminescence Studies51Manganese/Cerium Clusters Spanning a Range of Oxidation Levels and CeMn8, Ce2Mn4, and Ce6Mn4Nuclearities: Structural, Magnetic, and EPR Properties25Hybrid Uranium–Transition-Metal Oxide Cage Clusters28Playing with different metalloligands [NiL] and Hg to [NiL] ratios to tune the nuclearity of Ni(II)–Hg(II) complexes: Formation of di-, tri-, hexa- and nona-nuclear Ni–Hg clusters25Nitronyl nitroxide based 2p–3d–4f chains with the magnetocaloric effect and slow magnetic relaxation26High nuclearity cerium–manganese clusters and their structural and magnetic properties: CeIV3MnIII7 and CeIV5MnIII1111New Structural Types of Mn16 Single-Molecule Magnets: W-Shaped Topology from Reductive Aggregation13Oxo Clusters of 5f Elements24Topological Aspects of 3d/4f Polynuclear Coordination Clusters0Cation Substitution Effect on a Molecular Analogue of Perovskite Manganites5Single-molecule magnetism within a family of [LnIII2MnIII10] complexes from 2-hydroxymethylpyridine4Oxidation of Alcohols to Carbonyl Compounds Catalyzed by Oxo-Bridged Dinuclear Cerium Complexes with Pentadentate Schiff-Base Ligands under a Dioxygen Atmosphere51Family of [Ln4Mn8] (Ln = Gd, Tb, Dy, Ho) and Y4Mn8 single-molecule magnets from the use of 2-(pyridine-2-yl)propan-2-ol2Synthesis and Characterization of Alkoxide-Bridged Heterometallic Clusters of Cerium and Copper8Aggregation of a Giant Bean-like {Mn26Dy6} Heterometallic Oxo-Hydroxo-Carboxylate Nanosized Cluster from a Hexanuclear {Mn6} Precursor20Multinuclear nickel(II) complexes with chiral schiff base ligand4Long-Range Ferromagnetic Exchange Interactions Mediated by Mn–CeIV–Mn Superexchange Involving Empty 4f Orbitals17Unusual Mn5 cluster with a ‘twisted bow-tie’ topology and MnIIMnIII2MnIV2 oxidation states: Synthesis, structure, and magnetic properties5Rare nuclearities in Mn/oxo cluster chemistry: Synthesis and characterization of a mixed-valence {MnII/III11} complex bearing acetate and salicylhydroximate(-3) bridging/chelating ligands3Metallo‐Ligand Based 3d/4f Coordination Polymers: Synthesis, Structure and Magnetic Properties4MnII/III and CeIII/IV Units Supported on an Octahedral Molecular Nanoparticle of CeO24Thermodynamic Assessment of Sacrificial Oxidant Potential, H2O/O2 Potential, and Rate–Overpotential Relationship to Examine Catalytic Water Oxidation in Nonaqueous Solvents1Nickel Ion Induced Multistage Assembly of Th13 Cluster4Aluminate-mediated assembly of Keggin-type thorium-oxo clusters with a substitutable central octahedron and tunable shell ligands0Complexes to clusters: manganese and iron-based catalysts as sustainable torch bearers in homogeneous water oxidation2

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  1. “Switching On” the Properties of Single-Molecule Magnetism in Triangular Manganese(III) Complexes

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  2. A Mixed‐valent Heterometallic [Mn4Co4] Complex from Reductive Rearrangement of a [Mn4] Single‐Molecule Magnet

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  3. Mixed Transition Metal−Lanthanide Complexes at High Oxidation States: Heteronuclear Ce IV Mn IV Clusters

    Inorganic Chemistry · 2007-10-12

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  4. Dual Shell-like Magnetic Clusters Containing Ni II and Ln III (Ln = La, Pr, and Nd) Ions

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  5. Single-Molecule Magnets: A Family of MnIII/CeIV Complexes with a [Mn8CeO8]12+ Core

    Inorganic Chemistry · 2008-04-15

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  6. Exchange Coupling and Energy-Level Crossing in a Magnetic Chain [Dy2Cu2]n Evaluated by High-Frequency Electron Paramagnetic Resonance

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  7. High-Spin Mn4 and Mn10 Molecules: Large Spin Changes with Structure in Mixed-Valence MnII4MnIII6 Clusters with Azide and Alkoxide-Based Ligands

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  8. Large Mn25 Single-Molecule Magnet with Spin S = 51/2: Magnetic and High-Frequency Electron Paramagnetic Resonance Spectroscopic Characterization of a Giant Spin State

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  9. High Nuclearity Single-Molecule Magnets: a Mixed-Valence Mn26 Cluster Containing the Di-2-pyridylketone Diolate Dianion

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  10. Synthesis, Magnetism, and High-Frequency EPR Spectroscopy of a Family of Mixed-Valent Cuboctahedral Mn13 Complexes with 1,8-Naphthalenedicarboxylate Ligands

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    Christos Lampropoulos, Changhyun Koo, Stephen Hill, Khalil A. Abboud, George Christou

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  11. Employment of methyl 2-pyridyl ketone oxime in manganese non-carboxylate chemistry: MnII2MnIV and MnII2MnIII6 complexes

    Dalton Transactions · 2009-01-01

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  12. Structures of cerium manganese pivalates

    Russian Chemical Bulletin · 2009-01-01

    Г.В. Романенко, Elena Yu. Fursova, В.И. Овчаренко

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  13. Synthesis, Structure, and Magnetism of Heterobimetallic Trinuclear Complexes {[L2Co2Ln][X]} [Ln = Eu, X = Cl; Ln = Tb, Dy, Ho, X = NO3; LH3 = (S)P[N(Me)N═CH−C6H3-2-OH-3-OMe]3]: A 3d−4f Family of Single-Molecule Magnets

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    Vadapalli Chandrasekhar, Balasubramanian Murugesa Pandian, Jagadese J. Vittal, Rodolphe Clérac

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  14. Heterotetranuclear Oxalato-Bridged Re IV 3 M II (M = Mn, Fe, Co, Ni, Cu) Complexes: A New Example of a Single-Molecule Magnet (M = Ni)

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  15. Tridecanuclear [MnIII5LnIII8] Complexes Derived from N-tButyl-diethanolamine: Synthesis, Structures, and Magnetic Properties

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  16. Substitution reactions of thorium(IV) acetate to synthesize nano-sized carboxylate complexes

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  17. Spin Maximization from S = 11 to S = 16 in Mn7 Disk-Like Clusters: Spin Frustration Effects and Their Computational Rationalization

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  18. Homo‐ and Heterovalent Polynuclear Cerium and Cerium/Manganese Aggregates

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  19. Cerium(IV)−Lanthanide(III)−Pyridine-2,6-dicarboxylic Acid System: Coordination Salts, Chains, and Rings

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  20. Mn7 and Mn12 Clusters From Use of 2-(Pyridine-2-yl)propan-2-ol: A New Half-Integer Single-Molecule Magnet

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  21. Structural motifs and topological representation of Mn coordination clusters

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  22. Structure and magnetic properties of a decanuclear MnII2MnIII2Dy6 aggregate

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  23. The use of phosphonates for constructing 3d–4f clusters at high oxidation states: synthesis and characterization of two unusual heterometallic CeMn complexes

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  24. Experimental Evidence for Magnetic Exchange in Di- and Trinuclear Uranium(IV) Ethynylbenzene Complexes

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  25. The first pentanuclear heterobimetallic coordination cation with CeIII, CeIV and MnII

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  27. Combining Azide, Carboxylate, and 2-Pyridyloximate Ligands in Transition-Metal Chemistry: Ferromagnetic NiII5 Clusters with a Bowtie Skeleton

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  28. A dodecanuclear heterometallic dysprosium–cobalt wheel exhibiting single-molecule magnet behaviour

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  29. Synthesis, structure and properties of a heterometallic 4f-5d complex [Sm(Hinic)3(H2O)2]n·(1.5nHgCl4)·(2nH2O)

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  30. A new dodecanuclear manganese single-molecule magnet from the arrangement of manganese triangles

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  31. Heterobimetallic hexanuclear [Mn ΙΙΙ 4 Ln ΙΙΙ 2 ] clusters: A rare Mn ΙΙΙ 4 Nd ΙΙΙ 2 example exhibiting slow relaxation of magnetization

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  32. Using the flexible ligand bis(2-hydroxyethyl)amino–tris (hydroxymethyl)methane (“bis–tris”) to access a family of 3d–4f MnIII4Ln4 complexes

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  33. Periodic Trends in Hexanuclear Actinide Clusters

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  34. X-ray Magnetic Circular Dichroism (XMCD) Study of a Methoxide-Bridged DyIII–CrIII Cluster Obtained by Fluoride Abstraction from cis-[CrIIIF2(phen)2]+

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  35. Heterometallic FeIII–CeIV complexes from the use of aliphatic aminoalcohol ligands

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  37. Clusters of Actinides with Oxide, Peroxide, or Hydroxide Bridges

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  38. {Ce10Mn8}: Cerium Analogues of the Decavanadate Archetype

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  39. Magnetic anisotropy and exchange coupling in a family of isostructural FeIII2LnIII2 complexes

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  40. Dinuclear and heptanuclear nickel(II) complexes: Anion coordination induced ligand arm hydrolysis and aggregation around a nickel(II) core

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  41. Rare nuclearities, new structural motifs, and slow magnetization relaxation phenomena in manganese cluster chemistry: A Mn15Na2 cage from the use of triethanolamine/pivalate/azide “blend”

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  42. Tris-dipicolinate Cerium Complexes Bearing Dications of Arginine, Histidine, and Ornithine

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  43. A family of novel Mn 3 Ln 4 clusters displaying single-molecule magnet behavior

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  44. The multiple core–shell structure in Cu24Ln6 cluster with magnetocaloric effect and slow magnetization relaxation

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  45. Tuning the magnetic behaviors in [Fe III 12 Ln III 4 ] clusters with aromatic carboxylate ligands

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  46. Tetranuclear Lanthanide(III) Complexes with a Zigzag Topology from the Use of Pyridine-2,6-dimethanol: Synthetic, Structural, Spectroscopic, Magnetic and Photoluminescence Studies

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  47. Manganese/Cerium Clusters Spanning a Range of Oxidation Levels and CeMn8, Ce2Mn4, and Ce6Mn4Nuclearities: Structural, Magnetic, and EPR Properties

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  48. Hybrid Uranium–Transition-Metal Oxide Cage Clusters

    Inorganic Chemistry · 2014-12-01

    Jie Ling, Franklin Hobbs, Steven Prendergast, Pius O. Adelani, Jean‐Marie Babo, Jie Qiu, Zhehui Weng, Peter Carman Burns

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  49. Playing with different metalloligands [NiL] and Hg to [NiL] ratios to tune the nuclearity of Ni(II)–Hg(II) complexes: Formation of di-, tri-, hexa- and nona-nuclear Ni–Hg clusters

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    Lakshmi Kanta Das, Carlos J. Gómez‐García, Michael G. B. Drew, Ashutosh Ghosh

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  50. Nitronyl nitroxide based 2p–3d–4f chains with the magnetocaloric effect and slow magnetic relaxation

    Dalton Transactions · 2015-01-01

    Xiufeng Wang, Cun Li, Juan Sun, Licun Li

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