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RESEARCH PAPER · Coordination Chemistry Reviews · 2013

The crystal chemistry of uranium carboxylates

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The crystal chemistry of uranium carboxylatesOriginalActinide oxalates, solid state structures and applications160The exploration of supramolecular interactions stemming from the [UO 2 (NCS) 4 (H 2 O)] 2− tecton and substituted pyridinium cations37Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers18Increasing Complexity in the Uranyl Ion–Kemp’s Triacid System: From One- and Two-Dimensional Polymers to Uranyl–Copper(II) Dodeca- and Hexadecanuclear Species47A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Tris(acrylato)uranylates as a scaffold for NLO materials21A new organically templated open-framework uranyl ethylenediphosphonate6Changing Hafnium Speciation in Aqueous Sulfate Solutions: A High-Energy X-ray Scattering Study46CuPYDC Metalloligands and Postsynthetic Rearrangement/Metalation as Routes to Bimetallic Uranyl Containing Hybrid Materials: Syntheses, Structures, and Fluorescence37Uranyl Ion Complexes with all-cis-1,3,5-Cyclohexanetricarboxylate: Unexpected Framework and Nanotubular Assemblies55[(C 2 H 5 ) 4 N][U 2 O 4 (HCOO) 5 ], an Ammonium Uranyl Formate Framework Showing Para- to Ferro-Electric Transition: Synthesis, Structures, and Properties17Uranyl Ion Complexes with trans‐3‐(3‐Pyridyl)acrylic Acid Including a Uranyl–Copper(II) Heterometallic Framework21ChemInform Abstract: The Crystal Chemistry of Uranium Carboxylates1The First Family of Actinide Carboxyphosphinates: Two‐ and Three‐Dimensional Uranyl Coordination Polymers27Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29Use of 2,2-Bipyrimidine for the Preparation of UO22+-3d Diphosphonates18Novel [(UO2)O6(NO3) ] (n= 1, 2) based units in organically templated uranyl compounds10Isolated Uranyl Chromate and Polychromate Units in Crown Ether Templated Compounds18Trinuclear {Sr[UO 2 L 3 ] 2 (H 2 O) 4 } and pentanuclear {Sr[UO 2 L 3 ] 4 } 2− uranyl monocarboxylate complexes (L-acetate or n-butyrate ion)31Combining coordination and supramolecular chemistry to explore uranyl assembly in the solid state51Synthesis, spectroscopic characterization and crystal structures of thorium(IV) mononuclear lactato and hexanuclear formato complexes19A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31B-α-[AsW 9 O 33 ] 9− polyoxometalates incorporating hexanuclear uranium {U 6 O 8 }-like clusters bearing the U IV form or unprecedented mixed valence U IV /U VI involving direct U VI O–U IV bonding27Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Synthesis, spectral characterization, structural studies, molecular docking and antimicrobial evaluation of new dioxidouranium( vi ) complexes incorporating tetradentate N 2 O 2 Schiff base ligands49Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16Uranium( vi ) complexes with isonicotinic acid: from monomer to 2D polymer with unique U–N bonding43Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Uranyl and Uranyl–3d Block Cation Complexes with 1,3-Adamantanedicarboxylate: Crystal Structures, Luminescence, and Magnetic Properties68Synthesis and structure of AUO2(n-C3H7COO)3 (A= Rb or Cs) and RbUO2(n-C4H9COO)317Thorium(IV) organic frameworks with aromatic polycarboxylate ligands11Heterometallic zinc uranium oxyfluorides incorporating imidazole ligands3Structural variations in terbium(III) complexes with 1,3-adamantanedicarboxylate and diverse co-ligands10Synthesis, Structure, and Nonlinear Optical Activity of K, Rb, and Cs Tris(crotonato)uranylates(VI)17Solvothermal Synthesis of Tetravalent Uranium with Isophthalate or Pyromellitate Ligands13Role of N-Donor Sterics on the Coordination Environment and Dimensionality of Uranyl Thiophenedicarboxylate Coordination Polymers53Structural chemistry of uranium phosphonates143Tetranuclear Uranyl Polyrotaxanes: Preferred Selectivity toward Uranyl Tetramer for Stabilizing a Flexible Polyrotaxane Chain Exhibiting Weakened Supramolecular Inclusion28Two-dimensional assemblies in f-element ion (UO22+, Yb3+) complexes with two cyclohexyl-based polycarboxylates21Die Renaissance der nichtwässrigen Uranchemie81The Renaissance of Non‐Aqueous Uranium Chemistry515Uranyl Ion Complexes with 1,1′-Biphenyl-2,2′,6,6′-tetracarboxylic Acid: Structural and Spectroscopic Studies of One- to Three-Dimensional Assemblies36Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction7Unexpected cis-dioxido uranyl carboxylate compound: Synthesis, characterization and photocatalytic activity of uranyl-succinate complexes17The “periodic table” of benzotriazoles: Uranium(VI) complexes13Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Synthesis, Structure, and Photoluminescence Properties of an Organically‐Templated Uranyl Selenite3Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations25Complexes of uranyl glutarate with urea and dimethylurea: Synthesis and structure5Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52A Family of Uranyl Coordination Polymers Containing O-Donor Dicarboxylates and Trispyridyltriazine Guests36Uranyl Complexes with (Meth)acrylate Anions10The templated synthesis of a unique type of tetra-nuclear uranyl-mediated two-fold interpenetrating uranyl–organic framework36Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28Probing the Influence of N‐Donor Capping Ligands on Supramolecular Assembly in Molecular Uranyl Materials45Layered and three-dimensional uranyl–organic assemblies with 4,4′-oxidiphthalic acid4A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption17An investigation of the interactions of Eu 3+ and Am 3+ with uranyl minerals: implications for the storage of spent nuclear fuel21Anchoring flexible uranyl dicarboxylate chains through stacking interactions of ancillary ligands on chiral U( vi ) centres37Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39First three-dimensional actinide polyrotaxane framework mediated by windmill-like six-connected oligomeric uranyl: dual roles of the pseudorotaxane precursor19Structural diversity of uranyl acrylates6Structure and some properties of UO2(C2H5COO)2 · nQ · mH2O (Q is carbamide or ethylenecarbamide)2Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21Synthesis, structures, and photoluminescent properties of two uranium complexes constructed by a flexible zwitterion ligand18From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Directing dimensionality in uranyl malate and copper uranyl malate compounds15Uranyl Ion Complexes with Long-Chain Aliphatic α,ω-Dicarboxylates and 3d-Block Metal Counterions34Structural Variations of the First Family of Heterometallic Uranyl Carboxyphosphinate Assemblies by Synergy between Carboxyphosphinate and Imidazole Ligands21Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Synthesis and Hydrolysis of Uranyl, Neptunyl, and Plutonyl Gas-Phase Complexes Exhibiting Discrete Actinide–Carbon Bonds39Synthesis, structure, luminescence and photocatalytic properties of an uranyl-2,5-pyridinedicarboxylate coordination polymer32Uranyl oxamate hydrates: hydrothermal synthesis, crystal structure, photophysical properties, and selective crystallization0Modulation of the Structure and Properties of Uranyl Ion Coordination Polymers Derived from 1,3,5-Benzenetriacetate by Incorporation of Ag(I) or Pb(II)46An Unprecedented Two‐Fold Nested Super‐Polyrotaxane: Sulfate‐Directed Hierarchical Polythreading Assembly of Uranyl Polyrotaxane Moieties17Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores213Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores54Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Hydrothermal Crystallization of Uranyl Coordination Polymers Involving an Imidazolium Dicarboxylate Ligand: Effect of pH on the Nuclearity of Uranyl-Centered Subunits38Synthesis and structure of the complex of uranyl citraconate with urea4Structures of Metal–Organic Frameworks with Rod Secondary Building Units909Synthesis and crystal structure analysis of uranyl triple acetates12Copper/Zinc-Directed Heterometallic Uranyl-Organic Polycatenating Frameworks: Synthesis, Characterization, and Anion-Dependent Structural Regulation32Series of Hydrated Heterometallic Uranyl-Cobalt(II) Coordination Polymers with Aromatic Polycarboxylate Ligands: Formation of U═O—Co Bonding upon Dehydration Process29Harnessing uranyl oxo atoms via halogen bonding interactions in molecular uranyl materials featuring 2,5-diiodobenzoic acid and N-donor capping ligands39Tetrahydrofurantetracarboxylic Acid: An Isomerizable Framework-Forming Ligand in Homo- and Heterometallic Complexes with UO22+, Ag+, and Pb2+23Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption64Complexation of Uranyl Ion with Sulfonates: One‐ to Three‐Dimensional Assemblies with 1,5‐ and 2,7‐Naphthalenedisulfonates15Dicyanoaurate-based heterobimetallic uranyl coordination polymers26Inorganic Synthesis of Actinides3Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93Structure of glutarate-containing uranyl coordination polymers with organic amides2Temperature-induced reversible single-crystal-to-single-crystal isomerisation of uranyl polyrotaxanes: an exquisite case of coordination variability of the uranyl center19The crystalline α,ω-dicarboxylate metal complex with the longest aliphatic chain to date: uranyl 1,15-pentadecanedioate10Two uranyl heterocyclic carboxyl compounds with fluorescent properties as high sensitivity and selectivity optical detectors for nitroaromatics13Coordination Polymers and Cage-Containing Frameworks in Uranyl Ion Complexes with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylates: Consequences of Chirality38Syntheses, crystal structure, and photocatalytic property of two new complexes of an unsymmetrical Schiff base ligand26Two Three‐Dimensional Actinide–Silver Heterometallic Coordination Polymers Based on 2,2′‐Bipyridine‐3,3′‐dicarboxylic Acid with Helical Chains Containing Dimeric or Trimeric Motifs21Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Variations on the Honeycomb Topology: From Triangular- and Square-Grooved Networks to Tubular Assemblies in Uranyl Tricarballylate Complexes34New ligands for uranium complexation: A stable uranyl dimer bearing 2,6-diacetylpyridine dioxime7Thorium aspartate tetrahydrate precursor to ThO 2 : Comparison of hydrothermal and thermal conversions27AgI and PbII as Additional Assembling Cations in Uranyl Coordination Polymers and Frameworks44Charge‐Assisted Hydrogen‐Bonding and Crystallization Effects within UVI Glycine Compounds21Mixed-Ligand Uranyl Polyrotaxanes Incorporating a Sulfate/Oxalate Coligand: Achieving Structural Diversity via pH-Dependent Competitive Effect29Utilizing bifurcated halogen-bonding interactions with the uranyl oxo group in the assembly of a UO2–3-bromo-5-iodobenzoic acid coordination polymer17Tetrahedral and Cuboidal Clusters in Complexes of Uranyl and Alkali or Alkaline-Earth Metal Ions with rac- and (1R,2R)-trans-1,2-Cyclohexanedicarboxylate29Uranyl Complexes as Scaffolding or Spacers for Cucurbit[6]uril Molecules in Homo‐ and Heterometallic Species, Including a Uranyl–Lanthanide Complex13Bottom-up construction of a superstructure in a porous uranium-organic crystal355m-Carboranylphosphinate as Versatile Building Blocks To Design all Inorganic Coordination Polymers25Morphotropy in alkaline uranyl methacrylate complexes9Thermochemical properties of U(VI) hybrid materials containing uranyl tetrachloride anions8Syntheses, Crystal Structures, and Nonlinear Optical Activity of Cs 2 Ba[AnO 2 (C 2 H 5 COO) 3 ] 4 (An = U, Np, Pu) and Unprecedented Octanuclear Complex Units in KR 2 (H 2 O) 8 [UO 2 (C 2 H 5 COO) 3 ] 5 (R = Sr, Ba)21Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Synthesis and characterization of heterometallic uranyl pyridinedicarboxylate compounds19Syntheses, Structures, and Comparisons of Heterometallic Uranyl Iodobenzoates with Monovalent Cations27Supramolecular Host–Guest Inclusion for Distinguishing Cucurbit[7]uril‐Based Pseudorotaxanes from Small‐Molecule Ligands in Coordination Assembly with a Uranyl Center35Structure of complexes of uranyl succinate with carbamide and dimethylurea4Spectral Analysis of the Uranyl Squarate and Croconate System: Evaluating Differences between the Solution and Solid-State Phases17Porous Uranium Diphosphonate Frameworks with Trinuclear Units Templated by Organic Ammonium Hydrolyzed from Amine Solvents23Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Complexes of Uranyl Ions with Aromatic Di‐ and Tetracarboxylates Involving [Ni(bipy)n]2+ (n = 2, 3) Counterions12Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Mg, Ca and Ba glutaratouranylates – Synthesis and structure9Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones11Uranyl Ion Complexes with Chiral Malic and Citramalic, and Prochiral Citric and Tricarballylic Acids: Influence of Coligands and Additional Metal Cations19{Np 38 } clusters: the missing link in the largest poly-oxo cluster series of tetravalent actinides40A neptunium( v )-mediated interwoven transuranium-rotaxane network incorporating a mechanically interlocked [ c 2]daisy chain unit25Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110All inorganic coordination polymers have been made possible with the m -carboranylphosphinate ligand8Crystal structures of uranyl complexes with isobutyrate and isovalerate anions9Homoleptic U( iii ) and U( iv ) amidate complexes15Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour14Non-covalent interactions of uranyl complexes: a theoretical study18Probing hydrogen and halogen-oxo interactions in uranyl coordination polymers: a combined crystallographic and computational study25Uranyl dication mediated photoswitching of a calix[4]pyrrole-based metal coordination cage20Tunable 4f/5f Bimodal Emission in Europium-Incorporated Uranyl Coordination Polymers42An Anionic Uranium-Based Metal–Organic Framework with Ultralarge Nanocages for Selective Dye Adsorption67

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  21. Novel [(UO2)O6(NO3) ] (n= 1, 2) based units in organically templated uranyl compounds

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  37. Synthesis and structure of AUO2(n-C3H7COO)3 (A= Rb or Cs) and RbUO2(n-C4H9COO)3

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