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RESEARCH PAPER · Inorganic Chemistry · 2017

Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium

Nicolas P. Martin, Juliane März, Christophe Volkringer, Natacha Henry, Christoph Hennig, Atsushi Ikeda‐Ohno, Thierry Loiseau

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Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous MediumOriginalU(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands51Mixed sulfoisophthalate and 1,2,4-triazole directed d 10 metal coordination polymers: Synthesis, property and structural diversity10Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks127Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation40Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones11Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np 6 O 8 } hexanuclear clusters61Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates42Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange37Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14Effect of solution acidity on the structure of amino acid-bearing uranyl compounds7In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal–Organic Framework47Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions4A Redox-Innocent Uranium(IV)-Quinoid Metal-Organic Framework8Structural and Spectroscopic Investigation of Two Plutonium Mellitates18Pressure-Induced Spectroscopic Changes in a Californium 1D Material Are Twice as Large as Found in the Holmium Analog22Pronounced Pressure Dependence of Electronic Transitions for Americium Compared to Isomorphous Neodymium and Samarium Mellitates30Controlling the Reduction of Chelated Uranyl to Stable Tetravalent Uranium Coordination Complexes in Aqueous Solution15Coordination of trivalent lanthanum and cerium, and tetravalent cerium and actinides (An = Th( iv ), U( iv ), Np( iv )) by a 4-phosphoryl 1 H -pyrazol-5-olate ligand in solution and the solid state19Dimerization of Phthalate Ion in Non-Aqueous Solvents1The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds41An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Crystallographic, spectroscopic, thermal and computational studies of polymeric cobalt(II)–mellitate complex with 2,2′-bipyridine0Recent advances in uranium-containing polyoxometalates59Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates13Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids2Complexation of Np(V) and Pa(V) with some aromatic carboxylic ligands0Enhancing Gas Separation Selectivity Prediction through Geometrical and Chemical Descriptors15In Situ and Ex Situ Luminescence Investigation of Rare Earth Layered Double Hydroxides Intercalated with Mellitate Anion3Relativistic DFT investigation for reaction energies and electronic/bonding properties of Schiff-base polypyrrolic uranyl(V) complexes: effects of group 14-functionalized uranyl exo-oxo group0Reinvestigation of a Two‐Dimensional Cu(II)–Ba(II) Heterometallic Coordination Polymer Based on o ‐Phthalate Ligand, Infrared Spectroscopy, Thermal Behavior, and Hirshfeld Surface Analysis0The first bimetallic Np( v ) MOF with a Np 4 Cs 2 O 8 structural unit: sorption properties and thermal and radiation stability0

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  1. U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands

    Inorganic Chemistry · 2017-05-16

    Clément Falaise, Harrison A. Neal, May Nyman

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  2. Mixed sulfoisophthalate and 1,2,4-triazole directed d 10 metal coordination polymers: Synthesis, property and structural diversity

    Journal of Solid State Chemistry · 2017-07-04

    Bing Liu, Kai Guo, Huijun Feng, Wei-Ni Miao, Tingting He, Ling Fang Xu

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  3. Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks

    Journal of the American Chemical Society · 2017-10-25

    Ekaterina A. Dolgopolova, Otega A. Ejegbavwo, Corey R. Martin, Mark D. Smith, Wahyu Setyawan, S. Karakalos, Charles H. Henager, Hans‐Conrad zur Loye, Natalia B. Shustova

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  4. Interpenetrated Uranyl–Organic Frameworks with bor and pts Topology: Structure, Spectroscopy, and Computation

    Inorganic Chemistry · 2017-11-01

    Chao Liu, Fangyuan Chen, Hong‐Rui Tian, Jing Ai, Weiting Yang, Qing‐Jiang Pan, Zhong‐Ming Sun

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  5. Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones

    Solid State Sciences · 2017-12-08

    Korey Prescott Carter, Andrew T. Kerr, Il'ya Viktorovich Taydakov, Christopher L. Cahill

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  6. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

    Chemical Communications · 2018-01-01

    Ekaterina A. Dolgopolova, Allison M. Rice, Natalia B. Shustova

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  7. Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np 6 O 8 } hexanuclear clusters

    Chemical Communications · 2018-01-01

    Nicolas P. Martin, Juliane März, H. Feuchter, Sylvain Duval, Pascal Roussel, Natacha Henry, Atsushi Ikeda‐Ohno, Thierry Loiseau, Christophe Volkringer

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  8. Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates

    Inorganic Chemistry · 2018-06-07

    Nicole A. Vanagas, Jennifer N. Wacker, Christopher L. Rom, Elliot N. Glass, Ian Colliard, Yusen Qiao, Jeffery A. Bertke, Edward Van Keuren, Eric J. Schelter, May Nyman, Karah E. Knope

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  9. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  10. Conformational 2-Fold Interpenetrated Uranyl Supramolecular Isomers Based on (6,3) Sheet Topology: Structure, Luminescence, and Ion Exchange

    Inorganic Chemistry · 2018-11-27

    Chao Liu, Chao Wang, Zhong‐Ming Sun

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  11. Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )

    RSC Advances · 2019-01-01

    Maxime Dufaye, Nicolas P. Martin, Sylvain Duval, Christophe Volkringer, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  12. Effect of solution acidity on the structure of amino acid-bearing uranyl compounds

    Radiochimica Acta · 2019-01-05

    Еvgeny V. Nazarchuk, Yuri A. Ikhalaynen, Dmitri O. Charkin, Oleg I. Siidra, Vladimir Gennadievich Petrov, Stepan Nikolaevich Kalmykov, Artem S. Borisov

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  13. In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal–Organic Framework

    Journal of the American Chemical Society · 2019-07-22

    Sara E. Gilson, Peng Li, Jennifer E. S. Szymanowski, Jacob White, Debmalya Ray, Laura Gagliardi, Omar K. Farha, Peter Carman Burns

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  14. Thorium(IV) and Uranium(IV) Complexes with Cucurbit[8]Uril: Supramolecular Structures Via Direct Coordination and Second-Shell Interactions

    Polyhedron · 2020-01-01

    Yingjie Zhang, Inna Karatchevtseva, Ming Liu, Zhu Tao, Gang Wei

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  15. A Redox-Innocent Uranium(IV)-Quinoid Metal-Organic Framework

    ACS Omega · 2020-02-10

    Vanja E. Refn, Mariusz Grzegorz Kubus, Susanne Mossin, René Wugt Larsen, Kasper S. Pedersen

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  16. Structural and Spectroscopic Investigation of Two Plutonium Mellitates

    Inorganic Chemistry · 2020-02-10

    Joseph M. Sperling, Alyssa Gaiser, Cory J. Windorff, Bonnie E. Klamm, Megan A. Whitefoot, Alexander T. Chemey, Brian N. Long, Joanna G. Campbell, Thomas E. Albrecht‐Schmitt

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  17. Pressure-Induced Spectroscopic Changes in a Californium 1D Material Are Twice as Large as Found in the Holmium Analog

    Inorganic Chemistry · 2020-07-10

    Joseph M. Sperling, Evan Warzecha, Cory J. Windorff, Bonnie E. Klamm, Alyssa Gaiser, Megan A. Whitefoot, Frankie D. White, Todd N. Poe, Thomas E. Albrecht-Schönzart

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  18. Pronounced Pressure Dependence of Electronic Transitions for Americium Compared to Isomorphous Neodymium and Samarium Mellitates

    Inorganic Chemistry · 2020-12-16

    Joseph M. Sperling, Evan Warzecha, Bonnie E. Klamm, Alyssa Gaiser, Cory J. Windorff, Megan A. Whitefoot, Thomas E. Albrecht-Schönzart

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  19. Controlling the Reduction of Chelated Uranyl to Stable Tetravalent Uranium Coordination Complexes in Aqueous Solution

    Inorganic Chemistry · 2020-12-28

    Korey Prescott Carter, Kurt F. Smith, Toni Tratnjek, Gauthier J.‐P. Deblonde, Liane M. Moreau, Julian A. Rees, Corwin H. Booth, Rebecca J. Abergel

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  20. Coordination of trivalent lanthanum and cerium, and tetravalent cerium and actinides (An = Th( iv ), U( iv ), Np( iv )) by a 4-phosphoryl 1 H -pyrazol-5-olate ligand in solution and the solid state

    Dalton Transactions · 2021-01-01

    Jianfeng Zhang, Marco Wenzel, Kathleen Schnaars, Felix Hennersdorf, Kai Schwedtmann, Juliane März, A. Roßberg, Peter Kaden, Florian Kraus, Thorsten Stumpf, Jan J. Weigand

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  21. Dimerization of Phthalate Ion in Non-Aqueous Solvents

    Russian Journal of General Chemistry · 2021-05-01

    Viktor G. Nosov, K. A. Podryadrova, M. S. Vasilyeva, Nikita A. Bogachev, Mikhail Yu. Skripkin, Andrey S. Mereshchenko

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  22. The crystal and coordination chemistry of neptunium in all its oxidation states: An expanded structural hierarchy of neptunium compounds

    Coordination Chemistry Reviews · 2021-06-05

    Sara E. Gilson, Peter Carman Burns

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  23. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  24. Crystallographic, spectroscopic, thermal and computational studies of polymeric cobalt(II)–mellitate complex with 2,2′-bipyridine

    Journal of Molecular Structure · 2021-12-15

    Lidija Radovanović, Dušan P. Malenov, Marko V. Rodić, Aleksandar Kremenović, Jelena Rogan

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  25. Recent advances in uranium-containing polyoxometalates

    Inorganic Chemistry Frontiers · 2022-01-01

    Guo‐Ping Yang, Ke Li, Changwen Hu

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  26. Two Neptunium(III) Mellitate Coordination Polymers: Completing the Series Np–Cf of Trans-Uranic An(III) Mellitates

    Inorganic Chemistry · 2022-10-25

    Nicholas Beck, Zhuanling Bai, Jacob P. Brannon, Daniela Gomez Martinez, Dennis Grödler, Brian N. Long, Todd N. Poe, Brian M. Rotermund, Thomas E. Albrecht-Schönzart, Joseph M. Sperling

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  27. Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids

    Inorganic Chemistry · 2023-05-11

    Andrei Andreichenko, Aurélien R. Willauer, Till Schertenleib, Antoine Curé, Rosario Scopelliti, Farzaneh Fadaei‐Tirani, Wendy Lee Queen, Anne‐Sophie Chauvin, Marinella Mazzanti

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  28. Complexation of Np(V) and Pa(V) with some aromatic carboxylic ligands

    Unknown journal · 2023-06-28

    Meng Luo

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  29. Enhancing Gas Separation Selectivity Prediction through Geometrical and Chemical Descriptors

    Chemistry of Materials · 2023-08-30

    Emmanuel Ren, François‐Xavier Coudert

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  30. In Situ and Ex Situ Luminescence Investigation of Rare Earth Layered Double Hydroxides Intercalated with Mellitate Anion

    Advanced Optical Materials · 2024-11-02

    Ercules E. S. Teotônio, Giscard Doungmo, Jonas Ströh, Danilo Mustafa, Israel F. Costa, Hermi Felinto de Brito, Aleksei Kotlov, Huayna Terraschke

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  31. Relativistic DFT investigation for reaction energies and electronic/bonding properties of Schiff-base polypyrrolic uranyl(V) complexes: effects of group 14-functionalized uranyl exo-oxo group

    Journal of Molecular Modeling · 2025-05-14

    Xiu‐Jun Zheng, Qing‐Jiang Pan, Yanping Dong

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  32. Reinvestigation of a Two‐Dimensional Cu(II)–Ba(II) Heterometallic Coordination Polymer Based on o ‐Phthalate Ligand, Infrared Spectroscopy, Thermal Behavior, and Hirshfeld Surface Analysis

    Zeitschrift für anorganische und allgemeine Chemie · 2025-12-03

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  33. The first bimetallic Np( v ) MOF with a Np 4 Cs 2 O 8 structural unit: sorption properties and thermal and radiation stability

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