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RESEARCH PAPER · Inorganic Chemistry · 2015

Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System

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Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O SystemOriginalCentrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments45Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity596De facto methodologies toward the synthesis and scale-up production of UiO-66-type metal–organic frameworks and membrane materials197Chemical and Structural Evolution in the Th–SeO 3 2– /SeO 4 2– System: from Simple Selenites to Cluster-Based Selenate Compounds29Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions449Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U3827Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid28Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34A highly stable dimethyl-functionalized Ce( iv )-based UiO-66 metal–organic framework material for gas sorption and redox catalysis94Hydrolysis of thorium( iv ) at variable temperatures22Synthesis and structure of Zr( iv )- and Ce( iv )-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene99Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions21Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Postsynthetic Modification of Zirconium Metal‐Organic Frameworks238Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate32Synthesis and Characterization of New Ce(IV)-MOFs Exhibiting Various Framework Topologies235Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Thorium aspartate tetrahydrate precursor to ThO 2 : Comparison of hydrothermal and thermal conversions27U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands51Linking Solution Structures and Energetics: Thorium Nitrate Complexes17Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)11Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks127A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology16Structural diversity of a series of terpyridyl carboxylate coordination polymers: Luminescent sensor and magnetic properties24Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies5Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0A precursor method for the synthesis of new Ce( iv ) MOFs with reactive tetracarboxylate linkers82Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones11Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Computational screening of hydrophobic metal–organic frameworks for the separation of H 2 S and CO 2 from natural gas120Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction44Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np 6 O 8 } hexanuclear clusters61Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation152Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation32In Situ Reduction from Uranyl Ion into a Tetravalent Uranium Trimer and Hexamer Featuring Ion-Exchange Properties and the Alexandrite Effect16Cerium Metal–Organic Framework for Photocatalysis525Solution and Solid State Structural Chemistry of Th(IV) and U(IV) 4-Hydroxybenzoates42Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Thorium Oxo‐Clusters as Building Blocks for Open Frameworks37Systematic Investigations of the Transition between Framework Topologies in Ce/Zr-MOFs40Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF81From Transition Metals to Lanthanides to Actinides: Metal-Mediated Tuning of Electronic Properties of Isostructural Metal–Organic Frameworks100Synthesis, Structure, and Characterization of Defect‐free [Hf6(μ3‐O)4(μ3‐OH)4(C4H2O4)6] (Hf‐UiO‐66‐Fum)10Investigation of the Kinetic Stabilization of a Ce4+‐based MOF by in‐situ Powder X‐ray Diffraction26Metal doping in cerium metal-organic frameworks for visible-response water splitting photocatalysts82Water-Based Synthesis and Enhanced CO 2 Capture Performance of Perfluorinated Cerium-Based Metal–Organic Frameworks with UiO-66 and MIL-140 Topology122Photo-induced Charge Separation and Photoredox Catalysis in Cerium-Based Metal–Organic Frameworks7Temperature modulation of defects in NH 2 -UiO-66(Zr) for photocatalytic CO 2 reduction92The first water-based synthesis of Ce( iv )-MOFs with saturated chiral and achiral C 4 -dicarboxylate linkers42Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14Metal‐organic Framework Sponges4Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework44Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50Exploring the Role of Hexanuclear Clusters as Lewis Acidic Sites in Isostructural Metal–Organic Frameworks100Optimization of the synthesis of UiO-66(Zr) in ionic liquids25Monomeric and Trimeric Thorium Chlorides Isolated from Acidic Aqueous Solution18A Double-Walled Thorium-Based Metal–Organic Framework as a Promising Dual-Function Absorbent for Efficiently Capturing Iodine and Dyes54Effect of linker and metal on photoreduction and cascade reactions of nitroaromatics by M-UiO-66 metal organic frameworks17Crystal Chemistry and SAXS Studies of an Octahedral Polyoxoarsenotungstate Nanocluster Encapsulating Four Unprecedented Thorium Arsenate Fragments ({Th3As2On} – n = 25 or 26)10Atomic‐ and Molecular‐Level Design of Functional Metal–Organic Frameworks (MOFs) and Derivatives for Energy and Environmental Applications213Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34Actinide Dioxide Nanoparticles4Ce-MIL-140: expanding the synthesis routes for cerium( iv ) metal–organic frameworks33The chemistry of Ce-based metal–organic frameworks185Triazine Functionalized Porous Three-Dimensional Uranyl–Organic Framework: Extraction of Uranium(VI) and Adsorption of Cationic Dyes in Aqueous Solution34Influence of oxophilic behavior of UiO‐66(Ce) metal–organic framework with superior catalytic performance in Friedel‐Crafts alkylation reaction41Thorium–Organic Framework Constructed with a Semirigid Triazine Hexacarboxylic Acid Ligand: Unique Structure with Thorium Oxide Wheel Clusters and Iodine Adsorption Behavior74A periodic table of metal-organic frameworks121Supramolecular Assembly of U(IV) Clusters and Superatoms with Unconventional Countercations51Advancement of Actinide Metal–Organic Framework Chemistry via Synthesis of Pu-UiO-6660From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture302Building [UIV70(OH)36(O)64]4− Oxocluster Frameworks with Sulfate, Transition Metals, and UV11Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework86UiO-66(Ce) metal-organic framework as a highly active and selective catalyst for the aerobic oxidation of benzyl amines58Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10Ce IV 70 Oxosulfate Rings, Frameworks, Supramolecular Assembly, and Redox Activity**52CeIV70Oxosulfate Rings, Frameworks, Supramolecular Assembly, and Redox Activity**8Synthèses et caractérisations de nouveaux matériaux de coordination ou supramoléculaires à clusters d’éléments de transition0Synthesis of 1,8-naphthimide-based fluorescent perchloroethylene and its application in the analysis of H2O/DMF composition0Synthesis, Characterization, and Solid-State Structural Chemistry of Uranium(IV) Aliphatic Dicarboxylates7Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption35A hafnium-based metal-organic framework for the entrapment of molybdenum hexacarbonyl and the light-responsive release of the gasotransmitter carbon monoxide17Structural Evolution from Noninterpenetrated to Interpenetrated Thorium–Organic Frameworks Exhibiting High Propyne Storage19Cerium based UiO-66 MOF as a multipollutant adsorbent for universal water purification386Conception et élaboration de matériaux hybrides à base d'oxydes d'uranium et de thorium0An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization30An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145An fcu Th-MOF Constructed from In Situ Coupling of Monovalent Ligands7Rational tuning of thorium-organic frameworks by reticular chemistry for boosting radionuclide sequestration43Stepwise Assembly of a Multicomponent Heterometallic Metal–Organic Framework via Th6-Based Metalloligands15Sustainable synthesis of semicrystalline Zr-BDC MOF and heterostructural Ag3PO4/Zr-BDC/g-C3N4 composite for photocatalytic dye degradation65Discrimination and quantitation of halobenzoic acid positional isomers upon Th( iv ) coordination by mass spectrometry11Enhanced Xe/Kr separation via the pore size confinement effect of a microporous thorium-based metal–organic framework9Gas-phase synthesis and structure of thorium benzyne complexes9One Step Synthesis of Transition Metal Modified Uio-66-Ce Metal-Organic Framework: Catalytic Oxidation of Toluene and Investigation of the Mechanism0One-Step Synthesis of Transition Metal Modified Uio-66-Ce Metal-Organic Framework: Catalytic Oxidation of Toluene and Investigation of the Mechanism2Structural transformation of metal oxo species within UiO-66 type metal–organic frameworks9MOFs with 12-Coordinate 5f-Block Metal Centers41Extrusion-Spheronization of UiO-66 and UiO-66_NH2 into Robust-Shaped Solids and Their Use for Gaseous Molecular Iodine, Xenon, and Krypton Adsorption46Potassium Storage Performance of UiO-66 Derivatives from First Principles Calculations11The chemistry of metal–organic frameworks with face-centered cubic topology59Leveraging Nitrogen Linkages in the Formation of a Porous Thorium–Organic Nanotube Suitable for Iodine Capture24Metal–Oxo Cluster Formation Using Ammonium and Sulfate to Differentiate M IV (Th, U, Ce) Chemistries16The role of cobalt to control the synthesis of nanoscale Co/UiO‐66 composite for photocatalysis12Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Role of Metal Selection in the Radiation Stability of Isostructural M-UiO-66 Metal–Organic Frameworks58Extremely Stable Thorium‐MOF Assembly of Tetraphenylethylene Derivative With Tunable AIE Property and Highly Selective Detection of Nitro Aromatic Compounds28Polymer-in-salt electrolyte enables ultrahigh ionic conductivity for advanced solid-state lithium metal batteries197Fabrication of a Cd( ii ) metal–organic framework as a dual functional material: efficient iodine capture and selective adsorption of a cationic dye24Synthesis, structures, and characterizations of four uranyl coordination polymers constructed by mixed-ligand strategy0Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Bismuth-Polyoxocation Coordination Networks: Controlling Nuclearity and Dimension-Dependent Photocatalysis12Integrating Metal Complex Units and Redox Sites into Thorium‐Based Metal–Organic Frameworks for Selective Photocatalytic Oxidation of Sulfides37Green Synthesis of Cerium-Based Metal–Organic Framework (Ce-UiO-66 MOF) for Wastewater Treatment66Uranium extraction by metal–organic frameworks: advanced materials for new sorption possibilities18Designed assembly of heterometallic cluster organic frameworks based on Th6 cluster14Recent progress in separation of technetium-99 from spent nuclear fuel and radioactive waste. Challenges and prospects55Building Co16‐N3‐Based UiO‐MOF to Expand Design Parameters for MOF Photosensitization1Building Co16‐N3‐Based UiO‐MOF to Expand Design Parameters for MOF Photosensitization19Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials18Boosting the uranium adsorption capacity of UiO-66 (Ce) by incorporation of amino groups: Experimental and theoretical perspective12Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers8Developments in the discovery, synthesis, and characterization of RE( iii )-UiO-66 and its structural analogues1What goes on in sub-critical solvothermal synthesis of metal ion complexes?2Crystallographic Evidence for Formation of M 6 O 8 /M 6 O 9 f-Element Clusters in Hydrolysis Reactions6Acid Stability of M IV (M = Zr, Hf, Ce, Th) UiO-66 MOFs from a Solution Perspective34Influence of Node–Linker Connectivity on Radiolytic Stability of Thorium-Terephthalate Coordination Polymers5Organic Linker Effect on Iodine Adsorption in Thorium‐Based UiO‐66‐Type Metal Organic Frameworks4Reinvestigation of a Two‐Dimensional Cu(II)–Ba(II) Heterometallic Coordination Polymer Based on o ‐Phthalate Ligand, Infrared Spectroscopy, Thermal Behavior, and Hirshfeld Surface Analysis0A Zn-based MOF with honeycomb topology for highly efficient iodine uptake from vapor and liquid phases: synthesis, crystal structure, topology and dual-phase sorption performance4Aliovalent solid solutions of metal–organic frameworks3Structural and Electronic Insights into Titanium-Modified UiO-66: Probing Cation Substitution via Multi-Technique Characterization and High-Field (1.2 GHz) NMR3Solvent-Mediated Structural Tuning of Eu-MOFs for the N -Formylation of Amines with CO 20Construction of an Amino-Functionalized Thorium MOF for Bifunctional Catalysis toward CO2 Cycloaddition and N-Formylation0Discerning the Role of Simultaneous Morphology Modulation and Oxygen Vacancy Incorporation in Escalating the Photocatalytic Activity of BiOI0Probing the Synthetic Landscape of Thorium 2-Aminoterephthalic Acid MOFs: Implications for MOF Characteristics and Iodine Adsorption0

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  1. Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments

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  2. Cerium-based metal organic frameworks with UiO-66 architecture: synthesis, properties and redox catalytic activity

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  3. De facto methodologies toward the synthesis and scale-up production of UiO-66-type metal–organic frameworks and membrane materials

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  4. Chemical and Structural Evolution in the Th–SeO 3 2– /SeO 4 2– System: from Simple Selenites to Cluster-Based Selenate Compounds

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    Bin Xiao, Eike M. Langer, Jakob Dellen, Hartmut Schlenz, Dirk Bosbach, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  5. Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions

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  6. Ex‐Situ Kinetic Investigations of the Formation of the Poly‐Oxo Cluster U38

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  7. Solvothermal synthesis of uranium(VI) phases with aromatic carboxylate ligands: A dinuclear complex with 4-hydroxybenzoic acid and a 3D framework with terephthalic acid

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  8. Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

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  9. A highly stable dimethyl-functionalized Ce( iv )-based UiO-66 metal–organic framework material for gas sorption and redox catalysis

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  10. Hydrolysis of thorium( iv ) at variable temperatures

    Dalton Transactions · 2016-01-01

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  11. Synthesis and structure of Zr( iv )- and Ce( iv )-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

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  12. Uranium(VI) hybrid materials with [(UO 2 ) 3 (µ 3 ‐O)(µ 2 ‐OH) 3 ] + as the sub–building unit via uranyl–cation interactions

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  13. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers

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  14. Postsynthetic Modification of Zirconium Metal‐Organic Frameworks

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  15. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

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  16. Th3[Th6(OH)4O4(H2O)6](SO4)12(H2O)13: A Self-Assembled Microporous Open-Framework Thorium Sulfate

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  17. Synthesis and Characterization of New Ce(IV)-MOFs Exhibiting Various Framework Topologies

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  18. Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium

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  19. Thorium aspartate tetrahydrate precursor to ThO 2 : Comparison of hydrothermal and thermal conversions

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  20. U(IV) Aqueous Speciation from the Monomer to UO2 Nanoparticles: Two Levels of Control from Zwitterionic Glycine Ligands

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  21. Linking Solution Structures and Energetics: Thorium Nitrate Complexes

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  22. Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters

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  23. Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)

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  24. Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks

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  26. Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors

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  27. Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology

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  28. Structural diversity of a series of terpyridyl carboxylate coordination polymers: Luminescent sensor and magnetic properties

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  29. Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies

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  30. Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité

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  31. A precursor method for the synthesis of new Ce( iv ) MOFs with reactive tetracarboxylate linkers

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  32. Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones

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  33. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

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  34. Computational screening of hydrophobic metal–organic frameworks for the separation of H 2 S and CO 2 from natural gas

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  35. Formation of a new type of uranium( iv ) poly-oxo cluster {U 38 } based on a controlled release of water via esterification reaction

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  36. Synthesis and structural characterization of the first neptunium based metal–organic frameworks incorporating {Np 6 O 8 } hexanuclear clusters

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  37. Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation

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  38. Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation

    Angewandte Chemie · 2018-03-30

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