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RESEARCH PAPER · Dalton Transactions · 2015

Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments

Yuxiang Li, Zhehui Weng, Yanlong Wang, Lanhua Chen, Daopeng Sheng, Yunhai Liu, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environmentsOriginalSynthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34Thorium coordination: A comprehensive review based on coordination number96Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Determination of thorium (IV) using isophthalaldehyde-tetrapyrrole as probe by resonance light scattering, second-order scattering and frequency-doubling scattering spectra9Selective sensing of two novel coordination polymers based on tris(4-carboxylphenyl)phosphine oxide for organic molecules and Fe 3+ and Hg 2+ ions15Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices218Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks127A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology16Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Recent Progress in Asymmetric Catalysis and Chromatographic Separation by Chiral Metal–Organic Frameworks85Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation152Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation32Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride4Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation23Thorium Oxo‐Clusters as Building Blocks for Open Frameworks37A new set of metal–organic frameworks synthesised from diisophthalate-based, 2′-phosphorus-substituted m -terphenyl linker molecules6An untethered C 3v -symmetric triarylphosphine oxide locked by intermolecular hydrogen bonding7A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH4 adsorption: Design, and a systematic study29Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework86Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes22“Turn-on” fluorescent sensor for Th4+ in aqueous media based on a combination of PET-AIE effect22Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties9Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption35An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Structural and multi-functional properties of novel thorium complex bearing higher analogue of guanidine base12Elucidation of Thorium Redox-Active Ligand Complexes: Evidence for a Thorium-Tri(radical) Species23A review on chiral metal–organic frameworks: synthesis and asymmetric applications81Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 54MOFs with 12-Coordinate 5f-Block Metal Centers41Efficient Separation of Trace SO2 from SO2/CO2/N2 Mixtures in a Th-Based MOF23Stabilization of Pu(IV) in PuBr4(OPCy3)2 and Comparisons with Structurally Similar ThX4(OPR3)2 (R = Cy, Ph) Molecules7A ciprofloxacin derived task specific ionic liquid as a highly selective extractant of thorium versus uranium11Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials18Tripodal Tricarboxylic Acids on the Triphenylphosphine Oxide Platform0Metal–Organic Frameworks Formed from Self-Assembled Polynuclear Silver Halide Clusters0Phosphine-functionalized metal-organic frameworks: synthesis, structures and applications0Reactivity of Bestmann’s Ylide, Ph3PCOO, with the Actinides: Observation of An–C Bond Insertion or κ-O Coordination0

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  1. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers

    Crystal Growth & Design · 2016-01-15

    Nicolas P. Martin, Christophe Volkringer, Clément Falaise, Natacha Henry, Thierry Loiseau

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  2. Thorium coordination: A comprehensive review based on coordination number

    Coordination Chemistry Reviews · 2016-11-19

    Charmaine D. Tutson, Anne E. V. Gorden

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  3. Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium

    Inorganic Chemistry · 2017-02-16

    Nicolas P. Martin, Juliane März, Christophe Volkringer, Natacha Henry, Christoph Hennig, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  4. Determination of thorium (IV) using isophthalaldehyde-tetrapyrrole as probe by resonance light scattering, second-order scattering and frequency-doubling scattering spectra

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2017-06-27

    Jiao Wang, Jin-Hua Xue, Xilin Xiao, Li Xu, Min Hua Jiang, Pengcheng Peng, Lifu Liao

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  5. Selective sensing of two novel coordination polymers based on tris(4-carboxylphenyl)phosphine oxide for organic molecules and Fe 3+ and Hg 2+ ions

    Journal of Solid State Chemistry · 2017-09-08

    Liangqin Huo, Jie Zhang, Lingling Gao, Xiaoqing Wang, Liming Fan, Kegong Fang, Tuoping Hu

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  6. Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices

    Coordination Chemistry Reviews · 2017-10-11

    William P. Lustig, Jing Li

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  7. Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks

    Journal of the American Chemical Society · 2017-10-25

    Ekaterina A. Dolgopolova, Otega A. Ejegbavwo, Corey R. Martin, Mark D. Smith, Wahyu Setyawan, S. Karakalos, Charles H. Henager, Hans‐Conrad zur Loye, Natalia B. Shustova

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  8. A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants

    Nature Communications · 2017-11-01

    Yuxiang Li, Zaixing Yang, Yanlong Wang, Zhuanling Bai, Tao Zheng, Xing Dai, Shengtang Liu, Daxiang Gui, Wei Liu, Meng Chen, Lanhua Chen, Juan Diwu, Lingyan Y. Zhu, Ruhong Zhou, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  9. Probing the Influence of Acidity and Temperature to Th(IV) on Hydrolysis, Nucleation, and Structural Topology

    Inorganic Chemistry · 2017-11-08

    Jian Hung Lin, Meiying Qie, Linjuan Zhang, Xiaomei Wang, Yue‐Jian Lin, Wei Liu, Hongliang Bao, Jian‐Qiang Wang

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  10. Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité

    Unknown journal · 2017-12-07

    Nicolas P. Martin

    Read original paper ↗ ·

  11. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

    Chemical Communications · 2018-01-01

    Ekaterina A. Dolgopolova, Allison M. Rice, Natalia B. Shustova

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  12. Recent Progress in Asymmetric Catalysis and Chromatographic Separation by Chiral Metal–Organic Frameworks

    Catalysts · 2018-03-19

    Suchandra Bhattacharjee, Muhammad Ali Khan, Xiaofang Li, Qi‐Long Zhu, Xintao Wu

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  13. Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation

    Angewandte Chemie International Edition · 2018-03-30

    Yanlong Wang, Wei Liu, Zhuanling Bai, Tao Zheng, Mark A. Silver, Yuxiang Li, Yaxing Wang, Xia Wang, Juan Diwu, Zhifang Chai, Shuao Wang

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  14. Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation

    Angewandte Chemie · 2018-03-30

    Yanlong Wang, Wei Liu, Zhuanling Bai, Tao Zheng, Mark A. Silver, Yuxiang Li, Yaxing Wang, Xia Wang, Juan Diwu, Zhifang Chai, Shuao Wang

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  15. Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride

    Journal of Coordination Chemistry · 2018-05-18

    Fangyuan Wang, Lei Mei, Wei‐Qun Shi, Taiwei Chu

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  16. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  17. Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation

    Crystal Growth & Design · 2018-06-26

    Shuai Wang, Lei Mei, Jipan Yu, Kong‐Qiu Hu, Zhirong Liu, Zhifang Chai, Wei‐Qun Shi

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  18. Thorium Oxo‐Clusters as Building Blocks for Open Frameworks

    Chemistry - A European Journal · 2018-07-10

    Clément Falaise, Károly Kozma, May Nyman

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  19. A new set of metal–organic frameworks synthesised from diisophthalate-based, 2′-phosphorus-substituted m -terphenyl linker molecules

    Dalton Transactions · 2019-01-01

    Timo Stein, Frank Hoffmann, Michael Fröba

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  20. An untethered C 3v -symmetric triarylphosphine oxide locked by intermolecular hydrogen bonding

    Chemical Communications · 2019-01-01

    Timothy G. Carroll, Camden Hunt, Rachel Garwick, Guang Xin Wu, Roman Dobrovetsky, Gabriel Ménard

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  21. A novel microwave assisted reverse micelle fabrication route for Th (IV)‐MOFs as highly efficient adsorbent nanostructures with controllable structural properties to CO and CH4 adsorption: Design, and a systematic study

    Applied Organometallic Chemistry · 2019-02-12

    Ghasem Sargazi, Daryoush Afzali, Ali Mostafavi

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  22. Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials

    ACS Applied Nano Materials · 2019-03-15

    Peng Li, Xingjie Wang, Ken‐ichi Otake, Jiafei Lyu, Sylvia L. Hanna, Timur İslamoğlu, Omar K. Farha

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  23. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

    Chemistry - A European Journal · 2019-04-10

    Korey Prescott Carter, J. August Ridenour, Mark Kalaj, Christopher L. Cahill

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  24. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

    Inorganic Chemistry Frontiers · 2019-10-29

    Zi‐Jian Li, Shangyao Guo, Huangjie Lu, Yongjia Xu, Zenghui Yue, Linhong Weng, Xiaofeng Guo, Jian Hung Lin, Jian‐Qiang Wang

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  25. From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates

    European Journal of Inorganic Chemistry · 2020-06-19

    Aphra V. Murray, Nicole A. Vanagas, Jennifer N. Wacker, Jeffery A. Bertke, Karah E. Knope

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  26. Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework

    Journal of the American Chemical Society · 2020-07-17

    Sara E. Gilson, Melissa Fairley, Patrick Julien, Allen G. Oliver, Sylvia L. Hanna, Grace Arntz, Omar K. Farha, Jay A. LaVerne, Peter Carman Burns

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  27. Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes

    Chemistry - A European Journal · 2020-07-18

    Robert G. Surbella, Korey Prescott Carter, Trevor D. Lohrey, Dallas D. Reilly, Mark Kalaj, Bruce K. McNamara, Jon M. Schwantes, Rebecca J. Abergel

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  28. “Turn-on” fluorescent sensor for Th4+ in aqueous media based on a combination of PET-AIE effect

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2020-11-14

    Shibing Chen, Shengjie Jiang, Hongyu Guo, Fafu Yang

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  29. Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

    Chemical Science · 2021-01-01

    Corey R. Martin, Gabrielle A. Leith, Natalia B. Shustova

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  30. Two isomeric zeolite-like metal–organic frameworks with mechanically responsive luminescence emission and gas adsorption properties

    CrystEngComm · 2021-01-01

    Shuang Peng, Yan‐Jie Qi, Xin-Hao Li, Xin-Hao Li, Cai Sun, Lingyun Li, Xin-Xiong Li, Xin-Xiong Li, Shou‐Tian Zheng, Qichun Zhang

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  31. Interpenetration Control in Thorium Metal–Organic Frameworks: Structural Complexity toward Iodine Adsorption

    Inorganic Chemistry · 2021-03-19

    Yu Ju, Zi‐Jian Li, Huangjie Lu, Zhengyang Zhou, Yongxin Li, Xiaoling Wu, Xiaofeng Guo, Yuan Qian, Zhi‐Hui Zhang, Jian Hung Lin, Jian‐Qiang Wang, Ming‐Yang He

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  32. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  33. Structural and multi-functional properties of novel thorium complex bearing higher analogue of guanidine base

    Materials Chemistry and Physics · 2021-09-06

    A. Pushpaveni, S. Packiaraj, S. Poornima, Loganathan Kousalya, Subbiah Govindarajan

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  34. Elucidation of Thorium Redox-Active Ligand Complexes: Evidence for a Thorium-Tri(radical) Species

    Inorganic Chemistry · 2021-09-09

    D. M. Ramitha Y. P. Rupasinghe, Himanshu Gupta, Makayla R. Baxter, Robert F. Higgins, Mat­thias Zeller, Eric J. Schelter, Suzanne C. Bart

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  35. A review on chiral metal–organic frameworks: synthesis and asymmetric applications

    Nanoscale · 2022-01-01

    Mingxuan Ma, Jiahuan Chen, Hongyu Liu, Zhonghua Huang, Fuhong Huang, Quanliang Li, Yuan Xu

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  36. Understanding the role of flux, pressure and temperature on polymorphism in ThB 2 O 5

    Dalton Transactions · 2022-01-01

    Yucheng Hao, Gabriel L. Murphy, Philip Kegler, Yan Li, Piotr M. Kowalski, Simon Blouin, Yang Zhang, Shuao Wang, Lars Robben, Thorsten M. Gesing, Evgeny V. Alekseev

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  37. MOFs with 12-Coordinate 5f-Block Metal Centers

    Journal of the American Chemical Society · 2022-02-10

    Kai Lv, Christian Urbank, Michael Patzschke, Juliane März, Peter Kaden, Stephan Weiß, Moritz Schmidt

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  38. Efficient Separation of Trace SO2 from SO2/CO2/N2 Mixtures in a Th-Based MOF

    Inorganic Chemistry · 2022-07-20

    Wenhui Zhang, Wansheng Jia, Jie Qin, Lan Chen, Youyuan Ran, Rajamani Krishna, Li Wang, Feng Luo

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  39. Stabilization of Pu(IV) in PuBr4(OPCy3)2 and Comparisons with Structurally Similar ThX4(OPR3)2 (R = Cy, Ph) Molecules

    Inorganic Chemistry · 2023-10-24

    Cory J. Windorff, Conrad A. P. Goodwin, Joseph M. Sperling, Thomas E. Albrecht-Schönzart, Zhuanling Bai, William J. Evans, Zachary K. Huffman, Renaud Jeannin, Brian N. Long, David Paul Mills, Todd N. Poe, Joseph W. Ziller

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  40. A ciprofloxacin derived task specific ionic liquid as a highly selective extractant of thorium versus uranium

    Journal of Materials Chemistry A · 2024-01-01

    David Lledó, Guillermo Grindlay, H. Q. Nimal Gunaratne, Abel de Cózar, Ana Sirvent, Jose Miguel Sansano

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  41. Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials

    Journal of the American Chemical Society · 2024-06-29

    Kyoung Chul Park, Jaewoong Lim, Grace C. Thaggard, Natalia B. Shustova

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  42. Tripodal Tricarboxylic Acids on the Triphenylphosphine Oxide Platform

    Russian Journal of General Chemistry · 2025-02-01

    Т. В. Баулина, I. Yu. Kudryavtsev, Margarita P. Pasechnik, А. Г. Матвеева, Anna Vladimirovna Vologzhanina, Valery Kuzmich Brel

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  43. Metal–Organic Frameworks Formed from Self-Assembled Polynuclear Silver Halide Clusters

    ACS Materials Letters · 2025-12-29

    Rajashree Newar, Dipendu Mandal, Debobroto Sensharma, Madison R. Esposito, Seth M. Cohen

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  44. Phosphine-functionalized metal-organic frameworks: synthesis, structures and applications

    Inorganic Chemistry Communications · 2026-06-25

    Subham Sahoo, Peng Ren, Shasha Feng, Shunlin Zhang, Yuchen Qiao, X Y Yang

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  45. Reactivity of Bestmann’s Ylide, Ph3PCOO, with the Actinides: Observation of An–C Bond Insertion or κ-O Coordination

    Organometallics · 2026-08-13

    Gabriella S. Godinho, Qien Feng, Guang Wu, Trevor W. Hayton

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