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RESEARCH PAPER · Journal of the American Chemical Society · 2008

TOF-2: A Large 1D Channel Thorium Organic Framework

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TOF-2: A Large 1D Channel Thorium Organic FrameworkOriginalSynthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)53An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids42Morphology‐Selective Formation and Morphology‐Dependent Gas‐Adsorption Properties of Coordination Polymer Particles120Effect of Dehydration on the Aggregation Kinetics of Two Amyloid Peptides82Structural Investigation of Flexible 1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene Ligand in Keggin-Based Polyoxometalate Frameworks79Syntheses, Crystal Structures and Adsorption Properties of Ultramicroporous Coordination Polymers Constructed from Hexafluorosilicate Ions and Pyrazine119NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution270NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution37CAU-1 and CAU-2: New tubular alkali metal–organic framework materials, A3[C6H3(CO2)(CO2H0.5)(CO2H)]2 (A = K or Rb)31Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials113Fluorescent octahedron and rounded-octahedron coordination polymer particles (CPPs)19Solvent effect on the construction of two microporous yttrium–organic frameworks with high thermostability viain situ ligand hydrolysis45Heterogeneity Induced Effective Repulsion and Its Effects on Equilibrium Binding Fraction of a Divalent Receptor0Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands77Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions57Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions11Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48In[NC5H3(CO2)2](OH2)F: A new layered indium-organic framework material (NC5H3(CO2)2=2,6-pyridinedicarboxylate)3catena-Poly[thorium(IV)-tetrakis(μ2-3-carboxyadamantane-1-carboxylato)]: a quadruple helical strand driven by a synergy of coordination and hydrogen bonding9Advances in actinide solid-state and coordination chemistry37New alkali earth metal–organic frameworks with a very high thermal stability: synthesis, crystal structure, and characterization of AE[NC5H3(CO2)2] (AE = Ba or Sr)19Porous supramolecular compound based on paddle-wheel shaped copper(ii)–adenine dinuclear entities47Recent progress in actinide borate chemistry94Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands42From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium−Organic Framework, Ca[NC5H3(CO2)2](H2O)1.528From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt55Hydrothermal Synthesis and Structural Characterization of Organically Templated Uranyl Diphosphonate Compounds72Uranyl carboxyphosphonates that incorporate Cd(II)20Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability31Syntheses of Uranyl Diphosphonate Compounds Using Encapsulated Cations as Structure Directing Agents59Metal–Organic-Framework-Type 1D-Channel Open Network of a Tetravalent Uranium Trimesate56α,α′,α′′-Tris(hydroxyimino)-1,3,5-benzenetriacetonitrile: A three-fold symmetric, versatile and practical supramolecular building block65,10,15,20-tetra(4-pyridyl)porphyrinato zinc coordination polymeric particles with different shapes and luminescent properties29Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks57Bi[NC5H3(CO2)2](OH2)xF (x=1 and 2): New one-dimensional Bi-coordination materials—Reversible hydration and topotactic decomposition to α-Bi2O3163-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials76Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework176Barium uranyl diphosphonates16Solvothermal synthesis, crystal structure, and second-order nonlinear optical properties of a new noncentrosymmetric gallium-organic framework material, [N(C3H7)4]3Ga3[C6H3(CO2)3]48Nanomaterials and nanotechnologies in nuclear energy chemistry46Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials2950Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives46Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes3Metal–carboxylato–nucleobase systems: From supramolecular assemblies to 3D porous materials93A Robust Molecular Porous Material with High CO 2 Uptake and Selectivity264A Benzaldehyde Derivative as a Chelating Ligand: Helical Manganese(II) Coordination Polymers Assembling into a Porous Solid2Computational Studies of CO2 Sorption and Separation in an Ultramicroporous Metal–Organic Material46The crystal chemistry of uranium carboxylates394Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies16Three‐Dimensional Porous NbO‐Type Anionic Framework: Synthesis, Structure, Magnetic and Adsorption Properties2A molecular porous zirconium–organic material exhibiting highly selective CO 2 adsorption, high thermal stability, reversible hydration, facile ligand exchange and exclusive dimerization of phenylacetylene10MOFs of Uranium and the Actinides95Truncated trigonal prismatic tubular crystals consisting of a zeolite L-mimic metal–organic framework17Isostructural Synthesis of Porous Metal–Organic Nanotubes72A Robust Nanoporous Supramolecular Metal–Organic Framework Based on Ionic Hydrogen Bonds43A Robust Binary Supramolecular Organic Framework (SOF) with High CO2 Adsorption and Selectivity357A luminescent cadmium( ii ) metal–organic framework based on a triazolate–carboxylate ligand exhibiting selective gas adsorption and guest-dependent photoluminescence properties33Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments45Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides58Pb 3 [C 6 (CH 3 ) 3 (CO 2 ) 3 H 6 ] 2 [DMF] 3 : first layered Pb-Kemp's triacid complex9Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Thorium(IV) organic frameworks with aromatic polycarboxylate ligands11Insights into the new Th (IV) sulfate fluoride complex: Synthesis, crystal structures, and temperature dependent spectroscopic properties8Umbellate Distortions of the Uranyl Coordination Environment Result in a Stable and Porous Polycatenated Framework That Can Effectively Remove Cesium from Aqueous Solutions449Crystal growth, differential gas adsorption, high thermal stability, and reversible coordination of two new barium-organic frameworks, Ba(SBA)(DMF)4 and Ba2(BTEC)(H2O)10A Highly Stable Nanotubular MOF Rotator for Selective Adsorption of Benzene and Separation of Xylene Isomers103Supramolecular Metal–Organic Frameworks of s- and f-Block Metals: Impact of 1,8-Naphthalimide Functional Group42Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34First Cationic Uranyl–Organic Framework with Anion-Exchange Capabilities101Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores213Design and Synthesis of a Water‐Stable Anionic Uranium‐Based Metal–Organic Framework (MOF) with Ultra Large Pores54Recent Advances in Various Metal–Organic Channels for Photochemistry beyond Confined Spaces76Influence of the Amide Groups in the CO 2 /N 2 Selectivity of a Series of Isoreticular, Interpenetrated Metal–Organic Frameworks93A novel supramolecular magnesoborate framework with snowflake-like channels built by unprecedented huge B 69 cluster cages66Inorganic Synthesis of Actinides3Selective adsorption behaviour of carbon dioxide in OH-functionalized metal–organic framework materials9Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Two novel thorium organic frameworks constructed by bi- and tritopic ligands1A novel synthesis of a new thorium (IV) metal organic framework nanostructure with well controllable procedure through ultrasound assisted reverse micelle method86Multifaceted Modularity: A Key for Stepwise Building of Hierarchical Complexity in Actinide Metal–Organic Frameworks127A mesoporous cationic thorium-organic framework that rapidly traps anionic persistent organic pollutants409Synthèse et étude cristallochimique de carboxylates d'actinides tétravalents (Th, U, Np) : polymères de coordination et entités moléculaires à haute nucléarité0Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones11A supramolecular porous material comprising Fe( ii ) mesocates21Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Organosoluble tetravalent actinide di- and trifluorides2Construction of uranyl phosphonates from multifunctional zwitterionic ligands6Two novel 3D-MOFs (Ca-TATB and Co-HKUST): Synthesis, structure and characterization22Fine Tuning and Specific Binding Sites with a Porous Hydrogen-Bonded Metal-Complex Framework for Gas Selective Separations274Employing an Unsaturated Th 4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation152Employing an Unsaturated Th4+ Site in a Porous Thorium–Organic Framework for Kr/Xe Uptake and Separation32Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF81Preparation and characterization of single crystals of tetrakis(4-(5,5-dimethyl-2-phenyl-1,3-dioxan-2-yl)phenyl)germane1Selective Extraction of Thorium from Rare Earth Elements Using Wrinkled Mesoporous Carbon127A Zn(II)-based pillar-layered metal–organic framework: Synthesis, structure, and CO2 selective adsorption20Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90Hitherto unknown eight-connected frameworks formed from A 4 B 4 O 12 metal organophosphate heterocubanes7Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc) 2 followed by the formation of molecular poly-oxo cluster {U 14 } containing hemimellitate uranium( iv )14High Uptake of ReO 4 − and CO 2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th 48 Ni 6 ] Nanocage‐Based Metal–Organic Framework148High Uptake of ReO4− and CO2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th48Ni6] Nanocage‐Based Metal–Organic Framework21Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework44Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50Monomeric and Trimeric Thorium Chlorides Isolated from Acidic Aqueous Solution18Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34Highly Efficient and Selective Removal of Lead Ions from Aqueous Solutions by Conjugated Microporous Polymers with Functionalized Heterogeneous Pores32Porous Graphitic Biomass Carbons as Sustainable Adsorption and Controlled Release Carriers for Atrazine Fixation20Metal–organic tube or layered assembly: reversible sheet-to-tube transformation and adaptive recognition16A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture302Unprecedented Radiation Resistant Thorium–Binaphthol Metal–Organic Framework86Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Actinide Coordination Chemistry on Surfaces: Synthesis, Manipulation, and Properties of Thorium Bis(porphyrinato) Complexes17Crystal Structure Transformation in Hydrogen‐bonded Organic Frameworks via Ion Exchange16State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Mechanochemical synthesis of a robust cobalt-based metal–organic framework for adsorption separation methane from nitrogen37Recent advances in the applications of thorium-based metal–organic frameworks and molecular clusters50Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton18Hydrogen‐Bonded Metal–Nucleobase Frameworks for Efficient Separation of Xenon and Krypton89Hydrogen-Bonded Framework of a Cobalt(II) Complex Showing Superior Stability and Field-Induced Slow Magnetic Relaxation59A Noncovalent π‐Stacked Porous Organic Molecular Framework for Selective Separation of Aromatics and Cyclic Aliphatics42A Noncovalent π‐Stacked Porous Organic Molecular Framework for Selective Separation of Aromatics and Cyclic Aliphatics8Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Extremely Stable Thorium‐MOF Assembly of Tetraphenylethylene Derivative With Tunable AIE Property and Highly Selective Detection of Nitro Aromatic Compounds28Achieving High Photo/Thermocatalytic Product Selectivity and Conversion via Thorium Clusters with Switchable Functional Ligands87Exceptionally Water-Stable In(III)-Based Framework with Conjugated Rhombohedral Cavities for Efficiently Separating Humid Flue Gas8Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Experimental and theoretical exploration of nickel ion-implanted metal-organic frameworks (ZIF-67) as free-standing electrodes for hybrid supercapacitors15Integrating Metal Complex Units and Redox Sites into Thorium‐Based Metal–Organic Frameworks for Selective Photocatalytic Oxidation of Sulfides37Host-guest interactions between gaseous iodine and MOF materials : exploring dynamics and reactivity0Construction, structures, and magnetic studies of two cobalt( ii ) and nickel( ii ) coordination polymers displaying bex topology7Synthesis of Cuprous Organic Frameworks with Adjustable Pores as Membrane Materials for C3H6/C3H8 Separation19A customized zeolitic imidazolate framework enabling bionic preconcentration of ultralow CO23A robust pyrazolate metal–organic framework for integrated perfluorooctanoic acid concentration and degradation67Nanostructures and nuclear fuels1A zeolitic imidazolate framework with uncoordinated cyano groups in mixed matrix membranes for efficient propylene/propane separation14Achieving Dynamic Circularly Polarized Luminescence with 2D Hydrogen‐Bonded Organic Frameworks19

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  1. Synthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)

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  2. An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids

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  3. Morphology‐Selective Formation and Morphology‐Dependent Gas‐Adsorption Properties of Coordination Polymer Particles

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  4. Effect of Dehydration on the Aggregation Kinetics of Two Amyloid Peptides

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  5. Structural Investigation of Flexible 1,4-Bis(1,2,4-triazol-1-ylmethyl)benzene Ligand in Keggin-Based Polyoxometalate Frameworks

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  6. Syntheses, Crystal Structures and Adsorption Properties of Ultramicroporous Coordination Polymers Constructed from Hexafluorosilicate Ions and Pyrazine

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  7. NDTB‐1: A Supertetrahedral Cationic Framework That Removes TcO4− from Solution

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  9. CAU-1 and CAU-2: New tubular alkali metal–organic framework materials, A3[C6H3(CO2)(CO2H0.5)(CO2H)]2 (A = K or Rb)

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  10. Cubic and rhombohedral heterobimetallic networks constructed from uranium, transition metals, and phosphonoacetate: new methods for constructing porous materials

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  12. Solvent effect on the construction of two microporous yttrium–organic frameworks with high thermostability viain situ ligand hydrolysis

    Dalton Transactions · 2010-01-01

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  13. Heterogeneity Induced Effective Repulsion and Its Effects on Equilibrium Binding Fraction of a Divalent Receptor

    Bulletin of the Korean Chemical Society · 2010-02-20

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  14. Construction of Three‐Dimensional Uranyl–Organic Frameworks with Benzenetricarboxylate Ligands

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  15. Technetium‐99 MAS NMR Spectroscopy of a Cationic Framework Material that Traps TcO4− Ions

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  17. Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium

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  18. In[NC5H3(CO2)2](OH2)F: A new layered indium-organic framework material (NC5H3(CO2)2=2,6-pyridinedicarboxylate)

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  19. catena-Poly[thorium(IV)-tetrakis(μ2-3-carboxyadamantane-1-carboxylato)]: a quadruple helical strand driven by a synergy of coordination and hydrogen bonding

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  20. Advances in actinide solid-state and coordination chemistry

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  21. New alkali earth metal–organic frameworks with a very high thermal stability: synthesis, crystal structure, and characterization of AE[NC5H3(CO2)2] (AE = Ba or Sr)

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  22. Porous supramolecular compound based on paddle-wheel shaped copper(ii)–adenine dinuclear entities

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  23. Recent progress in actinide borate chemistry

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  24. Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands

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  25. From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium−Organic Framework, Ca[NC5H3(CO2)2](H2O)1.5

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  26. From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt

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  29. Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability

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  30. Syntheses of Uranyl Diphosphonate Compounds Using Encapsulated Cations as Structure Directing Agents

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  33. 5,10,15,20-tetra(4-pyridyl)porphyrinato zinc coordination polymeric particles with different shapes and luminescent properties

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  34. Chiral uranium phosphonates constructed from achiral units with three-dimensional frameworks

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  35. Bi[NC5H3(CO2)2](OH2)xF (x=1 and 2): New one-dimensional Bi-coordination materials—Reversible hydration and topotactic decomposition to α-Bi2O3

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  36. 3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

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  37. Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework

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  38. Barium uranyl diphosphonates

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  39. Solvothermal synthesis, crystal structure, and second-order nonlinear optical properties of a new noncentrosymmetric gallium-organic framework material, [N(C3H7)4]3Ga3[C6H3(CO2)3]4

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  40. Nanomaterials and nanotechnologies in nuclear energy chemistry

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  41. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

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  42. From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

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  43. Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials

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  44. Diamine Bis(phenolate) as Supporting Ligands in Organoactinide(IV) Chemistry. Synthesis, Structural Characterization, and Reactivity of Stable Dialkyl Derivatives

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  45. Towards a self-assembled honeycomb structure via diaminotriptycene metal complexes

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