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RESEARCH PAPER · Inorganic Chemistry · 2010

Comparison of Thorium(IV) and Uranium(VI) Carboxyphosphonates

Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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Comparison of Thorium(IV) and Uranium(VI) CarboxyphosphonatesOriginalSynthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium48Co3(2-OOCC6H4PO3)2(H2O)3·H2O: A layered metal phosphonate showing reversible dehydration–rehydration behavior and ferrimagnetism29One-dimensional uranium–organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate19Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands42From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt55Uranyl carboxyphosphonates that incorporate Cd(II)20Incorporation of Mn(II) and Fe(II) into Uranyl Carboxyphosphonates38Structures and luminescent properties of new uranyl-based hybrid materials56Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates69Layered zinc 4-phosphonoisophthalates pillared by flexible bis(imidazole) Co-ligands9Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions48Syntheses of Uranyl Diphosphonate Compounds Using Encapsulated Cations as Structure Directing Agents59Heterobimetallic Copper(II) Uranyl Carboxyphenylphosphonates67Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids50Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules77Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer127Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties37Thorium and uranium diphosphonates: Syntheses, structures, and spectroscopic properties32Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures418Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids15One-Dimensional Uranyl-2,2′-bipyridine Coordination Polymer with Cation–Cation Interactions: (UO2)2(2,2′-bpy)(CH3CO2)(O)(OH)44The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding40Mixed-solvothermal synthesis, structures, luminescent and surface photovoltage properties of four new transition metal diphosphonates with a 3D supramolecular structure17Layered Uranyl Coordination Polymers Rigidly Pillared by Diphosphonates36From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Correlations and Differences between Uranium(VI) Arsonates and Phosphonates25Zinc( ii ) and cadmium( ii ) carboxyphosphonates with a 3D pillared-layered structure: synthesis, crystal structures, high thermal stabilities and luminescent properties8Two different dimensional bbbm-based cobalt(II) coordination polymers tuned by benzenedicarboxylates: Assembly, structures and properties7A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(ii) and Cu(ii): synthesis, structural description and magnetic properties7Cobalt phosphonates based on 4-(ethoxycarbonyl)naphthalen-1-yl)phosphonic acid12Emission spectroscopy of uranium(iv) compounds: a combined synthetic, spectroscopic and computational study66Supramolecular networks formation in crystals of 3-carboxybenzylphosphonic acid, its complexes and salts: from coordination bonds to weak intermolecular interactions5Two novel lead(ii) carboxyphosphonates with a layered and a 3D framework structure: syntheses, crystal structures, reversible dehydration/hydration, and luminescence properties28A MnII5 tetragonal pyramid stabilized by p-tert-butylcalix[8]arene: Synthesis, structure and magnetic property9Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies75Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels33Hybrid Uranyl-Carboxyphosphonate Cage Clusters27Flexible Diphosphonic Acids for the Isolation of Uranyl Hybrids with Heterometallic UVI═O—ZnII Cation–Cation Interactions34Syntheses, crystal structures, surface photovoltage, luminescence and molecular recognition properties of zinc(ii) and iron(ii) carboxyphosphonates with 2D and 3D supramolecular structures14MOFs of Uranium and the Actinides95Synthesis, structures, surface photovoltage and luminescence properties of two new nickel( ii ) carboxyphosphonates with a 3D framework structure6Use of Charge-Assisted Hydrogen Bonding in the Supramolecular Assembly of Hybrid Uranyl Materials39Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands40Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence70Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers10Thiocyanate Complexes of Uranium in Multiple Oxidation States: A Combined Structural, Magnetic, Spectroscopic, Spectroelectrochemical, and Theoretical Study31Uranyl–Organic Hybrids Designed from Hydroxyphosphonate14Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments45Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Mixed-solvothermal synthesis, structures, surface photovoltage, luminescence and molecular recognition properties of three new transition metal phosphonates with 3D framework and supramolecular structures14Synthesis, structures, luminescent and molecular recognition properties of three new alkaline earth metal carboxyphosphonates with a 3D supramolecular structure5Rigid Phosphonic Acids as Building Blocks for Crystalline Hybrid Materials10Structural chemistry of uranium phosphonates143Molecular Metal Phosphonates220Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations25Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34Supramolecular Metal–Organic Frameworks of s- and f-Block Metals: Impact of 1,8-Naphthalimide Functional Group42Syntheses, structures and properties of group 12 element (Zn, Cd, Hg) coordination polymers with a mixed-functional phosphonate-biphenyl-carboxylate linker31Synthesis, structures, and photoluminescent properties of two uranium complexes constructed by a flexible zwitterion ligand18Charge-Assisted Hydrogen-Bonded Networks of NH4+ and [Co(NH3)6]3+ with the New Linker Anion of 4-Phosphono-Biphenyl-4′-Carboxylic Acid20Analysis of Hydrogen Bonds in Crystals2Inorganic Synthesis of Actinides3Th( iv ) and Ce( iv ) napthylsalophen sandwich complexes: characterization of unusual thorium fluorescence in solution and solid-state29Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39Two novel thorium organic frameworks constructed by bi- and tritopic ligands1Molecular and Crystal Structures of Uranyl Nitrate Coordination Polymers with Double-Headed 2-Pyrrolidone Derivatives19Conversion of lanthanide glutarate chlorides with interstitial THF into lanthanide glutarates with unprecedented topologies5Organosoluble tetravalent actinide di- and trifluorides2Structural Tuning and Sensitization of Uranyl Phosphonates by Incorporation of Countercations into the Framework16Tetranuclear oxido-bridged thorium( iv ) clusters obtained using tridentate Schiff bases18High Uptake of ReO 4 − and CO 2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th 48 Ni 6 ] Nanocage‐Based Metal–Organic Framework148High Uptake of ReO4− and CO2 Conversion by a Radiation‐Resistant Thorium–Nickle [Th48Ni6] Nanocage‐Based Metal–Organic Framework21The role of 1-ethyl-3-methylimidazolium diethyl phosphate ionic liquid in uranyl phosphate compounds7The presence of mixed-valent silver in the uranyl phenylenediphosphonate framework5Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)13An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers2

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  1. Synthesis, Structure, and Solid-State Transformation Studies of Phosphonoacetate Based Hybrid Compounds of Uranium and Thorium

    Inorganic Chemistry · 2010-07-27

    Padmini Ramaswamy, Ramanath Prabhu, Srinivasan Natarajan

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  2. Co3(2-OOCC6H4PO3)2(H2O)3·H2O: A layered metal phosphonate showing reversible dehydration–rehydration behavior and ferrimagnetism

    Dalton Transactions · 2011-01-01

    Pengfei Wang, Deng‐Ke Cao, Song‐Song Bao, Haojun Jin, Yizhi Li, Tianwei Wang, Li‐Min Zheng

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  3. One-dimensional uranium–organic coordination polymers: crystal and electronic structures of uranyl-diacetohydroxamate

    Dalton Transactions · 2011-01-01

    Philippe F. Weck, Cynthia-May S. Gong, Eunja Kim, P. Thuéry, Kenneth R. Czerwinski

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  4. Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands

    Inorganic Chemistry · 2011-01-20

    P. Thuéry

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  5. From Layered Structures to Cubic Frameworks: Expanding the Structural Diversity of Uranyl Carboxyphosphonates via the Incorporation of Cobalt

    Crystal Growth & Design · 2011-02-08

    A.N. Alsobrook, Brad G. Hauser, Joseph T. Hupp, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  6. Uranyl carboxyphosphonates that incorporate Cd(II)

    Journal of Solid State Chemistry · 2011-04-14

    A.N. Alsobrook, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  7. Incorporation of Mn(II) and Fe(II) into Uranyl Carboxyphosphonates

    Crystal Growth & Design · 2011-04-18

    A.N. Alsobrook, Evgeny V. Alekseev, Wulf Depmeier, Thomas E. Albrecht‐Schmitt

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  8. Structures and luminescent properties of new uranyl-based hybrid materials

    Solid State Sciences · 2011-04-22

    Rachel C. Severance, Shae Anne Vaughn, Mark D. Smith, Hans‐Conrad zur Loye

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  9. Layered and Three-Dimensional Framework Cesium and Barium Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-05-18

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  10. Layered zinc 4-phosphonoisophthalates pillared by flexible bis(imidazole) Co-ligands

    Inorganic Chemistry Communications · 2011-07-24

    Haojun Jin, Pengfei Wang, Cheng Yao, Li‐Min Zheng

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  11. Three-Dimensional Hybrid Framework Containing U2O13 Dimers Connected via Cation–Cation Interactions

    Inorganic Chemistry · 2011-08-04

    Rachel C. Severance, Mark D. Smith, Hans‐Conrad zur Loye

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  12. Syntheses of Uranyl Diphosphonate Compounds Using Encapsulated Cations as Structure Directing Agents

    Crystal Growth & Design · 2011-08-05

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  13. Heterobimetallic Copper(II) Uranyl Carboxyphenylphosphonates

    Crystal Growth & Design · 2011-08-30

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  14. Uranyl–organic one- and two-dimensional assemblies with 2,2′-bipyridine-3,3′-dicarboxylic, biphenyl-3,3′,4,4′-tetracarboxylic and bicyclo[2.2.2]oct-7-ene-2,3,5,6-tetracarboxylic acids

    CrystEngComm · 2011-10-10

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  15. Metal-Controlled Assembly of Uranyl Diphosphonates toward the Design of Functional Uranyl Nanotubules

    Inorganic Chemistry · 2011-11-03

    Pius O. Adelani, Thomas E. Albrecht‐Schmitt

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  16. Uranyl Sensitization of Samarium(III) Luminescence in a Two-Dimensional Coordination Polymer

    Inorganic Chemistry · 2011-12-15

    Karah E. Knope, Daniel T. de Lill, Clare E. Rowland, Paula M. Cantos, Ana de Bettencourt‐Dias, Christopher L. Cahill

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  17. Uranyl Heteropolyoxometalate: Synthesis, Structure, and Spectroscopic Properties

    Inorganic Chemistry · 2012-04-20

    Pius O. Adelani, Allen G. Oliver, Thomas E. Albrecht‐Schmitt

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  18. Thorium and uranium diphosphonates: Syntheses, structures, and spectroscopic properties

    Journal of Solid State Chemistry · 2012-05-02

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  19. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

    Crystal Growth & Design · 2012-08-02

    Hongyue Wu, Weiting Yang, Zhong‐Ming Sun

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  20. Uranyl Bearing Hybrid Materials: Synthesis, Speciation, and Solid-State Structures

    Chemical Reviews · 2012-08-10

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  21. Syntheses, structures, and fluorescent properties of two uranium coordination polymers with carboxylic acids

    Journal of Coordination Chemistry · 2012-08-24

    Jian-Ling Wang, Zhaoyan Deng, Shibo Duan, Yong‐Heng Xing

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  22. One-Dimensional Uranyl-2,2′-bipyridine Coordination Polymer with Cation–Cation Interactions: (UO2)2(2,2′-bpy)(CH3CO2)(O)(OH)

    Inorganic Chemistry · 2012-09-24

    Pius O. Adelani, Peter Carman Burns

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  23. The First Uranyl Arsonates Featuring Heterometallic Cation–Cation Interactions with UVI═O–ZnII Bonding

    Inorganic Chemistry · 2012-09-28

    Tao Tian, Weiting Yang, Qing‐Jiang Pan, Zhong‐Ming Sun

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  24. Mixed-solvothermal synthesis, structures, luminescent and surface photovoltage properties of four new transition metal diphosphonates with a 3D supramolecular structure

    New Journal of Chemistry · 2012-10-04

    Hui Tian, Yan‐Yu Zhu, Zhen‐Gang Sun, Fei Tong, Jiang Zhu, Wei Chu, Shou‐Hui Sun, Mingjing Zheng

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  25. Layered Uranyl Coordination Polymers Rigidly Pillared by Diphosphonates

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  26. From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

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    Weiting Yang, Hongyue Wu, Run-Xue Wang, Qing‐Jiang Pan, Zhong‐Ming Sun, Hongjie Zhang

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  27. Correlations and Differences between Uranium(VI) Arsonates and Phosphonates

    Inorganic Chemistry · 2012-10-25

    Pius O. Adelani, Laurent J. Jouffret, Jennifer E. S. Szymanowski, Peter Carman Burns

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  28. Zinc( ii ) and cadmium( ii ) carboxyphosphonates with a 3D pillared-layered structure: synthesis, crystal structures, high thermal stabilities and luminescent properties

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  29. Two different dimensional bbbm-based cobalt(II) coordination polymers tuned by benzenedicarboxylates: Assembly, structures and properties

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  30. A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(ii) and Cu(ii): synthesis, structural description and magnetic properties

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  31. Cobalt phosphonates based on 4-(ethoxycarbonyl)naphthalen-1-yl)phosphonic acid

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  32. Emission spectroscopy of uranium(iv) compounds: a combined synthetic, spectroscopic and computational study

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  33. Supramolecular networks formation in crystals of 3-carboxybenzylphosphonic acid, its complexes and salts: from coordination bonds to weak intermolecular interactions

    RSC Advances · 2013-01-01

    Danuta Dobrzyńska, Joanna Kubiak, Jan Janczak, Jerzy Zoń

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  34. Two novel lead(ii) carboxyphosphonates with a layered and a 3D framework structure: syntheses, crystal structures, reversible dehydration/hydration, and luminescence properties

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  35. A MnII5 tetragonal pyramid stabilized by p-tert-butylcalix[8]arene: Synthesis, structure and magnetic property

    Inorganic Chemistry Communications · 2013-01-08

    Shangchao Du, Hongshan Ke, Yanfeng Bi, Huaqiao Tan, Yang Yu, Jinkui Tang, Wuping Liao

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  36. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

    Inorganic Chemistry · 2013-02-21

    Weiting Yang, Tao Tian, Hongyue Wu, Qing‐Jiang Pan, Song Dang, Zhong‐Ming Sun

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  37. Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels

    Inorganic Chemistry · 2013-05-23

    Tao Tian, Weiting Yang, Hao Wang, Song Dang, Qing‐Jiang Pan, Zhong‐Ming Sun

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  38. Hybrid Uranyl-Carboxyphosphonate Cage Clusters

    Inorganic Chemistry · 2013-06-13

    Pius O. Adelani, Michael P. Ozga, Christine M. Wallace, Jie Qiu, Jennifer E. S. Szymanowski, Ginger E. Sigmon, Peter Carman Burns

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  39. Flexible Diphosphonic Acids for the Isolation of Uranyl Hybrids with Heterometallic UVI═O—ZnII Cation–Cation Interactions

    Inorganic Chemistry · 2013-07-09

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  40. Syntheses, crystal structures, surface photovoltage, luminescence and molecular recognition properties of zinc(ii) and iron(ii) carboxyphosphonates with 2D and 3D supramolecular structures

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  41. MOFs of Uranium and the Actinides

    Structure and bonding · 2014-01-01

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  42. Synthesis, structures, surface photovoltage and luminescence properties of two new nickel( ii ) carboxyphosphonates with a 3D framework structure

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  43. Use of Charge-Assisted Hydrogen Bonding in the Supramolecular Assembly of Hybrid Uranyl Materials

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  44. Structural Variation within Heterometallic Uranyl Hybrids Based on Flexible Alkyldiphosphonate Ligands

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  45. Postsynthetic Rearrangement/Metalation as a Route to Bimetallic Uranyl Coordination Polymers: Syntheses, Structures, and Luminescence

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  46. Synthesis and characterization of 1-D uranyl thiodigycolate coordination polymers

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  47. Thiocyanate Complexes of Uranium in Multiple Oxidation States: A Combined Structural, Magnetic, Spectroscopic, Spectroelectrochemical, and Theoretical Study

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  48. Uranyl–Organic Hybrids Designed from Hydroxyphosphonate

    European Journal of Inorganic Chemistry · 2014-12-09

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  49. Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments

    Dalton Transactions · 2015-01-01

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  50. Hybrid Materials of the f-Elements Part I

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