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RESEARCH PAPER · Inorganic Chemistry · 2012

3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic Materials

Hongyue Wu, Run-Xue Wang, Weiting Yang, Jinlei Chen, Zhong‐Ming Sun, Jun Li, Hongjie Zhang

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3-Fold-Interpenetrated Uranium–Organic Frameworks: New Strategy for Rationally Constructing Three-Dimensional Uranyl Organic MaterialsOriginalHighly selective acetone fluorescent sensors based on microporous Cd(ii) metal–organic frameworks148Solvents control over the degree of interpenetration in metal-organic frameworks and their high sensitivities for detecting nitrobenzene at ppm level178Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers82Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers92Solvent-Controlled Syntheses, Structure, and Magnetic Properties of Trinuclear Mn(II)-Based Metal–Organic Frameworks41From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange82Construction of Cu(ii) coordination polymers based on semi-rigid tetrahedral pyridine ligands14Construction of porous Mn(ii)-based metal–organic frameworks by flexible hexacarboxylic acid and rigid coligands29Two new uranyl fluoride complexes with UVIO–alkali (Na, Cs) interactions: Experimental and theoretical studies9Mono- and dinuclear uranyl(VI) complexes with chiral Schiff base ligand30Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O31Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies75Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates18Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels33A series of Zn(II) coordination polymers derived from dicarboxylate acids and flexible imidazole-based ligands: Syntheses, crystal structures and photoluminescent properties23The crystal chemistry of uranium carboxylates394Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids70Isolation of a series of uranium organophosphinates11MOFs of Uranium and the Actinides95Promising density functional theory methods for predicting the structures of uranyl complexes8Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent77Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules60Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers18A Family of UO22+–5-Nitro-1,3-dicarboxylate Hybrid Materials: Structural Variation As a Function of pH and Structure Directing Species20Photocatalytic Application of 4f–5f Inorganic–Organic Frameworks: Influence of Lanthanide Contraction on the Structure and Functional Properties of a Series of Uranyl–Lanthanide Complexes34Syntheses, Structures, Luminescence, and Photocatalytic Properties of a Series of Uranyl Coordination Polymers46UO 2 2+ -amino hybrid materials: structural variation and photocatalysis properties29A family of 3D UO 2 2+ –5-X-1,3-dicarboxylate (X = –H, –NO 2 , –NH 2 , –OH) hybrid materials: structural relevance with variation of substituent groups and photochemical properties29A family of uranyl-aromatic dicarboxylate (pht-, ipa-, tpa-) framework hybrid materials: photoluminescence, surface photovoltage and dye adsorption31Hybrid Materials of the f-Elements Part I5Hybrid Materials of the f-Elements Part II5Two novel uranyl complexes of a semi-rigid aromatic tetracarboxylic acid supported by an organic base as an auxiliary ligand or a templating agent: an experimental and theoretical exploration16New Three-Fold Interpenetrated Uranyl Organic Framework Constructed by Terephthalic Acid and Imidazole Derivative38A Series of Multifunctional Metal–Organic Frameworks Showing Excellent Luminescent Sensing, Sensitization, and Adsorbent Abilities235Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks78Multifunctional Uranyl Hybrid Materials: Structural Diversities as a Function of pH, Luminescence with Potential Nitrobenzene Sensing, and Photoelectric Behavior as p-type Semiconductors56Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework52Supramolecular Metal–Organic Frameworks of s- and f-Block Metals: Impact of 1,8-Naphthalimide Functional Group42Layered and three-dimensional uranyl–organic assemblies with 4,4′-oxidiphthalic acid4A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption17A robust indium–porphyrin framework for CO 2 capture and chemical transformation34Counter-ion control of structure in uranyl ion complexes with 2,5-thiophenedicarboxylate39From Helicates to Borromean Links: Chain Length Effect in Uranyl Ion Complexes of Aliphatic α,ω-Dicarboxylates21UO22+-polycarboxylate heterometallic complexes: structure, spectra, and photocatalytic properties12Counterion-Induced Variations in the Dimensionality and Topology of Uranyl Pimelate Complexes41Entangled Uranyl Organic Frameworks with (10,3)-b Topology and Polythreading Network: Structure, Luminescence, and Computational Investigation43Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework31Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption64Exploring New Assembly Modes of Uranyl Terephthalate: Templated Syntheses and Structural Regulation of a Series of Rare 2D → 3D Polycatenated Frameworks39Supramolecular Host–Guest Inclusion for Distinguishing Cucurbit[7]uril‐Based Pseudorotaxanes from Small‐Molecule Ligands in Coordination Assembly with a Uranyl Center35Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Luminescent metal–organic frameworks and coordination polymers as alternative phosphors for energy efficient lighting devices218Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)11Structural Consequences of 1,4-Cyclohexanedicarboxylate Cis/Trans Isomerism in Uranyl Ion Complexes: From Molecular Species to 2D and 3D Entangled Nets67Novel Viologen Derivative Based Uranyl Coordination Polymers Featuring Photochromic Behaviors61Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Highly selective luminescent sensor for CCl 4 vapor and pollutional anions/cations based on a multi-responsive MOF31An Anionic Uranium-Based Metal–Organic Framework with Ultralarge Nanocages for Selective Dye Adsorption67Ordered Entanglement in Actinide-Organic Coordination Polymers40Bimetallic Uranyl Organic Frameworks Supported by Transition-Metal-Ion-Based Metalloligand Motifs: Synthesis, Structure Diversity, and Luminescence Properties48In situ nitroso formation induced structural diversity of uranyl coordination polymers21Metal‐Carboxyl Helical Chain Secondary Units Supported Ion‐Exchangeable Anionic Uranyl–Organic Framework15Structural Diversity of Bipyridinium-Based Uranyl Coordination Polymers: Synthesis, Characterization, and Ion-Exchange Application46A series of uranium-organic frameworks: Crucial role of the protonation ability of auxiliary ligands15Regulation of the Degree of Interpenetration in Metal–Organic Frameworks49Counterion-Controlled Formation of Layered Honeycomb and Polythreading Uranyl Networks and the Highly Sensitive and Selective Detection of Fe3+ in Aqueous Media14Rational Design of a Uranyl Metal–Organic Framework for the Capture and Colorimetric Detection of Organic Dyes22Multifunctional Inorganic‐Organic U‐MOF Materials with Nitrogen Heterocyclic Carboxylate: Synthesis, Structure and Properties11Metal–organic frameworks based on multicarboxylate linkers284Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands173D Uranyl Organic Frameworks Supported by Rigid Octadentate Carboxylate Ligand: Synthesis, Structure Diversity, and Luminescence Properties8The construct of a novel threefold interpenetrating uranium-organic framework as a sensor for detecting Ru3+1Structural Design of Zinc-Directed Heterometallic Uranyl Organic Frameworks: Multifunction Detection of Cr 2 O 7 2– and Metamitron Contaminants from Water12Uranyl-organic framework: From structure design to cutting-edge applications1

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  1. Highly selective acetone fluorescent sensors based on microporous Cd(ii) metal–organic frameworks

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  2. Solvents control over the degree of interpenetration in metal-organic frameworks and their high sensitivities for detecting nitrobenzene at ppm level

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  3. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

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  4. Six-Fold Coordinated Uranyl Cations in Extended Coordination Polymers

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  5. Series of Mixed Uranyl–Lanthanide (Ce, Nd) Organic Coordination Polymers with Aromatic Polycarboxylates Linkers

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  6. Solvent-Controlled Syntheses, Structure, and Magnetic Properties of Trinuclear Mn(II)-Based Metal–Organic Frameworks

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  7. From 1D Chain to 3D Framework Uranyl Diphosphonates: Syntheses, Crystal Structures, and Selective Ion Exchange

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  8. Construction of Cu(ii) coordination polymers based on semi-rigid tetrahedral pyridine ligands

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  9. Construction of porous Mn(ii)-based metal–organic frameworks by flexible hexacarboxylic acid and rigid coligands

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  10. Two new uranyl fluoride complexes with UVIO–alkali (Na, Cs) interactions: Experimental and theoretical studies

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  11. Mono- and dinuclear uranyl(VI) complexes with chiral Schiff base ligand

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  12. Synthesis, Structural Characterization, and Dehydration Analysis of Uranyl Zinc Mellitate, (UO2)Zn(H2O)4(H2mel)·2H2O

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  13. Syntheses and Structures of a Series of Uranyl Phosphonates and Sulfonates: An Insight into Their Correlations and Discrepancies

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  14. Syntheses, structures and luminescent properties of two organic templated uranyl phosphonates

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  15. Syntheses and Structures of Uranyl Ethylenediphosphonates: From Layers to Elliptical Nanochannels

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  16. A series of Zn(II) coordination polymers derived from dicarboxylate acids and flexible imidazole-based ligands: Syntheses, crystal structures and photoluminescent properties

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  17. The crystal chemistry of uranium carboxylates

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  18. Synthesis, Structures, and Properties of Uranyl Hybrids Constructed by a Variety of Mono- and Polycarboxylic Acids

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  19. Isolation of a series of uranium organophosphinates

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  20. MOFs of Uranium and the Actinides

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  21. Promising density functional theory methods for predicting the structures of uranyl complexes

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  22. Uranyl–Organic Frameworks with Polycarboxylates: Unusual Effects of a Coordinating Solvent

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  23. Crystal Chemistry of Uranyl Carboxylate Coordination Networks Obtained in the Presence of Organic Amine Molecules

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  24. Room temperature crystallization of trichlorodioxouranate [UO2Cl3(L)] species in molecular assemblies involving aliphatic dicarboxylate linkers

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  36. Structural Variations in the Uranyl/4,4′-Biphenyldicarboxylate System. Rare Examples of 2D → 3D Polycatenated Uranyl–Organic Networks

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  38. Silver Ion-Mediated Heterometallic Three-Fold Interpenetrating Uranyl–Organic Framework

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  41. A family of uranium–carboxylic acid hybrid materials: synthesis, structure and mixed-dye selective adsorption

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  48. Novel Uranyl Coordination Polymers Based on Quinoline-Containing Dicarboxylate by Altering Auxiliary Ligands: From 1D Chain to 3D Framework

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  49. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

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  50. Solvent‐Dependent Synthesis of Porous Anionic Uranyl–Organic Frameworks Featuring a Highly Symmetrical (3,4)‐Connected ctn or bor Topology for Selective Dye Adsorption

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