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RESEARCH PAPER · Dalton Transactions · 2008

Synthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)

Kang Min Ok, Dermot M. O'Hare

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Synthesis, structure, and characterization of a new thorium–organic framework material, Th3F5[(C10H14)(CH2CO2)2]3(NO3)OriginalCAU-1 and CAU-2: New tubular alkali metal–organic framework materials, A3[C6H3(CO2)(CO2H0.5)(CO2H)]2 (A = K or Rb)31Structural diversity in a series of metal–organic frameworks (MOFs) composed of divalent transition metals, 4,4′-bipyridine and a flexible carboxylic acid48Synthesis, structural diversity and fluorescent characterisation of a series of d10 metal–organic frameworks (MOFs): reaction conditions, secondary ligand and metal effects78Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands42From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium−Organic Framework, Ca[NC5H3(CO2)2](H2O)1.528A Case Study of ZnII-bmb Meso-Helical Coordination Polymers upon the Spacer Angles and Lengths of Dicarboxylate Coligands102Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability31Three-Dimensional Cd(II) Coordination Polymers Based on Semirigid Bis(Methylbenzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties147Thorium(IV) Molecular Clusters with a Hexanuclear Th Core154Poly[(μ4-adamantane-1,3-dicarboxylato-κ5O1:O1′:O3,O3′:O3′)(μ3-adamantane-1,3-dicarboxylato-κ5O1,O1′:O3,O3′:O3′)dimagnesium]: a layered coordination polymer4Structure and stability range of a hexanuclear Th(iv)–glycine complex83Syntheses, Structures, and Photoluminescences of Four Cd(II) Coordination Architectures Based on 1-(4-Pyridylmethyl)-2-methylimidazole and Aromatic Carboxylates: From One-Dimensional Chain to Three-Dimensional Coordination Architecture49Solvothermal synthesis, crystal structure, and second-order nonlinear optical properties of a new noncentrosymmetric gallium-organic framework material, [N(C3H7)4]3Ga3[C6H3(CO2)3]48Nanomaterials and nanotechnologies in nuclear energy chemistry46Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures46A series of 2D coordination complexes constructed from a flexible bis(methylbenzimidazole) ligand and different dicarboxylates20Structure and Magnetic Behavior of CuII MOFs Supported by 1,2,4‐Triazolyl‐Bifunctionalized Adamantane Scaffold28Functionalized Adamantane Tectons Used in the Design of Mixed-Ligand Copper(II) 1,2,4-Triazolyl/Carboxylate Metal–Organic Frameworks62Identification of hexanuclear Actinide(IV) carboxylates with Thorium, Uranium and Neptunium by EXAFS spectroscopy15Construction of four coordination polymers with helical character based on a flexible bis(triazole) derivative and dicarboxylate coligands8Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes with a non-coplanar dicarboxylate26Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies16MOFs of Uranium and the Actinides95Structural variability, topological analysis and photocatalytic properties of neoteric Cd( ii ) coordination polymers based on semirigid bis(thiazolylbenzimidazole) and different types of carboxylic acid linkers82Three Cd(II) coordination polymers based on rigid 2,6-bis(3-(pyrid-3-yl)-1,2,4-triazolyl)pyridine ligand: Syntheses, crystal structures, and photocatalytic properties8Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments45Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster41Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate33Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System143Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology34Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers34A Hydrophobic Metal–Organic Framework Based on Cubane‐Type [Co 4 (μ 3 ‐F) 3 (μ 3 ‐SO 4 )] 3+ Clusters for Gas Storage and Adsorption Selectivity of Benzene over Cyclohexane48Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium34Two novel thorium organic frameworks constructed by bi- and tritopic ligands1Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Structural diversity, single-crystal to single-crystal transformation and photocatalytic properties of Cu(II)-metal-organic frameworks based on 1,4-phenylenedipropionic acid14Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)11Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones11Structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid13Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF81Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework44Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials40A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability501,3‐Adamantanedicarboxylate and 1,3‐Adamantanediacetate as Uranyl Ion Linkers: Effect of Counterions, Solvents and Differences in Flexibility11Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands34From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates2Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene10An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Synthesis and structure of metal-TCPE (metal = Th, Ce) metal-organic frameworks based on 1,2,4,5-tetrakis(4-carboxyphenyl) ethylene3Unveiling the Structure–Modulator Relationships in Thorium-Based Metal–Organic Framework Crystallization18Fluoride Clusterfullerenes: Tuning Metal–Metal Bonding and Magnetic Properties via Single Fluorine Atom Doping14

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  1. CAU-1 and CAU-2: New tubular alkali metal–organic framework materials, A3[C6H3(CO2)(CO2H0.5)(CO2H)]2 (A = K or Rb)

    CrystEngComm · 2010-01-01

    Min Kyung Kim, Vinna Jo, Dong Woo Lee, Il‐Wun Shim, Kang Min Ok

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  2. Structural diversity in a series of metal–organic frameworks (MOFs) composed of divalent transition metals, 4,4′-bipyridine and a flexible carboxylic acid

    CrystEngComm · 2010-01-01

    Pradip Pachfule, Tamas Panda, Chandan Dey, Rahul Banerjee

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  3. Synthesis, structural diversity and fluorescent characterisation of a series of d10 metal–organic frameworks (MOFs): reaction conditions, secondary ligand and metal effects

    Dalton Transactions · 2011-01-01

    Wei‐Hong Zhang, Zhe Dong, Yaoyu Wang, Lei Hou, Jun Cheng Jin, Wen Huan Huang, Qi Shi

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  4. Solid State Structure of Thorium(IV) Complexes with Common Aminopolycarboxylate Ligands

    Inorganic Chemistry · 2011-01-20

    P. Thuéry

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  5. From Pincers to Steps: Synthesis, Structure, Characterization, and Transformation of a New Helical Calcium−Organic Framework, Ca[NC5H3(CO2)2](H2O)1.5

    Crystal Growth & Design · 2011-01-27

    Min Kyung Kim, Kyung-Lyul Bae, Kang Min Ok

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  6. A Case Study of ZnII-bmb Meso-Helical Coordination Polymers upon the Spacer Angles and Lengths of Dicarboxylate Coligands

    Crystal Growth & Design · 2011-03-25

    Chunying Xu, Qianqian Guo, Xianjuan Wang, Hongwei Hou, Yaoting Fan

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  7. Sr2[C6H3(CO2)3(NO3)]·DMF: One-Dimensional Nano-Channel in a New Non-Centrosymmetric Strontium–Organic Framework with High Thermal Stability

    Crystal Growth & Design · 2011-05-18

    Dong Woo Lee, Vinna Jo, Kang Min Ok

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  8. Three-Dimensional Cd(II) Coordination Polymers Based on Semirigid Bis(Methylbenzimidazole) and Aromatic Polycarboxylates: Syntheses, Topological Structures and Photoluminescent Properties

    Crystal Growth & Design · 2011-08-29

    Chunying Xu, Linke Li, Yinping Wang, Qianqian Guo, Xianjuan Wang, Hongwei Hou, Yaoting Fan

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  9. Thorium(IV) Molecular Clusters with a Hexanuclear Th Core

    Inorganic Chemistry · 2011-09-08

    Karah E. Knope, Richard E. Wilson, Monica Vasiliu, David A. Dixon, L. Soderholm

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  10. Poly[(μ4-adamantane-1,3-dicarboxylato-κ5O1:O1′:O3,O3′:O3′)(μ3-adamantane-1,3-dicarboxylato-κ5O1,O1′:O3,O3′:O3′)dimagnesium]: a layered coordination polymer

    Acta Crystallographica Section C Crystal Structure Communications · 2011-10-05

    Anna M. Płonka, Debasis Banerjee, John B. Parise

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  11. Structure and stability range of a hexanuclear Th(iv)–glycine complex

    Dalton Transactions · 2012-01-01

    Christoph Hennig, Shinobu Takao, Koichiro Takao, Stephan Weiß, Werner Kraus, Franziska Emmerling, Andreas C. Scheinost

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  12. Syntheses, Structures, and Photoluminescences of Four Cd(II) Coordination Architectures Based on 1-(4-Pyridylmethyl)-2-methylimidazole and Aromatic Carboxylates: From One-Dimensional Chain to Three-Dimensional Coordination Architecture

    Crystal Growth & Design · 2012-03-05

    Fu-Jing Liu, Hong-Jun Hao, Chengjie Sun, Xiaohang Lin, Hao-Peng Chen, Rong‐Bin Huang, Lan‐Sun Zheng

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  13. Solvothermal synthesis, crystal structure, and second-order nonlinear optical properties of a new noncentrosymmetric gallium-organic framework material, [N(C3H7)4]3Ga3[C6H3(CO2)3]4

    Journal of Solid State Chemistry · 2012-06-09

    Dong Woo Lee, Vinna Jo, Kang Min Ok

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  14. Nanomaterials and nanotechnologies in nuclear energy chemistry

    Radiochimica Acta · 2012-07-30

    Wei‐Qun Shi, L.-Y. Yuan, Zhaoxi Li, Jian‐Hui Lan, Yu Zhao, Zhifang Chai

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  15. Tailor-Made Zinc Uranyl Diphosphonates from Layered to Framework Structures

    Crystal Growth & Design · 2012-08-02

    Hongyue Wu, Weiting Yang, Zhong‐Ming Sun

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  16. A series of 2D coordination complexes constructed from a flexible bis(methylbenzimidazole) ligand and different dicarboxylates

    Inorganica Chimica Acta · 2012-08-13

    Lu Liu, Yanhua Liu, Gang Han, Dongqing Wu, Hongwei Hou, Yaoting Fan

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  17. Structure and Magnetic Behavior of CuII MOFs Supported by 1,2,4‐Triazolyl‐Bifunctionalized Adamantane Scaffold

    European Journal of Inorganic Chemistry · 2012-10-15

    Ganna A. Senchyk, A.B. Lysenko, Eduard B. Rusanov, Alexander N. Chernega, Julia Jezierska, K.V. Domasevitch, Andrew Ozarowski

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  18. Functionalized Adamantane Tectons Used in the Design of Mixed-Ligand Copper(II) 1,2,4-Triazolyl/Carboxylate Metal–Organic Frameworks

    Inorganic Chemistry · 2013-01-07

    Ganna A. Senchyk, A.B. Lysenko, Harald Krautscheid, Eduard B. Rusanov, Alexander N. Chernega, Karl W. Krämer, Shi‐Xia Liu, Silvio Decurtins, K.V. Domasevitch

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  19. Identification of hexanuclear Actinide(IV) carboxylates with Thorium, Uranium and Neptunium by EXAFS spectroscopy

    Journal of Physics Conference Series · 2013-04-22

    Christoph Hennig, Shinobu Takao, Koichiro Takao, Stephan Weiß, Werner Kraus, Franziska Emmerling, Michel Meyer, Andreas C. Scheinost

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  20. Construction of four coordination polymers with helical character based on a flexible bis(triazole) derivative and dicarboxylate coligands

    Inorganica Chimica Acta · 2013-06-20

    Dongqing Wu, Wei Meng, Lin Zhang, Lu Liu, Hongwei Hou, Yaoting Fan

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  21. Coligand-regulated assembly, fluorescence, and magnetic properties of Co(II) and Cd(II) complexes with a non-coplanar dicarboxylate

    Journal of Solid State Chemistry · 2013-08-12

    Ling-Yun Xin, Guang‐Zhen Liu, Lu‐Fang Ma, Li‐Ya Wang

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  22. Isolation of thorium benzoate polytypes with discrete ThO8 square antiprismatic units involved in chain-like assemblies

    Inorganic Chemistry Communications · 2013-11-04

    Clément Falaise, Christophe Volkringer, Thierry Loiseau

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  23. MOFs of Uranium and the Actinides

    Structure and bonding · 2014-01-01

    Juan Su, Jiesheng Chen

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  24. Structural variability, topological analysis and photocatalytic properties of neoteric Cd( ii ) coordination polymers based on semirigid bis(thiazolylbenzimidazole) and different types of carboxylic acid linkers

    Dalton Transactions · 2014-01-01

    Lu Liu, Jie Ding, Ming Li, Xiaofeng Lv, Jie Wu, Hongwei Hou, Yaoting Fan

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  25. Three Cd(II) coordination polymers based on rigid 2,6-bis(3-(pyrid-3-yl)-1,2,4-triazolyl)pyridine ligand: Syntheses, crystal structures, and photocatalytic properties

    Polyhedron · 2014-06-18

    Lin Zhang, Lu Liu, Ming Li, Chao Ran Huang, Hong Liang Xu, Hongwei Hou, Yaoting Fan

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  26. Centrosymmetric and chiral porous thorium organic frameworks exhibiting uncommon thorium coordination environments

    Dalton Transactions · 2015-01-01

    Yuxiang Li, Zhehui Weng, Yanlong Wang, Lanhua Chen, Daopeng Sheng, Yunhai Liu, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  27. Double-walled pyr topology networks from a novel fluoride-bridged heptanuclear metal cluster

    Chemical Science · 2015-01-01

    Kai‐Jie Chen, John J. Perry, Hayley S. Scott, Qing‐Yuan Yang, Michael John Zaworotko

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  28. Solvent effects in solvo-hydrothermal synthesis of uranyl ion complexes with 1,3-adamantanediacetate

    CrystEngComm · 2015-01-01

    P. Thuéry, Jack McB. Harrowfield

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  29. Thorium Terephthalates Coordination Polymers Synthesized in Solvothermal DMF/H2O System

    Inorganic Chemistry · 2015-02-10

    Clément Falaise, Jean-Sébastien Charles, Christophe Volkringer, Thierry Loiseau

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  30. Surprising coordination for low-valent actinides resembling uranyl( vi ) in thorium( iv ) organic hybrid layered and framework structures based on a graphene-like (6,3) sheet topology

    Dalton Transactions · 2015-12-08

    Yuxiang Li, Zhehui Weng, Yanlong Wang, Lanhua Chen, Daopeng Sheng, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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  31. Synthesis and Crystal Structure Characterization of Thorium Trimesate Coordination Polymers

    Crystal Growth & Design · 2016-01-15

    Nicolas P. Martin, Christophe Volkringer, Clément Falaise, Natacha Henry, Thierry Loiseau

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  32. A Hydrophobic Metal–Organic Framework Based on Cubane‐Type [Co 4 (μ 3 ‐F) 3 (μ 3 ‐SO 4 )] 3+ Clusters for Gas Storage and Adsorption Selectivity of Benzene over Cyclohexane

    Chemistry - A European Journal · 2016-07-04

    Lei Zhang, Wenbin Yang, Xiao‐Yuan Wu, Can‐Zhong Lu, Wenzhe Chen

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  33. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

    Journal of Solid State Chemistry · 2016-07-28

    Lingling Liang, Ronglan Zhang, Jianshe Zhao, Chiyang Liu, Ng Seik Weng

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  34. Synthesis of Coordination Polymers of Tetravalent Actinides (Uranium and Neptunium) with a Phthalate or Mellitate Ligand in an Aqueous Medium

    Inorganic Chemistry · 2017-02-16

    Nicolas P. Martin, Juliane März, Christophe Volkringer, Natacha Henry, Christoph Hennig, Atsushi Ikeda‐Ohno, Thierry Loiseau

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  35. Two novel thorium organic frameworks constructed by bi- and tritopic ligands

    Radiochimica Acta · 2017-02-23

    Fei Chen, Cui Wang, Jian‐Hui Lan, Yanqin Ji, Zhifang Chai

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  36. Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters

    Crystal Growth & Design · 2017-08-31

    Ralph A. Zehnder, James M. Boncella, Justin N. Cross, Stosh A. Kozimor, Marisa J. Monreal, Henry S. La Pierre, Brian L. Scott, Aaron M. Tondreau, Mat­thias Zeller

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  37. Structural diversity, single-crystal to single-crystal transformation and photocatalytic properties of Cu(II)-metal-organic frameworks based on 1,4-phenylenedipropionic acid

    Inorganica Chimica Acta · 2017-08-31

    Surapoj Sanram, Jaursup Boonmak, Sujittra Youngme

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  38. Stress compensation in an extended series of lanthanide 2-sulfonatoterephthalates [Ln(TPSO3)(H2O)2]n (Ln = Ce − Lu, except Pm)

    Inorganica Chimica Acta · 2017-10-11

    Adrian Hernandez, James Jenkins, Harry Maslen, Mat­thias Zeller, Garrett Horner, Christian Dempsey, Jeffrey Urteaga, Charles Dunlap, Ralph A. Zehnder

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  39. Molecular and polymeric uranyl and thorium hybrid materials featuring methyl substituted pyrazole dicarboxylates and heterocyclic 1,3-diketones

    Solid State Sciences · 2017-12-08

    Korey Prescott Carter, Andrew T. Kerr, Il'ya Viktorovich Taydakov, Christopher L. Cahill

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  40. Structure variation and luminescence of 3D, 2D and 1D lanthanide coordination polymers with 1,3-adamantanediacetic acid

    Inorganica Chimica Acta · 2018-06-18

    Zhi-Peng Zhao, Kai Zheng, Haoran Li, Chenghui Zeng, Shengliang Zhong, Seik Weng Ng, Yanqiong Zheng, Yun Chen

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  41. Autoluminescent Metal–Organic Frameworks (MOFs): Self-Photoemission of a Highly Stable Thorium MOF

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  42. Stabilization of an Unprecedented Hexanuclear Secondary Building Unit in a Thorium-Based Metal–Organic Framework

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  43. Synthetic Control of Thorium Polyoxo-Clusters in Metal–Organic Frameworks toward New Thorium-Based Materials

    ACS Applied Nano Materials · 2019-03-15

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  44. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

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  45. 1,3‐Adamantanedicarboxylate and 1,3‐Adamantanediacetate as Uranyl Ion Linkers: Effect of Counterions, Solvents and Differences in Flexibility

    European Journal of Inorganic Chemistry · 2019-10-08

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  46. Unexpected structural complexity of thorium coordination polymers and polyoxo cluster built from simple formate ligands

    Inorganic Chemistry Frontiers · 2019-10-29

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  47. From Isolated Molecular Complexes to Extended Networks: Synthesis and Characterization of Thorium Furanmono‐ and Dicarboxylates

    European Journal of Inorganic Chemistry · 2020-06-19

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  48. Synthesis of luminescent thorium-based metal–organic frameworks with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

    RSC Advances · 2021-01-01

    Ting Yu, Zhenghua Qian, Lin Li, Xiaoling Wu, Hui He, Yanbo Qiao, Ye Guoan

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  49. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

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  50. State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization

    Journal of Hazardous Materials · 2021-11-25

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