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RESEARCH PAPER · Inorganic Chemistry · 2020

CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered Structure

Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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CsHgNO3Cl2: A New Nitrate UV Birefringent Material Exhibiting an Optimized Layered StructureOriginalAn antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters26From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]14Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer26The First Positive Uniaxial Cyanurate Crystals Containing a Crown-like Anionic Group Arrangement and Strengthened Optical Anisotropy17Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate4Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)6( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy3(C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent38Large optical anisotropy differentiation induced by the anion-directed regulation of structures29From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement26Potential optical functional crystals with large birefringence: Recent advances and future prospects322Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38(C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups31SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence32Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence91Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence18Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps6Cs2Pb4Br10: A layered perovskite shows large birefringence11Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions30Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials11A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains13Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups15First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties0Enhanced optical anisotropy of six-coordinated silica polymorphs via high-pressure hydrothermal treatment1Chiral-driven formation of hybrid cyanurates with large birefringence2Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices1“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge0Realizing large birefringence via S-substitution and anisotropic arrangement optimization4Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge2Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0(C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite0

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  1. An antimony( iii ) borate with large birefringence exhibiting unwonted [B 5 O 11 ] fundamental building blocks and dimeric [Sb 2 O 6 ] clusters

    Inorganic Chemistry Frontiers · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  2. From BaCl 2 to Ba(NO 3 )Cl: significantly enhanced birefringence derived from π-conjugated [NO 3 ]

    New Journal of Chemistry · 2021-01-01

    Zhen Chen, Hao Zeng, Shujuan Han, Zhihua Yang, Shilie Pan

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  3. Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer

    Journal of Materials Chemistry C · 2021-01-01

    Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Zi‐Jian Li, Shilie Pan

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  4. The First Positive Uniaxial Cyanurate Crystals Containing a Crown-like Anionic Group Arrangement and Strengthened Optical Anisotropy

    Crystal Growth & Design · 2021-02-25

    Dandan Wang, Fei Liang, Xinyuan Zhang, Zhanggui Hu, Yicheng Wu

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  5. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

    Inorganic Chemistry · 2021-04-06

    Yingwei Lu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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  6. Ba 2 B 5 O 8 (OH) 2 (NO 3 )·3H 2 O: the design of an alkaline earth metal borate-nitrate optimized from a hydroxylic borate

    Dalton Transactions · 2021-12-20

    Huaiyu Hu, Junben Huang, Zhiyong Guo, Min Zhang, Zhihua Yang, Shilie Pan

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  7. Hierarchical Modulation of Optical Anisotropy Driven by Metal Cation Polyhedra in Fluorooxoborates MIIB4O6F2 (MII=Be, Mg, Pb, Zn, Cd)

    Chemistry - A European Journal · 2021-12-27

    Shan Shu, Junben Huang, Chenhui Hu, Shilie Pan, Zhihua Yang

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  8. ( R )- and ( S )-[C 8 H 10 NO 3 ] 2 [NbOF 5 ]: noncentrosymmetric niobium oxyfluorides with large optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Jihyeon Moon, Kang Min Ok

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  9. (C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent

    Inorganic Chemistry Frontiers · 2022-01-01

    Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Hualiang Yu, Sangen Zhao, Junhua Luo

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  10. Large optical anisotropy differentiation induced by the anion-directed regulation of structures

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  11. From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement

    Inorganic Chemistry · 2022-01-11

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Yilin Li, Jiang‐Gao Mao

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  12. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  13. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  14. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  15. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  16. (C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups

    Inorganic Chemistry · 2022-08-31

    Yaoguo Shen, Bo Wen Chen, Hao Chen, Junhua Luo

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  17. SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

    Inorganic Chemistry · 2022-10-20

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  18. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

    Angewandte Chemie International Edition · 2022-11-08

    Xianghe Meng, Xingyu Zhang, Qingxiong Liu, Zhengyang Zhou, Xingxing Jiang, Yonggang Wang, Zheshuai Lin, Mingjun Xia

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  19. Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and Balanced Birefringence

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    Xianghe Meng, Xingyu Zhang, Qingxiong Liu, Zhengyang Zhou, Xingxing Jiang, Yonggang Wang, Zheshuai Lin, Mingjun Xia

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  20. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  21. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  22. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

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    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

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  23. Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps

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    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  24. Cs2Pb4Br10: A layered perovskite shows large birefringence

    Inorganic Chemistry Communications · 2023-08-26

    Bo Chen, Hao Chen, Shaobin Zhang, Yaoguo Shen

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  25. Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions

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  26. Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials

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  27. A2Hgx(SeO3)y (A = K, Rb, Cs): Three Alkali Metal Mercury Selenites Featuring Unique 1D [HgOm(SeO3)n]∞ Chains

    Inorganic Chemistry · 2023-12-11

    Jinxuan Ren, Hui Cui, Linhong Cheng, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye

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  28. Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides

    The Journal of Physical Chemistry C · 2024-01-14

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  29. Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

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  30. Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2

    Results in Physics · 2024-01-21

    Changyou Liu, Ketian Hou, Bei Zhang

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  31. Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures

    Inorganic Chemistry · 2024-01-23

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  32. Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization

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  33. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

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  34. Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

    Inorganic Chemistry · 2024-04-23

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  35. First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties

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  36. Enhanced optical anisotropy of six-coordinated silica polymorphs via high-pressure hydrothermal treatment

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  37. Chiral-driven formation of hybrid cyanurates with large birefringence

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  38. Rb 1.87 Cs 1.13 B 8 O 13 (NO 3 ): a new acentric borate-nitrate with two types of three-dimensional interpenetrating lattices

    New Journal of Chemistry · 2024-11-20

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  39. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

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  40. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

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  41. Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

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  42. Realizing large birefringence via S-substitution and anisotropic arrangement optimization

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  43. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

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  44. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

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  45. BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

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  46. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

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  47. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

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  48. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

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  49. (C 2 N 4 H 7 S)(H 2 PO 3 ): Optical Properties Study of a Metal‐Free Amidinothiourea Phosphite

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