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RESEARCH PAPER · Small · 2024

Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

Zhiyong Bai, Kang Min Ok

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Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth HalidesOriginalResearch progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34The Spin–Orbit Effect on the Electronic Structures, Refractive Indices, and Birefringence of X2PO4I (X = Pb, Sn, Ba and Sr): A First-Principles Investigation6Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19[C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy14Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy4Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution17SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence51[C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance8A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates4Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides33Lead-free perovskites for indoor photovoltaics2Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach8Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission0Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering0Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal8Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal2CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS1NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications0Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent1

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  1. Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds

    Inorganic Chemistry Frontiers · 2024-01-01

    Hangwei Jia, Xueling Hou, Shilie Pan

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  2. The Spin–Orbit Effect on the Electronic Structures, Refractive Indices, and Birefringence of X2PO4I (X = Pb, Sn, Ba and Sr): A First-Principles Investigation

    Nanomaterials · 2024-04-01

    Xudong Leng, Mei Hu, Qun Jing, Haiming Duan, Henglei Chen, Xiuhua Cui

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  3. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

    Inorganic Chemistry · 2024-07-04

    Jiachen Lu, Yang Li, Yunseung Kuk, Seung-Hun Choi, Kyungmo Kim, Chanhee Ko, Zhiyong Bai, Kang Min Ok

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  4. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  5. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  6. Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

    Science China Chemistry · 2024-08-19

    Jinbin Fan, Ziting Yan, Zilong Chen, Huimin Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  7. [C(NH2)3]2S2O6: A SBBO-Like Dithionate Crystal with Large Optical Anisotropy

    Inorganic Chemistry · 2024-12-11

    Siyu Li, Danyang Dou, Cheng Chen, Qi Shi, Bingbing Zhang, Ying Wang

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  8. Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy

    Materials Chemistry Frontiers · 2025-01-01

    Zhen Qian, Deman Kong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  9. Optimizing optical anisotropy in low-dimensional structures via intralayer hydrogen bonding modulation and anionic substitution

    Materials Horizons · 2025-01-01

    Muhammad Sharjeel Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  10. SnHPO4: A Layered Tin(II) Phosphate with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-23

    Xinyue Shi, Xueqing Liu, Chunxiao Nie, Yangkai Zhang, Degao Zhong, Bing Teng, Zhoubin Lin, Yisheng Huang, Shijia Sun

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  11. [C(NH2)3]Y(HCOO)4: Constructing 3D Framework for Guanidine-Based UV Nonlinear Optical Crystals with Good Performance

    Inorganic Chemistry · 2025-06-02

    Jiayin Tang, Xin Wen, Huili Zhang, Yuchen Yan, Jindong Chen, Shihui Ma, Min Luo, Chensheng Lin, Ning Ye, Guang Peng

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  12. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-08-15

    Zhiyuan Zhang, Yabo Wu, Luyong Zhang, Xu Liu, Qiuyuan Feng, Lihan Deng, Jin Li, Shujuan Han

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  13. Anion-Ordered [B3O5(OH)2] Induced by Crystal Water with Deep Ultraviolet Transparency and Large Birefringence in Boron-Rich Borophosphates

    Chemistry of Materials · 2025-08-20

    Huanhuan Zhao, Chenxu Li, Zhihua Yang, Xueling Hou, Jian Wei Han, Shilie Pan

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  14. Exceptional Enhancement of Optical Anisotropy Achieved via the Strategy of Combining Rigid Groups with High Symmetry and π‐Conjugated Organic Groups in Hybrid Fluorides

    Advanced Science · 2025-10-06

    Ru‐Ling Tang, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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  15. Lead-free perovskites for indoor photovoltaics

    Applied Physics Letters · 2025-10-20

    Muhammad Abdel‐Shakour, Junfang Wang, Hao Wang, Xiangyue Meng

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  16. Remarkable Birefringence Enhancement Enabled by π-Conjugated Cyanoguanidine Group Based on Anisotropic Molecule Coordination Approach

    The Journal of Physical Chemistry Letters · 2025-10-24

    Xinyue Shi, Xueqing Liu, Ying Su, Yangkai Zhang, Yong Wu, Run Li, Degao Zhong, Bing Teng, Yisheng Huang, Zhoubin Lin, Shijia Sun

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  17. Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission

    Advanced Optical Materials · 2025-12-10

    Zhenkai Cen, Z.-Y. Li, Guang Peng, Junbo Gong, Junbo Gong

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  18. Rational design of large birefringence infrared oxychalcogenides via heteroanionic octahedron engineering

    Chemical Communications · 2026-01-01

    Xinyao Qi, Haonan Liu, Yu-Jie Zhang, Shihui Ma, Hongping Wu, Zhanggui Hu, Hongwei Yu

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  19. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie International Edition · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  20. Unit Symmetry‐Breaking and Layered Linear Ordering Enabling Superior Short‐Wave Ultraviolet Birefringent Crystal

    Angewandte Chemie · 2026-01-14

    Xin Wen, Dequan Kong, Jingyao Lu, Jindong Chen, Haohai Yu, Huaijin Zhang, Zhanggui Hu, Jiyang Wang, Ning Ye, Guang Peng

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  21. CdY 2 Si 2 S 8 : A Wide Bandgap IR NLO Material with d 10 Metal-Induced Structure Transformation from CS to NCS

    Inorganic Chemistry · 2026-03-26

    Hongbo Zhang, Haixia Wang, Aoya He, Jiaze Sun, Jindou Hu, G. L. Li

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  22. NaNO 3 [(NH 2 ) 2 SO 2 ] 2 : A Halogen‐Free KBBF‐Type Nitrate Crystal with Record Birefringence for Ultraviolet Applications

    Advanced Optical Materials · 2026-04-25

    Juhui Cui, Feng Yu, Minqiang Gai

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  23. Steric hindrance and hydrogen-bond networks synergistically directing molecular alignment for high-performance ultraviolet birefringent

    Journal of Molecular Structure · 2026-05-07

    Yuqi Qin, Paipai Zhang, Peng Jiang, Xueling Hou, Hu Jiang, Minqiang Gai

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