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RESEARCH PAPER · Journal of Materials Chemistry C · 2021

Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layer

Zixiu Lu, Fangfang Zhang, Abudukadi Tudi, Zhihua Yang, Zi‐Jian Li, Shilie Pan

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Sn 14 O 11 Br 6 : a promising birefringent material with a [Sn 14 O 11 Br 6 ] layerOriginalPolymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency20NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)17Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Sn 9O 4Br 9X (X = Cl, Br): Two New Sn(II) Oxyhalides Exhibiting Large Birefringence Derived from Highly Distortive Polyhedra of Lone Pair Cations0Potential optical functional crystals with large birefringence: Recent advances and future prospects322Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15Synthesis, structure and characterization of Cd 2 TeO 3 Cl 2 with unprecedented [Cd 2 O 6 Cl 4 ] octahedral dimers5Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Sn9O4Br9X (X = Cl, Br): Two new Sn(II) oxyhalides exhibiting large birefringence derived from highly distortive polyhedra of lone pair cations9Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties11Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation4CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range44Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence11New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties0Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence8Recent progress in structural design strategies of high-birefringence optical crystals54Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1

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  1. Polymorphic Pb14O8I12 and Pb7O4I6 oxyhalides featuring unprecedented [O8Pb14] clusters with broad IR transparency

    Science China Materials · 2021-11-10

    Jiahao Jiao, Abudukadi Tudi, Min Zhang, Wenbing Cai, Junjie Li, Zhihua Yang, Shilie Pan

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  2. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

    Crystal Growth & Design · 2021-12-09

    Kui Wang, Xiaofei Li, Chao He, Jinhua Li, Xing‐Tao An, Li Wei, Qi Wei, Guo‐Ming Wang

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  3. Second-Harmonic-Generation-Active Oxyhalides: CuSb2O3X (X = Cl, Br)

    Inorganic Chemistry · 2021-12-15

    Mei Yang, Zhi‐Hui Shi, Wen‐Dong Yao, Sheng‐Ping Guo

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  4. Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material

    SSRN Electronic Journal · 2022-01-01

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Jiayue Xu

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  5. Sn 9O 4Br 9X (X = Cl, Br): Two New Sn(II) Oxyhalides Exhibiting Large Birefringence Derived from Highly Distortive Polyhedra of Lone Pair Cations

    SSRN Electronic Journal · 2022-01-01

    Mei Ying Hu, Chenchen Tu, Zhihua Yang, Shujuan Han, Shilie Pan

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  6. Potential optical functional crystals with large birefringence: Recent advances and future prospects

    Coordination Chemistry Reviews · 2022-02-08

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  7. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

    Inorganic Chemistry · 2022-11-04

    Jingdong Yan, Dongdong Chu, Zilong Chen, Jian Wei Han

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  8. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Yu Meng, Jiayue Xu

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  9. Synthesis, structure and characterization of Cd 2 TeO 3 Cl 2 with unprecedented [Cd 2 O 6 Cl 4 ] octahedral dimers

    Dalton Transactions · 2023-01-01

    Linan Wang, Chen Bai, Yingying Kong, Maqsood Iqbal, Yu Chu, Junjie Li

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  10. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  11. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  12. Sn9O4Br9X (X = Cl, Br): Two new Sn(II) oxyhalides exhibiting large birefringence derived from highly distortive polyhedra of lone pair cations

    Scripta Materialia · 2023-03-27

    Mei Hu, Chenchen Tu, Zhihua Yang, Shujuan Han, Shilie Pan

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  13. Heteroanionic LaBrVIO4 (VI = Mo, W): Excellence in Both Nonlinear Optical Properties and Photoluminescent Properties

    Chemistry of Materials · 2023-08-14

    Zixian Jiao, Osvaldo Medina Mireles, Kevin Ensz, Fei Wang, Mingli Liang, P. Shiv Halasyamani, Bingbing Zhang, D. Paul Rillema, Jian Wang

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  14. Positive and Negative Contribution from Lead–Oxygen Groups and Halogen Atoms to Birefringence: A First Principles Investigation

    Nanomaterials · 2023-11-28

    Can Deng, Jialong Wang, Mei Hu, Xiuhua Cui, Haiming Duan, Peng Li, Ming‐Hsien Lee

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  15. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  16. K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission

    Inorganic Chemistry · 2023-12-15

    Jianyi Zuo, Qiuyuan Feng, Hong Lei Du

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  17. Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range

    Small · 2023-12-15

    Jun-Bo Wang, Mengmeng Zhu, Yaoqing Chu, Jindan Tian, Lili Liu, Bingbing Zhang, P. Shiv Halasyamani

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  18. Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence

    Inorganic Chemistry Frontiers · 2024-01-01

    Chenhui Hu, Dongdong Chu, Xueling Hou, Feng Zhang, Jian Wei Han

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  19. Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence

    Dalton Transactions · 2024-01-01

    Liying Ren, Zeqiao Yin, Shiyi Wang, Zhengyan Lin, Liling Cao, Xuehua Dong, Ling Huang, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  20. New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

    Chemical Communications · 2024-01-01

    Chenhui Hu, Mengfan Wu, Jian Wei Han, Zhihua Yang, Shujuan Han, Shilie Pan

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  21. First-principles study of three isomers of the large birefringent crystal Sb4O4F4: electronic structure and optical properties

    Physica Scripta · 2024-10-24

    Hongheng Chen, Mei Hu, Jialong Wang, Haiming Duan, Qun Jing, Zhaohui Chen

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  22. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  23. Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-21

    Hongkun Liu, Gangji Yi, Jiarong Lv, Xuehua Dong, Hongmei Zeng, Ling Huang, Zhien Lin, Guohong Zou

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  24. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  25. Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides

    Crystal Growth & Design · 2025-07-11

    Xu Liu, Abudukadi Tudi, Junben Huang, Juanjuan Lu, Zhaofeng Wu

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  26. Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures

    Dalton Transactions · 2025-12-04

    Shenghong Zeng, Mayinuer Maimaiti, Jinche Wu, Tingwen Han, Hui Chai, Fangfang Zhang, Min Zhang

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