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RESEARCH PAPER · Coordination Chemistry Reviews · 2022

Potential optical functional crystals with large birefringence: Recent advances and future prospects

Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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Potential optical functional crystals with large birefringence: Recent advances and future prospectsOriginalBa 2 Zn 2 B 6 O 13 : coplanar [B 2 O 5 ] in unnoted U-shaped [B 6 O 13 ] groups achieving large birefringence6Broad-Band Cyan Emission Induced by Two-Locations of Eu2+ Activator for a New Phosphor Bala2y2(Sio4)3o: Eu2+3Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges4Linear unit BN 2 : a novel birefringence-enhanced fundamental module with sp orbital hybridization9LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence16Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy13Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects37Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold14NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units32RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution80Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response27Magnetically tunable and stable deep-ultraviolet birefringent optics using two-dimensional hexagonal boron nitride105An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains185Crystal Growth of K2HCO3F·H2O with a Very Short Cutoff Edge and Large Birefringence17NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge5Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching43ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22Excellent thermostability and blue light emitting properties of a new phosphor BaLa2Y2(SiO4)3:Tm3+4Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups142D material inorganic liquid crystals for tunable deep UV light modulation1CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization25Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence30LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks33Large birefringence in the quasi-one-dimensional material Sb2Se3: A DFT investigation of electronic and optical anisotropy19Digital holography for real-time detection based on femtosecond laser1Design of deep-ultraviolet nonlinear optical materials based on fundamental building blocks with excellent microscopic properties1Broadband and Incident-Angle-Modulation Near-Infrared Polarizers Based on Optically Anisotropic SnSe13Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)16Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap29Complete Stokes-Mueller matrix extraction using angular multiplexing polarization holography0Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)19K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation7Linear π-conjugated units of the D ∞h point group as superior ultraviolet birefringent units1LiVTeO 5 : a mid-infrared nonlinear optical vanadium tellurate crystal exhibiting enhanced second harmonic generation activities and notable birefringence21Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Mg assists in modulating the dimensionalities of the anionic frameworks of borates1Na 7 (SeO 4 ) 3 (IO 3 ) and K 2 (SeO 4 )[IO 2 (OH)]: two new iodate-selenates with short-wave UV cutoff edge and large birefringence8Recent advances in F-containing iodate nonlinear optical materials6Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates51Intense d‐p Hybridization in Nb3O15 Tripolymer Induced the Largest Second Harmonic Generation Response and Birefringence in Germanates7Coherent Phonon‐Induced Gigahertz Optical Birefringence and Its Manipulation in SrTiO39Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance26Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Shooting mid-infrared nonlinear optical materials with targeted balance performances in ternary d0-transition metal oxides through first-principles13Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Target‐Driven Design of Deep‐UV Nonlinear Optical Materials via Interpretable Machine Learning125Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials53Chain‐like [S x ] ( x =2–6) Units Realizing Giant Birefringence with Transparency in the Near‐Infrared for Optoelectronic Materials5Four New Sb‐based Orthophosphates: Cation Regulation to Investigate Diversified Structural Architecture1Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324“Cation Activation”: An Effective Strategy for the Enhancement of Birefringence36Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides56Birefringence Regulation by Clarifying the Relationship Between Stereochemically Active Lone Pairs and Optical Anisotropy in Tin‐based Ternary Halides2Inherent law of SHG and phase-matching in 0D NLO materials: Permutation tetra-coordinated groups2Triboelectric active pressure sensor with ultrabroad linearity range by femtosecond laser shaping based on electrons dynamics control43Na4[B6O9 (OH)3](H2O) Cl: A Deep-Ultraviolet Transparent Nonlinear Optical Borate Chloride with {[B6O9 (OH)3]3–}∞ Chains5Mixed Alkali Metal and Alkaline Earth Metal Scandium Borate Birefringence Material with Layered Structure and Short Ultraviolet Cutoff Edge17Tunable multicolor luminescence in vanadates from yttrium to indium with enhanced luminous efficiency and stability for its application in WLEDs and indoor photovoltaics12Birefringent Glass‐Engraved Tilted Pillar Metasurfaces for High Power Laser Applications21Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence5Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit38Improved Birefringence Activated by Tetrahedra Decorated with a Single Linear Unit1From Centrosymmetry to Noncentrosymmetry: Precise Structural Regulation and Characterization on ZnHPO3·2H2O Polymorphs13Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra2Three-in-One Tetrahedral Functional Units Constructing Diamondlike Ag2In2SiS3.06Se2.94 with High-Performance Nonlinear-Optical Activity4A survey of stereoactive oxysalts for linear and nonlinear optical applications40Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals12Designing a Dimension Reduced Hybrid Perovskite with Robust Large Birefringence by Expanding Cationic π‐Delocation40Pressure driven structural phase transitions and modulations in optical properties of lanthanum nitride: an account from on the fly molecular dynamics and SCF vis-à-vis non-SCF first-principle calculations13Cs2Pb4Br10: A layered perovskite shows large birefringence11Ba3.75MgB7O14F2.5: A Mixed Alkaline-Earth Metal Borate Fluoride with Short Ultraviolet Cutoff Edge and Large Birefringence9YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6Designing a Hybrid Perovskite with Enlarged Birefringence and Bandgap for Modulation of Light Polarization32Visible to mid-infrared giant in-plane optical anisotropy in ternary van der Waals crystals41Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring51Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring11[RbSr 3 X][(BS 3 ) 2 ] (X = Cl, Br): two salt-inclusion thioborates with large birefringence and structure transformation from centrosymmetric to asymmetric8Hydroxyl-Driven Enhanced Birefringence in Borophosphates3Vanadate Crystals with an Enhanced Birefringence and a Broadened Transparency Spectrum through Controlled [VO3]∞ Chain Arrangements and Alkali Metal Cation Introduction4AGe2O4Q (A = Ba, Sr; Q = S, Se): A series of heteroanionic oxychalcogenides with large birefringence9PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12Na 6 Mg 3 P 4 S 16 and RbMg 2 PS 4 Cl 2 : two Mg-based thiophosphates with ultrawide bandgaps resulting from [MgS 6 ] and [MgS x Cl 6− x ] octahedra4A Sharp Improvement of Sulfate's Birefringence Induced by the Synergistic Effect of Heteroleptic and Dimeric Strategies14K 2 RbB 8 PO 16 : A Borophosphate with Moderate Birefringence and Deep-Ultraviolet Transmission10Quenching mechanism and luminescence enhancement strategy of Eu2+-activator in fluoroborate host Ba5B4O10F213Cd8(BO3)4SiO4: Metal Cation Inducing the Formation of Isolated [BO3] and [SiO4] Units in Borate Silicate15“One stone two birds” design of borates featuring edge-sharing [BO 4 ] and different B–O configurations in one structure utilizing covalent tetrahedra8(C 3 N 6 H 7 )BF 4 ·H 2 O and (C 3 N 6 H 7 )SO 3 CH 3 ·H 2 O with large birefringence induced by coplanar π-conjugated [C 3 N 6 H 7 ] + groups33[Sn 3 OF]PO 4 vs. [Sn 3 F 3 ]PO 4 : enhancing birefringence by breaking the R 3 symmetry and realigning lone pairs121D Cu( i )-based chiral organic–inorganic hybrid material with second harmonic generation and circular polarized luminescence10Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Exploration of antimony( iii ) oxyhalides via single-site substitution in quest of large birefringence10Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8Exploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups8From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups13K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Modulating the birefringence of two-dimensional hybrid lead bromide perovskites using pyridine derivative cations11NaB(OH) 3 CH 3 : a deep-ultraviolet optical crystal with unprecedented methyl-modified [B(OH) 3 CH 3 ] units6Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O 4 Se (AE = Sr and Ba)17Prediction of ultraviolet optical materials in the K 2 O–B 2 O 3 system1Research progress in optical materials with cationic organic planar π-conjugated groups containing CN bonds34Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties18Synthesis and Characterization of Metal Iso-cyamelurate K0.5In0.5(H2C6N7O3)2·9H2O with Large Birefringence8THE INFLUENCE OF THE [LI]/[NB] RATIO ON THE HOLOGRAPHIC STORAGE PERFORMANCE OF MGFECULINBO3 CRYSTALS0THE INFLUENCE OF THE [LI]/[NB] RATIO ON THE HOLOGRAPHIC STORAGE PERFORMANCE OF MGFECULINBO3 CRYSTALS0Sb4O5I2: Enhancing Birefringence through Optimization of Sb/I Ratio for Alignment of Stereochemically Active Lone Pairs18Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl24Designing Optical Anisotropy: Silver-Aminoalkylpyridine Nitrate Complexes with Tunable Structures3Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence18Giant Optical Anisotropy in a Covalent Molybdenum Tellurite via Oxyanion Polymerization43Toward the ultraviolet (UV) or deep-UV nonlinear optical crystals: The combination of π-conjugated planar [XY3] and tetrahedral [XY4]80Dual-Anion Strategy Induces Dual Enhancement Toward Ultrashort Phase-Matching Wavelength in Deep-UV Transparent d0 Transition Metal Oxyfluorides21AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra14Stereochemically Active Lone Pair Leads to Birefringence in the Vacancy Ordered Cs3Sb2Cl9 Perovskite Single Crystals13Unleashing the potential of π-conjugated [B2O3(OH)2] to enhance birefringence in DUV crystals9Wavelength‐Linearly‐Dependent and Polarization‐Sensitive Perfect Absorbers based on Optically Anisotropic Germanium Selenide (GeSe)7Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11Enhanced Birefringence in Phosphates via “Two Steps in One”: d0 Transition Metal Regulation and Fluorination Synergistic Strategy7Giant ab‐Plane Birefringence in Quasi‐1D Fibrous Red Phosphorus13Giant ab‐Plane Birefringence in Quasi‐1D Fibrous Red Phosphorus0A Highly Optical Anisotropic Hybrid Perovskite for Efficient Manipulation of Light Polarization64M6[Cd2(CO3)2(B12O18)(OH)6] (M = K, Rb): Borate–Carbonates with Two CdCO3 Embedded in a Cyclic Oxoboron Anion10Highly anisotropic and stretchable birefringent elastomers for multicolored strain displays8Lithium niobate on insulator – fundamental opto‐electronic properties and photonic device prospects30A solution-processable natural crystal with giant optical anisotropy for efficient manipulation of light polarization161Review on birefringence in borates based on birefringence-active functional groups and arrangements57Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56Ba3Zn4Si4O15: A Novel Centrosymmetric Silicate with Isolated SiO4 and Si2O7 Units0Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Halogen Bond Unlocks Ultra‐High Birefringence73Halogen Bond Unlocks Ultra‐High Birefringence14NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3

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  1. Ba 2 Zn 2 B 6 O 13 : coplanar [B 2 O 5 ] in unnoted U-shaped [B 6 O 13 ] groups achieving large birefringence

    Chemical Communications · 2022-01-01

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  2. Broad-Band Cyan Emission Induced by Two-Locations of Eu2+ Activator for a New Phosphor Bala2y2(Sio4)3o: Eu2+

    Physica B Condensed Matter · 2022-01-01

    Menghan Yu, Dan Zhao, Ruijuan Zhang, Qingxia Yao, Wen Liu

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  3. Li 7 SrScB 12 O 24 and Li 7 Ba 0.6 Ca 0.4 ScB 12 O 24 : two new quaternary rare-earth borates with short UV cutoff edges

    New Journal of Chemistry · 2022-01-01

    Jianbang Chen, Jie Zhang, Aixin Zhu, Xuchu Huang

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  4. Linear unit BN 2 : a novel birefringence-enhanced fundamental module with sp orbital hybridization

    RSC Advances · 2022-01-01

    Jianbang Chen, Mengfan Wu, Jie Zhang, Xuchu Huang

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  5. LiSrSbS 3 : parallel configurations of lone pair electrons inducing a large birefringence

    Dalton Transactions · 2022-01-01

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  6. Mg(H 2 O) 6 [(IO 2 (OH)) 2 (IO 3 )] 2 : a new iodate with a very large band gap and optical anisotropy

    Journal of Materials Chemistry C · 2022-01-01

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  7. Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects

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  8. Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold

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  9. NaBaBS3: A Promising Infrared Functional Material with Large Birefringence Induced by π-Conjugated [BS3] Units

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  10. RbBiP2S6: A Promising IR Nonlinear Optical Material with a Giant Second-Harmonic Generation Response Designed by Aliovalent Substitution

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  11. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

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  12. Ba 3 HgGa 2 S 7 : A Zero-Dimensional Quaternary Sulfide Featuring a Unique [Hg 2 Ga 4 S 14 ] 12– String and Exhibiting a High Photocurrent Response

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  13. Magnetically tunable and stable deep-ultraviolet birefringent optics using two-dimensional hexagonal boron nitride

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  14. An excellent deep-ultraviolet birefringent material based on [BO2]∞ infinite chains

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  15. Crystal Growth of K2HCO3F·H2O with a Very Short Cutoff Edge and Large Birefringence

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  16. NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge

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  17. Design of novel deep-UV nonlinear optical materials with one-dimensional functional module [BO2]∞ chain and fluorine-driven short phase-matching

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  18. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

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  19. Excellent thermostability and blue light emitting properties of a new phosphor BaLa2Y2(SiO4)3:Tm3+

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  20. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

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  21. 2D material inorganic liquid crystals for tunable deep UV light modulation

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  22. CaBO2F: A novel deep-UV structural template with high nonlinear optical performance induced by electron delocalization

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  23. Li0.5Na0.5AlB2O4F2: Fluoroaluminoborate with Aligned 1∞[BO2] Chain Induced by Unprecedented [AlO3F3]6− Species Features Enhanced Birefringence

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  24. LiNaB6O9F2: A Promising UV NLO Crystal Having Fluorine‐Directed Optimal Performances and Double Interpenetrating 3[B6O9F2]∞ Networks

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  25. Large birefringence in the quasi-one-dimensional material Sb2Se3: A DFT investigation of electronic and optical anisotropy

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  26. Digital holography for real-time detection based on femtosecond laser

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  27. Design of deep-ultraviolet nonlinear optical materials based on fundamental building blocks with excellent microscopic properties

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  28. Broadband and Incident-Angle-Modulation Near-Infrared Polarizers Based on Optically Anisotropic SnSe

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  29. Achieving broadband ultraviolet to mid-infrared transparency in germanate-based nonlinear optical crystals Cs 3 REGe 3 O 9 (RE = Y, Gd)

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  30. Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials

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  31. C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap

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  32. Complete Stokes-Mueller matrix extraction using angular multiplexing polarization holography

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  33. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

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  34. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

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  35. Heteroanion-introduction-driven birefringence enhancement in oxychalcogenide Ba 3 M II Ge 3 O 2 S 8 (M II = Mn, Cd)

    Inorganic Chemistry Frontiers · 2023-01-01

    Shenghua Zhou, Mao‐Yin Ran, Wenbo Wei, A-Yang Wang, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  36. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

    Dalton Transactions · 2023-01-01

    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  37. Li2AB5O8F2 (A = Na and K): two new deep-ultraviolet transparent fluorooxoborates with moderate birefringence designed by targeted dimensional modulation

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