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RESEARCH PAPER · Inorganic Chemistry · 2024

Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 Groups

Wencong Li, Junbo Wang, Lili Liu, Chunmei Huang, Yanyan Ding, Mengmeng Zhu, Jindan Tian, Hai-Xin Qi, Yaoqing Chu, Jiayue Xu

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Na3K6(CO3)3(NO3)2X·6H2O (X = NO3, Cl, Br): Exploring High-Performance UV Birefringent Crystals Induced by Coplanar π-Conjugated CO3 and NO3 GroupsOriginalExploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups8Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate4K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family4The impact of anionic group arrangement on the optical properties of the arsenate series0Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16Recent progress in structural design strategies of high-birefringence optical crystals54Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy7Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications1Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network1Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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  1. Exploring short-wavelength birefringent crystals via triggering cooperative arrangement between different π-conjugated groups

    Chemical Communications · 2024-01-01

    Xiao Wang, Tingwen Han, Kenneth Reinhard Poeppelmeier, Xueling Hou, Shilie Pan, Fangfang Zhang

    Read original paper ↗ ·

  2. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  3. Cationic Coordination Modification Drives Birefringence and Nonlinear Effect Double Lifting in Sulfate

    Inorganic Chemistry · 2024-12-18

    Jiahao Wan, Ping Wang, Zhenhua Li, Chunxiang Wu, Weining Zheng, Lehui Liu, Hongming Liu

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  4. K6NaCaRe2(B5O10)3 (Re = Y, Lu): Two NLO Compounds Exhibiting a Short Absorption Edge in the A7–xA’xAeRe2(B5O10)3 (x = 0, 1) Family

    Inorganic Chemistry · 2024-12-19

    Wencong Li, Zhaowei Hu, Yanyan Ding, Yueting Zhu, Qun Jing, Lili Liu

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  5. The impact of anionic group arrangement on the optical properties of the arsenate series

    Journal of Materials Chemistry C · 2025-01-01

    Yunjie Wang, Zhihao He, Jiafu Ding, Jian Cui, Fuhong Wan, Jiajun Li, Xin Su, Yu Chu

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  6. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  7. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  8. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  9. KCd(IO 3 ) 2 Cl: A New UV NLO Crystal with Balanced Optical Properties Engineering via Target‐Driven Multi‐Ion Substitution Strategy

    Small · 2025-12-15

    Lei Hou, Siyu Li, Wencong Li, Bingchen Xiao, Yaoqing Chu, Bingbing Zhang, Ying Wang, Xinglong Chen, Lili Liu

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  10. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

    Inorganic Chemistry Frontiers · 2026-01-01

    Hussin Elkik, Muhammad Mujahid Iqbal, Aqsa Munawar, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  11. Synthesis and characterization of mixed carbonate and bicarbonate materials as candidates for deep-UV applications

    Chemical Communications · 2026-01-01

    Muhammad Mujahid Iqbal, Hussin Elkik, Changyou Liu, Aqsa Munawar, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  12. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  13. Synergistic Enhancement of Optical Anisotropy in Nitrate Sulfamate for UV Applications: Role of Functional Group Alignment and Hydrogen Bond Network

    Small · 2026-04-09

    Xiaotian Ma, Hongyuan Sha, Qianzhen Zhang, Ruyi Niu, Xiya Wen, Xifa Long, Shilie Pan, Yun Mo Yang

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  14. Unlocking Hidden Potential via Reprogrammed Mineral Structures: How Anionic Transformation Achieves Ultraviolet Nonlinear Optical Performance

    Journal of the American Chemical Society · 2026-09-11

    Wenbin Zhang, Ruonan Zhang, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

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  15. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

    Inorganic Chemistry · 2026-09-28

    Xiangtian Liu, Bingchen Xiao, Lei Hou, Wencong Li, Wenlong Zhao, Kaixin Yin, Haonan Pei, Xiaonan Li, Zhuangzhuang Dong, Lili Liu

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