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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

Zhiyong Bai, Kang Min Ok

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Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3OriginalStereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 319A survey of stereoactive oxysalts for linear and nonlinear optical applications40Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring51Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring11Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals33Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation8C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy36Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region14Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units18Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions1The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation3Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching19Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching0Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response2A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1

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  1. Stereochemically active lone-pair-driven giant enhancement of birefringence from three-dimensional CsZn 4 Ga 5 Se 12 to two-dimensional CsZnAsSe 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Chao Zhang, Mao‐Yin Ran, Xin Chen, Shenghua Zhou, Hua Lin, Yi Liu

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  2. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  3. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie International Edition · 2023-10-27

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·

  4. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie · 2023-10-27

    Zhiyong Bai, Kang Min Ok

    Read original paper ↗ ·

  5. Crystal clear: unveiling giant birefringence in organic–inorganic cocrystals

    Chemical Science · 2024-01-01

    Yang Li, Kang Min Ok

    Read original paper ↗ ·

  6. Explorations of highly birefringent materials in the vanadium oxyfluoride–iodate system by fluoride ion modulation

    Journal of Materials Chemistry C · 2024-01-01

    Yu Huang, Xueying Zhang, Sangen Zhao, Jiang‐Gao Mao, Bing‐Ping Yang

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  7. C(NH2)3MoO3(IO3): A Molybdenyl Iodate with Giant Birefringence Designed via a Cation–Anion Synergetic Interaction Strategy

    Chemistry of Materials · 2024-02-08

    Wei Zeng, Yao Tian, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

    Read original paper ↗ ·

  8. Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates

    Inorganic Chemistry · 2024-07-04

    Jiachen Lu, Yang Li, Yunseung Kuk, Seung-Hun Choi, Kyungmo Kim, Chanhee Ko, Zhiyong Bai, Kang Min Ok

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  9. NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra

    Inorganic Chemistry · 2024-07-22

    Lehui Liu, Feifei Yuan, Lizhen Zhang, Yisheng Huang, Zhoubin Lin

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  10. The New Paradigm of Ligand Substitution-Driven Enhancement of Anisotropy from SO4 Units in Short-Wavelength Region

    ACS Central Science · 2024-11-27

    Chenhui Hu, Huimin Li, Guangsheng Xu, Zhihua Yang, Jian Wei Han, Shilie Pan

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  11. Exploring new horizons in mid-to-far infrared nonlinear optical crystals: the significant potential of trigonal pyramidal [TeS 3 ] 2− functional units

    Chemical Science · 2025-01-01

    Bo Zhang, Sheng-Hua Zhou, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·

  12. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  13. K 2 Na(I 3 O 8 ) 3 : a promising mid-infrared birefringent material with two different structures of octaoxotriiodate( v ) polyanions

    New Journal of Chemistry · 2025-01-01

    Min-Quan Lin, M. Duan, Jiang-Gao Mao, Bing‐Ping Yang

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  14. The birefringence in orthorhombic and triclinic lead-iodates and the functional basic units' contribution: A first-principles investigation

    Chemical Physics Letters · 2025-02-22

    Jialong Wang, Enshen Wang, Xiuhua Cui, Peng Li, Qun Jing, Zhaohui Chen

    Read original paper ↗ ·

  15. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie International Edition · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·

  16. Potassium Tetraiodatoiodate(III) Iodate(V): A Nonlinear Optical Crystal with Exceptional Second‐Harmonic Generation and Full‐Wavelength Phase Matching

    Angewandte Chemie · 2025-03-31

    Min-Quan Lin, Chun‐Li Hu, M. Duan, Bingxuan Li, Jiang‐Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·

  17. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  18. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  19. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  20. LiBa 2 GaSi 2 O 8 : A Noncentrosymmetric Silicate Exhibiting Wide Transmission Range and Moderate Second Harmonic Generation Response

    Inorganic Chemistry · 2025-12-11

    Mingyue Gu, Hu Liu, Xianchao Zhu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  21. A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )

    New Journal of Chemistry · 2026-01-01

    Jia Wang, Wenbin Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  22. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

    Read original paper ↗ ·

  23. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

    Coordination Chemistry Reviews · 2026-08-12

    Meiqi Liu, Miao Zhang, Ziyang Wang, Shizheng Li, Yang Zhao, Jiahang Liu, Jianmin Gu, Weiwei Cao, Desong Wang, Tianhui Wu

    Read original paper ↗ ·
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