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RESEARCH PAPER · Inorganic Chemistry · 2024

Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large BirefringenceOriginalFully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence7Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5

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  1. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  2. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  3. MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence

    Journal of Solid State Chemistry · 2024-05-12

    Yueling Sun, Lei Huai, An-Hua Gong

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  4. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  5. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  6. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  7. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  8. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  9. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  10. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  11. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  12. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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