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RESEARCH PAPER · Inorganic Chemistry · 2021

Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

Yingwei Lu, Xingxing Jiang, Chao Wu, Lin Lin, Zhipeng Huang, Zheshuai Lin, Mark Graeme Humphrey, Chi Zhang

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Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation SubstitutionOriginalNaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Advances in second-order nonlinear optical sulfates38CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection26The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency7Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence5Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Cs2Pb4Br10: A layered perovskite shows large birefringence11A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction6The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions18Heteroatom substitution enhances generation and reactivity of surface-activated peroxydisulfate complexes for catalytic fenton-like reactions23Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4(CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration5Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 25Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal9CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials3Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials1

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  1. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

    Crystal Growth & Design · 2021-12-09

    Kui Wang, Xiaofei Li, Chao He, Jinhua Li, Xing‐Tao An, Li Wei, Qi Wei, Guo‐Ming Wang

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  2. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  3. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  4. CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection

    Inorganic Chemistry · 2022-03-01

    Yaoguo Shen, Longjie Huang, Zhifeng Wang, Yingwu Zhou, Xiaoling Xue, Hong Lin, Renwen Yan, Sangen Zhao, Junhua Luo

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  5. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

    Journal of Alloys and Compounds · 2022-05-13

    Daniel J. Clark, Jian‐Han Zhang, Andrew J. Craig, Ashley Weiland, Jacilynn A. Brant, Jeong Bin Cho, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  6. A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency

    Dalton Transactions · 2023-01-01

    Zilong Geng, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  7. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

    Inorganic Chemistry · 2023-04-21

    Xiaofei Li, Kui Wang, Chao He, Jinhua Li, Xing‐Tao An, Jie Pan, Qi Wei, Guo‐Ming Wang, Guo‐Yu Yang

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  8. Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence

    Inorganic Chemistry Communications · 2023-06-25

    Xiaofei Li, Huili Zhang, Dong‐Xue Jiao, Chao He, Yu-Xue Guo, Xing‐Tao An, Qi Wei

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  9. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  10. Cs2Pb4Br10: A layered perovskite shows large birefringence

    Inorganic Chemistry Communications · 2023-08-26

    Bo Chen, Hao Chen, Shaobin Zhang, Yaoguo Shen

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  11. A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction

    Inorganic Chemistry Frontiers · 2024-01-01

    Hao Fu, Xiaohui Zhang, Peiyu Liu, Bo Li, Baolin Wu, Ye Tao, Qianshuang Lu, Yingjie Li, Jiaxi Huang, Fangfang Zhang, Tingchao He, Zhi Chen, Heng Wang, Chenliang Su, Hong‐Ying Zang, Xiujun Yu, Xiaopeng Li

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  12. The Birefringence Modulation in Short‐Wave Ultraviolet Sulfates with Functional π‐Conjugated Cations and Polymerized Heteroleptic Tetrahedral Anions

    Advanced Optical Materials · 2024-02-07

    Yanran Shang, Hongyuan Sha, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  13. Heteroatom substitution enhances generation and reactivity of surface-activated peroxydisulfate complexes for catalytic fenton-like reactions

    Journal of Hazardous Materials · 2024-02-09

    Yan Wei, Jie Miao, Jiahao Cui, Junyu Lang, Qunli Rao, Baoxue Zhou, Mingce Long, Pedro J. J. Alvarez

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  14. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  15. NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra

    Inorganic Chemistry · 2024-07-22

    Lehui Liu, Feifei Yuan, Lizhen Zhang, Yisheng Huang, Zhoubin Lin

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  16. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  17. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  18. (CN 4 H 7 ) 2 SO 4 ·H 2 O: high-performance metal-free ultraviolet birefringent crystal with KBBF-like configuration

    Inorganic Chemistry Frontiers · 2025-01-01

    Xia Hao, Sijing Xie, Ruijie Wang, Chensheng Lin, Lingli Wu, Guang Peng, Tao Yan, Ning Ye, Min Luo

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  19. Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 2

    Journal of Materials Chemistry C · 2025-01-01

    Qinghe Li, Hanxiang Mi, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Rongbing Su, Bin Su, Chao He

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  20. Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal

    Small · 2025-05-02

    Yuexin Zhang, Zhengnan Yuan, Yanqiang Li, Yipeng Song, Weiqi Huang, Yao Yao, Ji Qi, Zhiyong Bai, Sangen Zhao, Junhua Luo

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  21. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

    Inorganic Chemistry · 2025-05-23

    Lehui Liu, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  22. Ce-centered polyhedral arrangement pattern and optical performance in Ce-based nonlinear optical materials

    Chinese Chemical Letters · 2025-11-01

    Xuan Li, Tianhui Wu, Meiqi Liu, Yang Zhao, Jiahang Liu, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  23. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  24. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  25. The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates

    Advanced Functional Materials · 2026-03-16

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  26. A Polar Cerium Iodate Ce 2 (IO 3 ) 6 (H 2 O) with a Strong Second-Harmonic Generation Response in Trivalent Ce-Based Materials

    Inorganic Chemistry · 2026-03-17

    Jiahang Liu, Miao Zhang, Shizheng Li, Ziyang Wang, Yang Zhao, NianRui Qu, Weiwei Cao, Jianmin Gu, Tianhui Wu

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