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RESEARCH PAPER · Inorganic Chemistry · 2022

Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical MaterialOriginal[C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy21[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence33RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap29Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Nonlinear Optical Properties in Perovskite Structure and Their Applications7The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates33Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions30Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6Synergistic combination of different types of functional motif in Rb(NO 3 )(SO 3 NH 3 ) for realizing excellent ultraviolet optical nonlinearity18Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides8Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal5KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts10Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups11“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge0Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge2Aliovalent Doping-Induced Enhancement of Self-Trapped Exciton Emission in Ruddlesden–Popper Perovskite10Highly Efficient Inch‐Sized Cs 3 Cu 2 I 5 : In Single Crystal for Radiation Dose Monitor and Nuclear Battery Applications1Photochromic Cs 2 Pb(NO 3 ) 2 Br 2 Perovskite Nanosheets as a Novel Anti‐Counterfeiting Material0Photochromic Cs 2 Pb(NO 3 ) 2 Br 2 Perovskite Nanosheets as a Novel Anti‐Counterfeiting Material2Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1[Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation0Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Synthesis and characterization of hydrated alkali metal calcium nitrates ACa(NO 3 ) 3 ·2H 2 O (A = NH 4 , Rb, Cs) as short ultraviolet birefringent materials0Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0

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  1. [C(NH 2 ) 3 ] 2 S 2 O 8 : combining delocalized and localized π-conjugate units to achieve strong optical anisotropy

    Inorganic Chemistry Frontiers · 2022-01-01

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  2. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

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  3. Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material

    SSRN Electronic Journal · 2022-01-01

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Jiayue Xu

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  4. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  5. BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response

    Materials Today Physics · 2022-10-05

    Y. Long, X. Dong, Lilian Huang, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Guangtian Zou

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  6. SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

    Inorganic Chemistry · 2022-10-20

    Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  7. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Yu Meng, Jiayue Xu

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  8. An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles

    Journal of Materials Chemistry C · 2023-01-01

    Zhaowei Hu, Lili Liu, Ruixin Zhang, Qun Jing, Huan Wang, Jindan Tian, Jiayue Xu, P. Shiv Halasyamani

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  9. C 3 N 6 H 7 SO 3 NH 2 : non-π-conjugated tetrahedra decoupling π-conjugated groups achieving large optical anisotropy and wide band gap

    Materials Chemistry Frontiers · 2023-01-01

    Danyang Dou, Qi Shi, Yunjie Bai, Cheng Chen, Bingbing Zhang, Ying Wang

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  10. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  11. Nonlinear Optical Properties in Perovskite Structure and Their Applications

    Springer eBooks · 2023-01-01

    J.L. Clabel H., Leandro H. Zucolotto Cocca, André G. Pelosi, Rafael de Q. Garcia, Leonardo De Boni, Cléber Renato Mendonça

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  12. The transformation of a zero-dimensional cluster into a one-dimensional chain structure achieving a dramatically enhanced birefringence in tin( ii )-based oxalates

    Inorganic Chemistry Frontiers · 2023-01-01

    Liying Ren, Linhong Cheng, Xiaoyan Zhou, Jinxuan Ren, Liling Cao, Ling Huang, Xuehua Dong, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  13. Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions

    Chinese Chemical Letters · 2023-10-26

    Pu Zhang, Xiang Mao, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  14. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  15. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

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  16. Synergistic combination of different types of functional motif in Rb(NO 3 )(SO 3 NH 3 ) for realizing excellent ultraviolet optical nonlinearity

    Inorganic Chemistry Frontiers · 2024-01-01

    Yunxia Song, Chensheng Lin, Xin Yi Zhao, Tao Yan, Ning Ye, Haotian Tian, Min Luo

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  17. Screening Large Birefringent Materials via Halogen Regulation in Ternary d0-Transition Metal Oxyhalides

    The Journal of Physical Chemistry C · 2024-01-14

    Xueting Pan, Junben Huang, Yineng Huang

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  18. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

    Inorganic Chemistry · 2024-03-28

    Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  19. Zn(C6H4NO2)2·4H2O: A Solar-Blind Birefringent Crystal

    Crystal Growth & Design · 2024-05-14

    Yaoguo Shen, Yu Wang, Zixiang Chen, Wencheng Lu

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  20. KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts

    Chinese Chemical Letters · 2024-06-26

    Qin Lin Wang, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  21. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

    Inorganic Chemistry · 2024-07-11

    Dan Wang, Han Luo, Tingyu Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  22. Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups

    Inorganic Chemistry · 2024-10-11

    Yanyan Ding, Mengmeng Zhu, Junbo Wang, Bo Li, Hai-Xin Qi, Lili Liu, Yaoqing Chu

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  23. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  24. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

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  25. Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

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  26. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

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  27. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

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  28. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

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    Zhiyuan Zhang, Yabo Wu, Luyong Zhang, Xu Liu, Qiuyuan Feng, Lihan Deng, Jin Li, Shujuan Han

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  29. BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    European Journal of Inorganic Chemistry · 2025-08-27

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  30. Aliovalent Doping-Induced Enhancement of Self-Trapped Exciton Emission in Ruddlesden–Popper Perovskite

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  31. Highly Efficient Inch‐Sized Cs 3 Cu 2 I 5 : In Single Crystal for Radiation Dose Monitor and Nuclear Battery Applications

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  32. Photochromic Cs 2 Pb(NO 3 ) 2 Br 2 Perovskite Nanosheets as a Novel Anti‐Counterfeiting Material

    Angewandte Chemie · 2025-10-23

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  33. Photochromic Cs 2 Pb(NO 3 ) 2 Br 2 Perovskite Nanosheets as a Novel Anti‐Counterfeiting Material

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  34. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

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  35. [Al(H 2 O) 6 ](NO 3 )Cl 2 : achieving parallel arrangement of functional units and birefringence enhancement through free halogen-mediated structural regulation

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  36. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

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  37. Synthesis and characterization of hydrated alkali metal calcium nitrates ACa(NO 3 ) 3 ·2H 2 O (A = NH 4 , Rb, Cs) as short ultraviolet birefringent materials

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  38. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

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  39. Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation

    Chinese Chemical Letters · 2026-09-01

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  40. Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)

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