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RESEARCH PAPER · Inorganic Chemistry · 2025

Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

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Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV TransparencyOriginalSb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Recent progress in structural design strategies of high-birefringence optical crystals54Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence1Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  2. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  3. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  4. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  5. Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence

    Dalton Transactions · 2026-01-01

    Jingsha Xu, Xiaofeng Zhang, Shanshan Chen, Weiyi Wang, Wenbo Qiu, Weizhao Cai, Liujiang Zhou

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  6. Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite

    Dalton Transactions · 2026-01-01

    Jingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian Wu

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  7. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  8. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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  9. Halogen-Mediated Dimensionality Reduction in Bismuth Oxychlorides: Trade-off between Birefringence and Band Gap

    Journal of Molecular Structure · 2026-08-03

    Huaiqiang Xun, Shumei Cao, Qingyue Cui, Yi Feng, Rui Wu, Chunmei Huang, Leyan Nian

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  10. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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