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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropyOriginalCsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions6From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge19Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect1MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence6Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13(C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy9BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect9(C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution38“All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy29A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals9Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence11A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy5BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge2K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations6Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5

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  1. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  2. Exploration of silver borates with diverse low-dimensional anion frameworks by introducing monovalent heteroanions

    New Journal of Chemistry · 2024-01-01

    Lei Huai, Wenlong Liu, Beibei Zhang, Ru‐Ling Tang, Yi‐Lei Lv, Yue‐Qi Wei, Sheng‐Ping Guo

    Read original paper ↗ ·

  3. From ZnF2 to ZnF2(H2O)4: Partial Substitution Achieves Structural Transformation and Nonlinear Optical Activity while Keeping Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2024-01-17

    Yue‐Qi Wei, Wei Xu, Lei Huai, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  4. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

    Inorganic Chemistry · 2024-03-28

    Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

    Read original paper ↗ ·

  5. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  6. HgC4H4O6: A mercury tartrate exhibits phase matchable second harmonic generation effect

    Inorganic Chemistry Communications · 2024-04-17

    Yueling Sun, An-Hua Gong

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  7. MgHg(SeO3)2(H2O)2: A magnesium mercury selenite with large birefringence

    Journal of Solid State Chemistry · 2024-05-12

    Yueling Sun, Lei Huai, An-Hua Gong

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  8. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  9. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units

    Inorganic Chemistry · 2024-07-08

    Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  10. (C5H12N2S)Hg(NO3)2: A Mercury Nitrate Nonlinear Optical Crystal Motivated by Heteroatom Coordination Strategy

    Inorganic Chemistry · 2024-07-31

    Yi‐Lei Lv, Liang Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  11. BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect

    Inorganic Chemistry · 2024-12-02

    Yuan Hua Lin, Rongfang Zhang, Yucheng Hao, Ming-Yang Cao, Xuanlin Pan, Jiang‐Gao Mao

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  12. (C 6 H 5 N 2 )HgCl 3 : Discovery of a Polar Hg‐Based Hybrid Halide as Preeminent Nonlinear Optical and Birefringent Material Activated by π‐Conjugated Organic Cation Substitution

    Advanced Optical Materials · 2024-12-30

    Ru‐Ling Tang, Die‐Xue Yang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  13. “All-four-in-one”: a novel mercury tellurite–nitrate Hg 3 (TeO 3 )(Te 3 O 7 )(NO 3 ) 2 exhibiting exceptional optical anisotropy

    Chemical Science · 2025-01-01

    Ru‐Ling Tang, Yi‐Lei Lv, Liang Ma, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo

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  14. A π-conjugated organic molecule-modified strategy to achieve high-performance metal nitrate birefringent crystals

    Inorganic Chemistry Frontiers · 2025-01-01

    Yi‐Lei Lv, Liang Ma, Guo-Ren Zhu, Bing-Wei Miao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  16. Controlling d10 Metal in Phenylthiourea‐Based Hybrid Metal Halides to Actualize Dimensional Transformation and Significantly Improve the Birefringence

    Advanced Optical Materials · 2025-07-20

    Yi‐Lei Lv, Ru‐Ling Tang, Liang Ma, Cheng Chen, Wenlong Liu, Sheng‐Ping Guo

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  17. A3ZnNO3X4 (A = Rb, NH4, X = Cl, I): Regulating Cations and Halides Yields Birefringent Crystals with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-08-15

    Zhiyuan Zhang, Yabo Wu, Luyong Zhang, Xu Liu, Qiuyuan Feng, Lihan Deng, Jin Li, Shujuan Han

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  18. BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    European Journal of Inorganic Chemistry · 2025-08-27

    Yueling Sun, Anhua Gong

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  19. K5NaZr4F22(H2O)2: A Hydrated Zirconium Fluoride with a Second-Harmonic Generation Effect and a Short Ultraviolet Cutoff Edge Induced by Cosubstitution with Heterovalent Cations

    Inorganic Chemistry · 2025-08-27

    Bing-Wei Miao, Guo-Ren Zhu, Ling Wang, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  20. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  21. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

    Read original paper ↗ ·
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