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RESEARCH PAPER · Inorganic Chemistry · 2022

SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large Birefringence

Ying Long, Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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SbHPO3F: 2D van der Waals Layered Phosphite Exhibiting Large BirefringenceOriginalSolvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses5Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence18A survey of stereoactive oxysalts for linear and nonlinear optical applications40Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size83Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions30Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials11CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework24Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation19New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution15Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence18Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization10Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals12Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence10From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units13Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials150Unveiling Charge Dependent Law to Enhance Birefringence in 2‐Aminopyrimidine Family21Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge0Can Low Structural Anisotropy Produce High Optical Anisotropy? Anomalous Giant Optical Birefringent Effect in PI4AlI4 in Focus11Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal28Recent progress in structural design strategies of high-birefringence optical crystals54BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge2Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges6Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O0孤对电子效应羟基硼酸盐非线性光学研究进展（特邀）0Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals11Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence1Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Lisiteng Luo, Xuemei Wen, Juan Cheng, Jing Li, Hongmei Zeng, Guohong Zou, Zhien Lin

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  2. Pb2Cl2(HPO3)(H2O) and Pb3Br2(HPO3)2: Two Phosphite Halides with 3D Structural Networks and Enlarged Birefringence

    Inorganic Chemistry · 2023-01-09

    Gang-Xiang Liu, Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  3. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  4. Highly Birefringent d 0 Transition Metal Fluoroantimonite in the Mid Infrared Band: Order–Disorder Regulation by Cationic Size

    Journal of the American Chemical Society · 2023-10-26

    Jia-Hang Wu, Chun‐Li Hu, Ting-Kun Jiang, Jiang‐Gao Mao, Fang Kong

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  5. Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions

    Chinese Chemical Letters · 2023-10-26

    Pu Zhang, Xiang Mao, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  6. Two van der Waals Layered Antimony(III) Phosphites as UV Optical Materials

    Inorganic Chemistry · 2023-11-10

    Yuxi Liu, Ying Long, Wei Zeng, Yao Tian, Hongmei Zeng, Xuehua Dong, Zhien Lin, Guohong Zou

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  7. CsSn2(HPO3)2I: The first inorganic metal phosphite iodide as a promising birefringent material exhibits a large birefringence with ideally layered framework

    Scripta Materialia · 2023-12-14

    Liang Ma, Wei Xu, Liyuanyue Xu, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  8. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Xiaoyan Zhou, Xiang Mao, Pu Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  9. New antimony fluorooxoborates with strong birefringence and unprecedented structural characterisation

    Chemical Communications · 2024-01-01

    Chenhui Hu, Mengfan Wu, Jian Wei Han, Zhihua Yang, Shujuan Han, Shilie Pan

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  10. New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution

    Inorganic Chemistry Frontiers · 2024-01-01

    Guanglian Sun, Xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  11. Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides

    Small · 2024-01-17

    Zhiyong Bai, Kang Min Ok

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  12. Two Short-Wave UV Antimony(III) Sulfates Exhibiting Large Birefringence

    Inorganic Chemistry · 2024-01-24

    Yang Lan, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  13. Enhancement of Birefringence in π-Conjugated Oxyfluorides Achieved via van der Waals Layered Structural Optimization

    Crystal Growth & Design · 2024-04-01

    Wenyao Zhang, Zichen Li, Xudong Leng, Qun Jing, Qiao Wen

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  14. Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals

    Inorganic Chemistry · 2024-04-11

    Liang Ma, Yi‐Lei Lv, Xiao-Fang Ao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  15. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  16. Sb2O2SeO3 and Sb2O(SeO3)2: Two-Layered Antimony(III) Selenites with Enhanced Birefringence

    Inorganic Chemistry · 2024-06-04

    Han Luo, Yu Zhang, Tingyu Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  17. From Pb6(HPO3)(H2PO3)Cl9 to Pb6(HPO3)2Br8(H2O)·H2O: Halogen Regulation to Achieve Inorganic Metal Phosphite Halide Nonlinear Optical Material with Unprecedented Pb-Centered Polyhedral Units

    Inorganic Chemistry · 2024-07-08

    Ru‐Ling Tang, Liang Ma, Yi‐Lei Lv, Wenlong Liu, Sheng‐Ping Guo

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  18. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

    Accounts of Chemical Research · 2024-12-12

    Xuehua Dong, Ling Huang, Guohong Zou

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  19. Unveiling Charge Dependent Law to Enhance Birefringence in 2‐Aminopyrimidine Family

    Advanced Optical Materials · 2024-12-16

    Muhammad Sharjeel Arif, Xu Liu, Zi‐Jian Li, Hangwei Jia, Yansheng Jiang, Zhihua Yang, Xueling Hou, Shilie Pan

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  20. Bazn2(Hpo3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    SSRN Electronic Journal · 2025-01-01

    Yueling Sun, Jian-Cheng Qiao, An-Hua Gong

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  21. Can Low Structural Anisotropy Produce High Optical Anisotropy? Anomalous Giant Optical Birefringent Effect in PI4AlI4 in Focus

    Journal of the American Chemical Society · 2025-01-14

    Huige Chen, Pifu Gong, Zheshuai Lin, Lei Kang

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  22. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  23. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie · 2025-02-22

    Xinyang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  24. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

    Xin‐Yang Li, Xiyue Cheng, Chun‐Li Hu, Bingxuan Li, Zhengyang Zhou, Jian‐Han Zhang, Shuiquan Deng, Jiang‐Gao Mao, Fang Kong

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  25. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  26. BaZn2(HPO3)3: A New Barium Zincophosphite with Short Ultraviolet Cutoff Edge

    European Journal of Inorganic Chemistry · 2025-08-27

    Yueling Sun, Anhua Gong

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  27. Stepwise Substitution Strategy for Beryllium-Based Selenites with Enhanced SHG Response, Moderate Birefringence, and Short UV Cutoff Edges

    Chemistry of Materials · 2025-11-17

    Yurui Wang, Xuehua Dong, Wei Zeng, Ling Huang, Zhien Lin, Hongmei Zeng, Guohong Zou

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  28. Crystal structures and optical properties of two layered lead halide phosphites Pb 3 (HPO 3 )Cl 4 ·H 2 O and Pb 3 (HPO 3 ) 2 Cl 2 ·H 2 O

    Dalton Transactions · 2026-01-01

    Zong-Jie Zhao, Yu-Zheng Yan, Jia-Jian Fu, Hongyan Wu, Jian‐Han Zhang

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  29. 孤对电子效应羟基硼酸盐非线性光学研究进展（特邀）

    Chinese Journal of Lasers · 2026-01-01

    刘开通 Liu Kaitong, 饶远 Rao Yuan, 熊龙耀 Xiong Longyao, 张志忠 Zhang Zhizhong

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  30. Density-Compensated Polarizability Anisotropy for Record Birefringence in Short-Wavelength Ultraviolet Inorganic Crystals

    Journal of the American Chemical Society · 2026-03-05

    Chong‐An Chen, Yang Li, Congcong Jin, S. D. Lee, Zhihua Yang, Kang Min Ok

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  31. Halogen-Substitution-Modulated Lone-Pair Orientation in Sb(H 2 PO 2 ) 2 X (X = Cl, F) for Enhanced UV Birefringence

    Crystal Growth & Design · 2026-06-29

    Ying Long, Xuehua Dong, Lin Qi, Lindong Luan, Zichen Ren, Zhien Lin, Guohong Zou

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  32. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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