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RESEARCH PAPER · Journal of Materials Chemistry C · 2019

A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materials

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A 2 Bi 2 (SO 4 ) 2 Cl 4 (A = NH 4 , K, Rb): achieving a subtle balance of the large second harmonic generation effect and sufficient birefringence in sulfate nonlinear optical materialsOriginalTb(HSO 4 )(SO 4 ) – a green emitting hydrogensulfate sulfate with second harmonic generation response21K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups14Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design302Structural phase transitions coupled with prominent dielectric anomalies and dielectric relaxation in [(CH 3 ) 3 NH] 2 [KCo(CN) 6 ] and mixed [(CH 3 ) 3 NH] 2 [KFe x Co 1−x (CN) 6 ] double perovskite hybrids16The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties98Effect of Substituent Exchange on Optical Anisotropy in Multicomponent Isostructural Materials Containing Sulfathiazole and 2-Aminopyridine Derivatives13Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Synthesis, Crystal Structures, Spectroscopic Characterization, and Thermal Analyses of the New Bismuth Sulfates NaBi(SO4)2·H2O and ABi(SO4)2 (A = K, Rb, Cs)5A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)319AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement37Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 254Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization28Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap26The tin sulfates Sn(SO 4 ) 2 and Sn2(SO4)3: crystal structures, optical and thermal properties10Two bismuth iodate sulfates with enhanced optical anisotropy17[C(NH2)3]3PO4·2H2O: A new metal-free ultraviolet nonlinear optical phosphate with large birefringence and second-harmonic generation response70Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution26Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties5Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials282D van der Waals Layered [C(NH2)3]2SO3S Exhibits Desirable UV Nonlinear-Optical Trade-Off47From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence19Pushing KTiOPO4-like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region19A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency15A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency96[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence10KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group3High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence21High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence199Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement26HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)47Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Advances in second-order nonlinear optical sulfates38The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)39CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection26Engineering DAST Nanoscale-Thick Films for Giant and Isotropic Second Harmonic Generation: Implications for Bioimaging and Quantum Optics10A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals33(C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups31Constructing ultraviolet nonlinear optical crystals with large second harmonic generation and short absorption edges by using polar tetrahedral S 2 O 3 groups14Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2β-(C 3 H 7 N 6 ) 2 Cl 2 ·H 2 O and (C 3 H 7 N 6 )F·H 2 O: two UV birefringent crystals induced by uniformly aligned structural groups35Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 331Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route8Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27ASb(SO4)2 (A = Rb, Cs): Two short-wave UV antimony sulfates exhibiting large birefringence43Pb(OH)I: A lead(II)-based oxyhalide with a large birefringence5Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Li2RbSO4Cl with a Short Ultraviolet Absorption Edge and an Acentric Structure through Assembling Heteroleptic [LiO3Cl] Tetrahedra2Design, Synthesis, Crystal Structure, and Thermal Studies of Ni0.779SbF3(SO4): A New Electrode Material for Electrochemical Supercapacitors8Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring51Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring11(C 2 H 10 N 2 )[Zn 2 (HPO 4 ) 2 Cl 2 ]: substitution-activated new short-wave ultraviolet phosphate with pivotal dual-property enhancement5Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material32Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Synthesis and Characterization of Metal Iso-cyamelurate K0.5In0.5(H2C6N7O3)2·9H2O with Large Birefringence8Exceptional Optical Anisotropy Enhancement Achieved Through Dual‐Ions Cosubstitution Strategy in Novel Hybrid Bismuth Halides23Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153(C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group13Bi(SO4)F·H2O and Bi(SO4)(NO3)·3H2O: Chemical Substitution-Induced Birefringence Enhancement in Bismuth Sulfates6NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5CdInO(BO3): An oxyborate birefringent material explored from d10 metal compounds1Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4A strongly birefringent sulfate crystal with a wide second-harmonic generation phase-matching range4Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal9CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10Thermal Evolution and Crystal Structure Features of Cs2SO4 and Cs2Ca3(SO4)4 Sulfates2(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1Achieving large birefringence in oxalate crystals by a hydrogen bond-directed strategy1(C7H10N)3Bi2I9·I2: Synergistic Cooperation of π-Conjugated Cations and Distorted [BiI6] Octahedra Enabling a Large Infrared Birefringence4Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1Ultrastrong second harmonic generation in organic DAST nano-films via interface-controlled strain engineering2A dobrovolskyite-type Na4Ca(SO4)3 sulfate: structural phase transition, thermal expansion and ionic conductivity0Strategically designed deep-ultraviolet optical crystals with balanced properties by small heteroatom substitution1立体化学活性孤对电子与极性基元协同构筑高性能紫外非线性光学晶体(NH4)2Sb3F9SeO4(特邀)0BaScSi2O6F: A barium-containing rare-earth metal silicate fluoride with a short cutoff edge0RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives5Cation‐Dominated Second‐Order Nonlinear Optical Response Enabled by π‐Conjugated Guanidinium Derivatives0Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials4Enhancing Birefringence of Sulphates by Polarity Modification in Planar Cations0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Two Rare Earth-Based Sulfates with Enhanced Birefringence and Broad Optical Transparency Window0A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response0

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  1. Tb(HSO 4 )(SO 4 ) – a green emitting hydrogensulfate sulfate with second harmonic generation response

    Dalton Transactions · 2019-01-01

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  2. K 4 (PO 2 F 2 ) 2 (S 2 O 7 ): first fluorooxophosphorsulfate with mixed-anion [S 2 O 7 ] 2− and [PO 2 F 2 ] − groups

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  3. Novel ultraviolet (UV) nonlinear optical (NLO) materials discovered by chemical substitution-oriented design

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  4. Structural phase transitions coupled with prominent dielectric anomalies and dielectric relaxation in [(CH 3 ) 3 NH] 2 [KCo(CN) 6 ] and mixed [(CH 3 ) 3 NH] 2 [KFe x Co 1−x (CN) 6 ] double perovskite hybrids

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  5. The study of structure evolvement of KTiOPO4 family and their nonlinear optical properties

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  6. Effect of Substituent Exchange on Optical Anisotropy in Multicomponent Isostructural Materials Containing Sulfathiazole and 2-Aminopyridine Derivatives

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  7. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

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  8. Synthesis, Crystal Structures, Spectroscopic Characterization, and Thermal Analyses of the New Bismuth Sulfates NaBi(SO4)2·H2O and ABi(SO4)2 (A = K, Rb, Cs)

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  9. A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)3

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  10. AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement

    Chemical Communications · 2021-01-01

    Hongming Liu, Qingchen Wu, Lili Liu, Zheshuai Lin, P. Shiv Halasyamani, Xingguo Chen, Jingui Qin

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  11. Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

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  12. Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization

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  13. Rb3In(SO4)3: a defluorinated mixed main-group metal sulfate for ultraviolet transparent nonlinear optical materials with a large optical band gap

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  14. The tin sulfates Sn(SO 4 ) 2 and Sn2(SO4)3: crystal structures, optical and thermal properties

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  15. Two bismuth iodate sulfates with enhanced optical anisotropy

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  16. [C(NH2)3]3PO4·2H2O: A new metal-free ultraviolet nonlinear optical phosphate with large birefringence and second-harmonic generation response

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  17. Molecular Engineering toward an Enlarged Optical Band Gap in a Bismuth Sulfate via Homovalent Cation Substitution

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  18. Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties

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  19. Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials

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  20. 2D van der Waals Layered [C(NH2)3]2SO3S Exhibits Desirable UV Nonlinear-Optical Trade-Off

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  21. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

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  22. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

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  23. NaSb3O2(SO4)3·H2O: A New Alkali-Metal Antimony(III) Sulfate with a Unique Sb6O20H4 Unit and Moderate Birefringence

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  24. Pushing KTiOPO4-like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region

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  25. A Lanthanum Ammonium Sulfate Double Salt with a Strong SHG Response and Wide Deep‐UV Transparency

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  28. K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence

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  29. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

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  30. PO(CH 2 CH 2 CF 3 ) 3 : an organic ultraviolet nonlinear optical material without any anionic group

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  31. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

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  32. High‐Performance Sulfate Optical Materials Exhibiting Giant Second Harmonic Generation and Large Birefringence

    Angewandte Chemie International Edition · 2022-01-04

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  33. Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

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  34. From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement

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  35. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

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  36. Crystal Structure and Theoretical Analysis of Cs2Ca3(SO4)4

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  37. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

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  38. Advances in second-order nonlinear optical sulfates

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  39. The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)3

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  40. CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection

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  41. Engineering DAST Nanoscale-Thick Films for Giant and Isotropic Second Harmonic Generation: Implications for Bioimaging and Quantum Optics

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  42. A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

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  43. (C3N6H7)2SbF5·H2O Exhibiting Strong Optical Anisotropy from the Optimal Arrangement of π-Conjugated (C3N6H7)+ Groups

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  44. Constructing ultraviolet nonlinear optical crystals with large second harmonic generation and short absorption edges by using polar tetrahedral S 2 O 3 groups

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  45. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

    CrystEngComm · 2023-01-01

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  46. Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 2

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    Qin Wang, Jinxuan Ren, Dan Wang, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  47. Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge

    New Journal of Chemistry · 2023-01-01

    Zhiyuan Zhang, Lihan Deng, Die Xu, Mei Ying Hu, Zhencheng Wu, Xin Su, Yineng Huang

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  48. β-(C 3 H 7 N 6 ) 2 Cl 2 ·H 2 O and (C 3 H 7 N 6 )F·H 2 O: two UV birefringent crystals induced by uniformly aligned structural groups

    Inorganic Chemistry Frontiers · 2023-01-01

    Yaoguo Shen, Liang Ma, Guofa Dong, Hualiang Yu, Junhua Luo

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  49. Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates

    Journal of the American Chemical Society · 2023-01-12

    Chao Wu, Chunbo Jiang, Guangfeng Wei, Xingxing Jiang, Zujian Wang, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  50. A Rare‐Earth Selenite with Unexpectedly Well‐Balanced Ultraviolet Nonlinear Optical Functionality, Sc(HSeO 3 ) 3

    Small · 2023-02-09

    Zhiyong Bai, Jihyun Lee, Heewon Kim, Yunseung Kuk, Myung‐Ho Choi, Chun‐Li Hu, Kang Min Ok

    Read original paper ↗ ·
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