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RESEARCH PAPER · Inorganic Chemistry · 2022

CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing Connection

Yaoguo Shen, Longjie Huang, Zhifeng Wang, Yingwu Zhou, Xiaoling Xue, Hong Lin, Renwen Yan, Sangen Zhao, Junhua Luo

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CsY(SO4)2·4H2O: A Deep-Ultraviolet Birefringent Crystal Induced by an Edge-Sharing ConnectionOriginal(C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent38Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material0H/F-Substitution-Induced Confinement Effect for Designing High-Phase-Transition-Temperature Organic–Inorganic Hybrid Materials16Three polar indium phosphites exhibiting diverse structural networks and SHG-activity9RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence15Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10β-(C 3 H 7 N 6 ) 2 Cl 2 ·H 2 O and (C 3 H 7 N 6 )F·H 2 O: two UV birefringent crystals induced by uniformly aligned structural groups35YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range44AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation153Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal11NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering61Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering4Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Structural Regularities, Thermal Stability, and Nature of Chemical Bonding in the Series of Actinide Double Sulfates Cs[An(SO4)2(H2O)3]·H2O (An = U, Np, Pu, or Am)3Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems3Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8Enhancement of optical anisotropy from [BF4] units by ligand substitution0Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response4Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )1A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups0Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation1

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  1. (C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent

    Inorganic Chemistry Frontiers · 2022-01-01

    Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Hualiang Yu, Sangen Zhao, Junhua Luo

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  2. Rbcl·(H2seo3)2: A New Salt-Inclusion Selenite as a Promising Uv Birefringent Material

    SSRN Electronic Journal · 2022-01-01

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Jiayue Xu

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  3. H/F-Substitution-Induced Confinement Effect for Designing High-Phase-Transition-Temperature Organic–Inorganic Hybrid Materials

    Crystal Growth & Design · 2022-09-15

    Yan‐Ning Wang, Min Wan, Wenlong Zheng, Hao Chen, Liang Tong, Siyu Ye, Jun‐Yi Li, Li-Zhuang Chen

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  4. Three polar indium phosphites exhibiting diverse structural networks and SHG-activity

    Journal of Solid State Chemistry · 2022-10-10

    Gang-Xiang Liu, Yu-Long Wei, Li-Nan Zhang, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

    Read original paper ↗ ·

  5. RbCl·(H2SeO3)2: A Salt-Inclusion Selenite Featuring Short UV Cut-Off Edge and Large Birefringence

    Inorganic Chemistry · 2022-12-23

    Huan Wang, Lili Liu, Zhaowei Hu, Junbo Wang, Mengmeng Zhu, Yu Meng, Jiayue Xu

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  6. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

    CrystEngComm · 2023-01-01

    Jingdong Yan, Dongdong Chu, Fangfang Zhang, Zhihua Yang, Shilie Pan, Xueling Hou

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  7. β-(C 3 H 7 N 6 ) 2 Cl 2 ·H 2 O and (C 3 H 7 N 6 )F·H 2 O: two UV birefringent crystals induced by uniformly aligned structural groups

    Inorganic Chemistry Frontiers · 2023-01-01

    Yaoguo Shen, Liang Ma, Guofa Dong, Hualiang Yu, Junhua Luo

    Read original paper ↗ ·

  8. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

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  9. Rational Design of the Alkali Metal Sn‐Based Mixed Halides with Large Birefringence and Wide Transparent Range

    Small · 2023-12-15

    Jun-Bo Wang, Mengmeng Zhu, Yaoqing Chu, Jindan Tian, Lili Liu, Bingbing Zhang, P. Shiv Halasyamani

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  10. AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems

    Inorganic Chemistry · 2024-02-27

    Zhencheng Wu, Huimin Li, Xueling Hou, Zhihua Yang, Hongsheng Shi

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  11. Hg4(Te2O5)(SO4): A Giant Birefringent Sulfate Crystal Triggered by a Highly Selective Cation

    Journal of the American Chemical Society · 2024-03-08

    Pengfei Li, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  12. Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal

    Inorganic Chemistry · 2024-05-31

    Yunqi Zhao, Yipeng Song, Yanqiang Li, Wei Liu, Zhou Yang, Weiqi Huang, Junhua Luo, Sangen Zhao, Belal Ahmed

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  13. NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra

    Inorganic Chemistry · 2024-07-22

    Lehui Liu, Feifei Yuan, Lizhen Zhang, Yisheng Huang, Zhoubin Lin

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  14. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie International Edition · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Shilie Pan, Zhihua Yang

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  15. Sulfate Derivatives with Heteroleptic Tetrahedra: New Deep‐Ultraviolet Birefringent Materials in which Weak Interactions Modulate Functional Module Ordering

    Angewandte Chemie · 2024-08-15

    Huan Zhou, Meng Cheng, Dongdong Chu, Xu Liu, Ran An, Shilie Pan, Zhihua Yang

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  16. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  17. Structural Regularities, Thermal Stability, and Nature of Chemical Bonding in the Series of Actinide Double Sulfates Cs[An(SO4)2(H2O)3]·H2O (An = U, Np, Pu, or Am)

    Inorganic Chemistry · 2025-02-18

    Tatiana R. Poliakova, Iurii M. Nevolin, Andrei A. Shiryaev, Alexander Fedoseev, Mikhail S. Grigoriev, А. А. Аверин, Vladislava Zubkova, Daniil Andreevich Novichkov, Alexander L. Trigub, Anna Krot, M. I. Volgin, Petr Igorevich Matveev

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  18. Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems

    Inorganic Chemistry · 2025-02-20

    Jiawei Zhao, Wei Wei, Meihui Chen, Donghai An, Yanna Chen, Hongsheng Shi

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  19. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  20. Enhancement of optical anisotropy from [BF4] units by ligand substitution

    Journal of Organometallic Chemistry · 2025-06-20

    Xiaotian Zhang, Chunbo Jiang, Lu Qi, Chao Wu, Chi Zhang

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  21. Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2025-10-02

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xintao Wu

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  22. Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations

    Chemistry of Materials · 2025-10-23

    Luyong Zhang, Zhencheng Wu, Jingdong Yan, Shibin Wang, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  23. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  24. A 2 Sb 2 SO 4 F 6 (A = NH 4 + , Na + ): two sulfate fluoride crystals exhibiting enhanced birefringence driven by stereochemically active antimony( iii )

    New Journal of Chemistry · 2026-01-01

    Jia Wang, Wenbin Zhang, Zhihua Yang, Shujuan Han, Shilie Pan

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  25. A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups

    Inorganic Chemistry Frontiers · 2026-01-01

    Yuchen Yan, Xin Wen, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  26. Ternary Anion‐Engineered Rare Earth Crystals for Broadband UV Transparency and Enhanced Second‐Harmonic Generation

    Chinese Journal of Chemistry · 2026-03-12

    Xiaohui Zhang, Ye Tao, Qianshuang Lu, J. N. Tan, Chenglong Xu, Yingjie Li, Yi Chen, Jianke Pan, F. H. Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Xiujun Yu, Xiaopeng Li

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