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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2021

Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2

Lei Wang, Hongmei Wang, Die Zhang, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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Centrosymmetric RbSnF 2 NO 3 vs. noncentrosymmetric Rb 2 SbF 3 (NO 3 ) 2OriginalNoncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)214Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation58NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents38Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps7[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)47KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence15KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23Large optical anisotropy differentiation induced by the anion-directed regulation of structures29Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response31Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response29Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials181Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy21Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 234Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph11Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence79Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence9A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions30Mg(C 3 O 4 H 2 )(H 2 O) 2 : A New Ultraviolet Nonlinear Optical Material Derived from KBe 2 BO 3 F 2 with High Performance and Excellent Water‐Resistance7Mg(C3O4H2)(H2O)2: A New Ultraviolet Nonlinear Optical Material Derived from KBe2BO3F2 with High Performance and Excellent Water‐Resistance43[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups23From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy14Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )25Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material32Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence11The Spin–Orbit Effect on the Electronic Structures, Refractive Indices, and Birefringence of X2PO4I (X = Pb, Sn, Ba and Sr): A First-Principles Investigation6Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5Two Mixed Alkali Metal Isocyanurates with Wide Band Gap and Giant Birefringence2Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements8KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts10Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials150Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal4From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal28Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering4Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br40Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap3Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials3Bonding-type-driven structural transformation toward novel fluoroiodosulfates: Achieving non-centrosymmetry and enhanced optical properties in K2(IO3F)SO30[C(NH 2 ) 3 ]SbCl 4 : An NLO Material with Enhanced Second Harmonic Response and Birefringence3Cation-regulated orientational coherence in one-dimensional antimony fluoride selenate chains modulates ultraviolet second-Harmonic generation0Short-UV Metal Halide Nitrates: Moderate SHG in K3Sb(NO3)3F3 and Enhanced Optical Anisotropy in K3Zn(NO3)X4 (X = Cl, Br)0Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. Noncentrosymmetric Rb3(COOH)3(H3BO3)2 vs Centrosymmetric Cs3(COOH)3(H3BO3)2

    Crystal Growth & Design · 2021-09-17

    Yunqiao Guo, Die Zhang, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  2. Synergistic Effect of π-Conjugated [C(NH 2 ) 3 ] Cation and Sb(III) Lone Pair Stereoactivity on Structural Transformation and Second Harmonic Generation

    Inorganic Chemistry · 2021-11-19

    Man Zhang, Bingbing Zhang, Daqing Yang, Ying Wang

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  3. NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

    Journal of Alloys and Compounds · 2021-11-24

    Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  4. Two molybdenyl carbonates with different dimensional structures exhibiting huge differences in band gaps

    Inorganic Chemistry Frontiers · 2021-11-26

    Yunqiao Guo, Yalan Deng, Ting Zheng, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  5. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

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  6. Halogen regulation triggers structural transformation from centrosymmetric to noncentrosymmetric switches in tin phosphate halides Sn 2 PO 4 X (X = F, Cl)

    Inorganic Chemistry Frontiers · 2022-01-01

    Ting Zheng, Qiang Wang, Jinxuan Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  7. KRE(CO 3 ) 2 (RE = Eu, Gd, Tb): new mixed metal carbonates with strong photoluminescence and large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuan Hua Lin, Chun‐Li Hu, Zhi Gang Fang, Jin Chen, Weijie Xie, Yan Chen, Jianpu Wang, Jiang‐Gao Mao

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  8. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

    Journal of Materials Chemistry C · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  9. Large optical anisotropy differentiation induced by the anion-directed regulation of structures

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  10. Unprecedented boat-shaped [Mo 2 O 5 (IO 3 ) 4 ] 2− polyanions induced a strong second harmonic generation response

    Chemical Communications · 2022-01-01

    Wei Zeng, Xuehua Dong, Yao Tian, Ling Huang, Hongmei Zeng, Zhien Lin, Guohong Zou

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  11. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  12. One-Side Capping in Two-Dimensional WO 3 -Type Materials Leading to Strong Second-Harmonic Response

    Chemistry of Materials · 2022-03-29

    Haonan Liu, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  13. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  14. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  15. Anisotropic structure building unit involving diverse chemical bonds: a new opportunity for high-performance second-order NLO materials

    Chemical Society Reviews · 2023-01-01

    Xin Liu, Yi‐Chang Yang, Mengyue Li, Ling Chen, Li‐Ming Wu

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  16. Hg 3 O 2 (NO 3 )F: a mercury nitrate oxyfluoride with an unprecedented [(Hg 3 O 2 F) + ] ∞ cationic framework and excellent optical anisotropy

    Inorganic Chemistry Frontiers · 2023-01-01

    Yi‐Lei Lv, Lei Huai, Yu-Long Wei, Liang Ma, Yue‐Qi Wei, Wenlong Liu, Ru‐Ling Tang

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  17. Low temperature molten salt synthesis of noncentrosymmetric (NH 4 ) 3 SbF 3 (NO 3 ) 3 and centrosymmetric (NH 4 ) 3 SbF 4 (NO 3 ) 2

    Inorganic Chemistry Frontiers · 2023-01-01

    Qin Wang, Jinxuan Ren, Dan Wang, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  18. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

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  19. Alignment of Λ-Shaped Basic Building Units to Construct One New KMoO3(IO3) Polar Polymorph

    Inorganic Chemistry · 2023-02-22

    Qing Li, Haonan Liu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  20. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  21. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  22. Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence

    Angewandte Chemie International Edition · 2023-05-22

    Haotian Tian, Chensheng Lin, Yuqiao Zhou, Xin Lei Zhao, Huixin Fan, Tao Yan, Ning Ye, Min Luo

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  23. Design of the Ionic Organic Nonlinear Optical Material NH 4 [LiC 3 H(CH 3 )O 4 ] with Ultrawide Band Gap and Moderate Birefringence

    Angewandte Chemie · 2023-05-22

    Haotian Tian, Chensheng Lin, Yuqiao Zhou, Xin Lei Zhao, Huixin Fan, Tao Yan, Ning Ye, Min Luo

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  24. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

    Materials Today Physics · 2023-06-01

    Jingru Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  25. Two UV organic-inorganic hybrid antimony-based materials with superior optical performance derived from cation-anion synergetic interactions

    Chinese Chemical Letters · 2023-10-26

    Pu Zhang, Xiang Mao, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  26. Mg(C 3 O 4 H 2 )(H 2 O) 2 : A New Ultraviolet Nonlinear Optical Material Derived from KBe 2 BO 3 F 2 with High Performance and Excellent Water‐Resistance

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  27. Mg(C3O4H2)(H2O)2: A New Ultraviolet Nonlinear Optical Material Derived from KBe2BO3F2 with High Performance and Excellent Water‐Resistance

    Angewandte Chemie International Edition · 2023-11-28

    Lingli Wu, Chensheng Lin, Haotian Tian, Yuqiao Zhou, Huixin Fan, Shunda Yang, Ning Ye, Min Luo

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  28. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  29. Designing excellent UV birefringent materials through the synergistic interaction of two highly distorted functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

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  30. From (NH 4 ) 3 [Zr(PO 4 ) 2 F] to (NH 4 ) 3 [Sn 2 (PO 4 ) 2 ]Cl: the rational design of a tin-based short-wave ultraviolet phosphate with large optical anisotropy

    Inorganic Chemistry Frontiers · 2024-01-01

    Zhi Gang Fang, Wenhua Ma, Qiuyu Chen, Xin-Ting Zhu, Xin-Mei Zeng, P. L. Li, Q-W Zhou, Tingting Song, Meihong Duan

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  31. Fully tricoordinated assembly unveils a pioneering nonlinear optical crystal (SbTeO 3 )(NO 3 )

    Chemical Science · 2024-01-01

    Bo Zhang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  32. Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material

    Chemical Science · 2024-01-01

    Zhiyong Bai, Jihyun Lee, Chun‐Li Hu, Guohong Zou, Kang Min Ok

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  33. Na 4 Sn 4 (C 2 O 4 ) 3 F 6 and NaSnC 2 O 4 F·H 2 O: two tin( ii ) fluoride oxalates display large birefringence

    Dalton Transactions · 2024-01-01

    Liying Ren, Zeqiao Yin, Shiyi Wang, Zhengyan Lin, Liling Cao, Xuehua Dong, Ling Huang, Yuqiao Zhou, Daojiang Gao, Guohong Zou

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  34. The Spin–Orbit Effect on the Electronic Structures, Refractive Indices, and Birefringence of X2PO4I (X = Pb, Sn, Ba and Sr): A First-Principles Investigation

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    Xudong Leng, Mei Hu, Qun Jing, Haiming Duan, Henglei Chen, Xiuhua Cui

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  35. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  36. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

    Inorganic Chemistry · 2024-04-23

    Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu, Huaijin Zhang

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  37. Two Mixed Alkali Metal Isocyanurates with Wide Band Gap and Giant Birefringence

    Crystal Growth & Design · 2024-05-15

    Xinyue Wang, Jinhui Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  38. Two Short-Wave UV Beryllium Selenites Exhibiting Diverse Optical Properties Stemming from Functional Group Arrangements

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  39. KSb2F7·2KNO3: Unveiling the peak birefringence in inorganic antimony oxysalts

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    Qin Lin Wang, Han Luo, Luli Wang, Ling Huang, Liling Cao, Xuehua Dong, Guohong Zou

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  40. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

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  41. Rational Design and Controlled Synthesis of High-Performance Inorganic Short-Wave UV Nonlinear Optical Materials

    Accounts of Chemical Research · 2024-12-12

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  42. Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain

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  43. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

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  44. From Holodirected to Hemidirected Coordination Activated by Oxygenation Strategy: A Facile Route to Long Wave Infrared Birefringent Crystal

    Angewandte Chemie International Edition · 2025-02-22

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  45. Designing High-Performance Short-Wave UV Tellurium-Based Mixed Halides Birefringent Crystals via Halogen Substitution Engineering

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  46. Synthesis, structure and properties of a new nitrate halide optical material: Cs3Zn(NO3)Br4

    Journal of Solid State Chemistry · 2025-07-03

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  47. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

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  48. Ag3In3(SeO3)3(SO4)F4: A Sulfate Selenite Nonlinear Optical Material with a Wide Bandgap

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  49. Layered perovskite-like nitrates A 2 Ca(NO 3 ) 2 Cl 2 (A = Rb, Cs) as ultraviolet birefringent optical materials

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  50. Bonding-type-driven structural transformation toward novel fluoroiodosulfates: Achieving non-centrosymmetry and enhanced optical properties in K2(IO3F)SO3

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