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RESEARCH PAPER · Inorganic Chemistry · 2021

Pushing KTiOPO4-like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral Region

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Pushing KTiOPO4-like Nonlinear Optical Sulfates into the Deep-Ultraviolet Spectral RegionOriginalExploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)34Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)334Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence10Enlargement of Bandgap and Birefringence in Nonlinear Optical Alkali‐Metal Sulfate Crystals by the Substitution of Asymmetrical Non‐π‐Conjugated Cation8Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal3Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal45The Directional Design of the Quasi‐Phase‐Matching Short‐Wave Ultraviolet Nonlinear Optical Crystal25Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Inorganic Solid‐State Electrolytes in Potassium Batteries: Advances, Challenges, and Future Prospects9The birefringence optimization by hydroxyl in organic nonlinear optical crystals3Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups0Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates0The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates1Two Rare Earth-Based Sulfates with Enhanced Birefringence and Broad Optical Transparency Window0

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  1. Exploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)3

    SSRN Electronic Journal · 2022-01-01

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, A. M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  2. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  3. Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)3

    Molecules · 2022-06-21

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, Alexey M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  4. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

    Chinese Journal of Structural Chemistry · 2023-02-24

    Chen Xu, Yanqiang Li, Junhua Luo, Sangen Zhao

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  5. A Non‐π‐Conjugated Molecular Crystal with Balanced Second‐Harmonic Generation, Bandgap, and Birefringence

    Small · 2023-09-08

    Zhou Yang, Nan He, Zheshuai Lin, Xiaoying Shang, Xueyuan Chen, Yanqiang Li, Weiqi Huang, Maochun Hong, Sangen Zhao, Junhua Luo

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  6. Enlargement of Bandgap and Birefringence in Nonlinear Optical Alkali‐Metal Sulfate Crystals by the Substitution of Asymmetrical Non‐π‐Conjugated Cation

    Advanced Optical Materials · 2023-10-02

    Pengfei Zhu, Pifu Gong, Zhenyan Wang, Huatong Jiang, Jianfu Zhao, Chao Li, Zheshuai Lin, Xiulan Duan, Fapeng Yu

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  7. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

    Ziting Yan, Jinbin Fan, Shilie Pan, Min Zhang

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  8. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

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  9. Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal

    Angewandte Chemie · 2024-08-12

    Jia-Xiang Zhang, Qing-Gang Yue, Shenghua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  10. Screening Strategy Identifies an Overlooked Deep‐Ultraviolet Transparent Nonlinear Optical Crystal

    Angewandte Chemie International Edition · 2024-08-12

    Jia-Xiang Zhang, Qing-Gang Yue, Shenghua Zhou, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  11. The Directional Design of the Quasi‐Phase‐Matching Short‐Wave Ultraviolet Nonlinear Optical Crystal

    Laser & Photonics Review · 2024-08-13

    Hongyuan Sha, Dongling Yang, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Bin Su, Xiaoming Yang, Xifa Long, Shilie Pan

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  12. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  13. Inorganic Solid‐State Electrolytes in Potassium Batteries: Advances, Challenges, and Future Prospects

    ChemElectroChem · 2025-02-14

    Titus N. Masese, Godwill Mbiti Kanyolo

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  14. The birefringence optimization by hydroxyl in organic nonlinear optical crystals

    Materials Today Chemistry · 2025-08-01

    Lilin Yang, Hanxiang Mi, Qinghe Li, Dongling Yang, Hongyuan Sha, Zujian Wang, Rongbing Su, Bin Su, Chao He

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  15. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  16. A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups

    Inorganic Chemistry Frontiers · 2026-01-01

    Yuchen Yan, Xin Wen, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

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  17. Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

    Angewandte Chemie · 2026-03-05

    Yujie Fan, Cheng Hu, Li Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan, Min Luo

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  18. The Enhancement of Phase‐Matching Capability by Recombining π‐Conjugated Group in Nonlinear Optical Sulfates

    Advanced Optical Materials · 2026-04-25

    Lilin Yang, Qinghe Li, Dongling Yang, Hongyuan Sha, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

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  19. Two Rare Earth-Based Sulfates with Enhanced Birefringence and Broad Optical Transparency Window

    Crystal Growth & Design · 2026-09-08

    Chang Liu, Ji Qi, Zhenchao Bai, Yong Wang, Weiqi Huang, Lina Li, Junhua Luo

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