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RESEARCH PAPER · Chemistry of Materials · 2022

A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

Yingshuang Sun, Chensheng Lin, Haotian Tian, Yuqiao Zhou, Jindong Chen, Shunda Yang, Ning Ye, Min Luo

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A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical CrystalsOriginal[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence10AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units152Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap79NaHSO4·H2O: A Promising Deep-Ultraviolet Nonlinear-Optical Bisulfate with Large Birefringence and a Second-Harmonic-Generation Effect16Cd(NH 2 SO 3 ) 2 · x H 2 O ( x = 0, 2): new sulfamates with a unique coordination environment and reversible phase transitions20Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10New Ultraviolet Nonlinear Optical Crystal Rb3Hg2(SO4)3Cl3Tetrahedron-based deep-ultraviolet nonlinear optical crystal with optimized KBe 2 BO 3 F 2 -like structure and disordered cations2Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response7Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals21Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence25YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra19Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence11Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence75A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction6Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra14A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra5The (C2N2H10)[Cu(H2O)4](TX4)2 Structural Family: When Fluoroberyllate, Sulfate, and Selenate Are Full Analogs7K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 25Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems3Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges2From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups0RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates0The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates4

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33 direct citing papers saved.

  1. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

    Read original paper ↗ ·

  2. K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yingshuang Sun, Chensheng Lin, Shenghao Fang, Haotian Tian, Ning Ye, Min Luo

    Read original paper ↗ ·

  3. AIB3IIC3IIIQ8VI: A New Family for the Design of Infrared Nonlinear Optical Materials by Coupling Octahedra and Tetrahedra Units

    Journal of the American Chemical Society · 2022-11-18

    Ling Luo, Linan Wang, Jianbang Chen, Jiazheng Zhou, Zhihua Yang, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  4. Rb 2 CdSi 4 S 10 : novel [Si 4 S 10 ] T2-supertetrahedra-contained infrared nonlinear optical material with large band gap

    Materials Horizons · 2022-11-25

    Jiazheng Zhou, Zhongxu Fan, Kewang Zhang, Zhihua Yang, Shilie Pan, Junjie Li

    Read original paper ↗ ·

  5. NaHSO4·H2O: A Promising Deep-Ultraviolet Nonlinear-Optical Bisulfate with Large Birefringence and a Second-Harmonic-Generation Effect

    Inorganic Chemistry · 2022-11-30

    Han Li, Haotian Tian, Chensheng Lin, Xin Lei Zhao, Chao Wang, Ning Ye, Min Luo

    Read original paper ↗ ·

  6. Cd(NH 2 SO 3 ) 2 · x H 2 O ( x = 0, 2): new sulfamates with a unique coordination environment and reversible phase transitions

    Inorganic Chemistry Frontiers · 2022-12-13

    Xuefei Wang, Jihyun Lee, Yang Li, Yunseung Kuk, Kang Min Ok

    Read original paper ↗ ·

  7. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

    CrystEngComm · 2023-01-01

    Jingdong Yan, Dongdong Chu, Fangfang Zhang, Zhihua Yang, Shilie Pan, Xueling Hou

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  8. New Ultraviolet Nonlinear Optical Crystal Rb3Hg2(SO4)3Cl

    Journal of Inorganic Materials · 2023-01-01

    Yunxia Song, Yinglei Han, Tao Yan, Min Luo

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  9. Tetrahedron-based deep-ultraviolet nonlinear optical crystal with optimized KBe 2 BO 3 F 2 -like structure and disordered cations

    New Journal of Chemistry · 2023-01-01

    Junxin Xu, Hongyuan Sha, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  10. Recent advances of inorganic phosphates with UV/DUV cutoff edge and large second harmonic response

    Chinese Journal of Structural Chemistry · 2023-02-13

    Boxuan Zhang, Zhaohui Chen

    Read original paper ↗ ·

  11. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

    Chinese Journal of Structural Chemistry · 2023-02-24

    Chen Xu, Yanqiang Li, Junhua Luo, Sangen Zhao

    Read original paper ↗ ·

  12. The Strategy to Improve the Phase Matching Ability in Tetrahedron‐Based Deep‐Ultraviolet Nonlinear Optical Crystals

    Advanced Optical Materials · 2023-07-09

    Hongyuan Sha, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

    Read original paper ↗ ·

  13. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  14. Sr(NO 3 )(NH 2 SO 3 )·H 2 O: First Nitrate Sulfamate Revealing Remarkable Second Harmonic Generation and Optimized Birefringence

    Small Structures · 2023-09-13

    Xuefei Wang, Yang Li, Zilong Chen, Jihyun Lee, Fangfang Zhang, Kenneth Reinhard Poeppelmeier, Shilie Pan, Kang Min Ok

    Read original paper ↗ ·

  15. YSO4F·H2O: A Deep-Ultraviolet Birefringent Rare-Earth Sulfate Fluoride with Enhanced Birefringence Induced by Fluorinated Y-Centered Polyhedra

    Inorganic Chemistry · 2023-10-12

    Dong‐Xue Jiao, Huili Zhang, Xiao-Fei Li, Chao He, Jinhua Li, Qi Wei, Guo‐Yu Yang

    Read original paper ↗ ·

  16. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

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  17. Deep‐Ultraviolet Transparent Mixed Metal Sulfamates with Enhanced Nonlinear Optical Properties and Birefringence

    Angewandte Chemie International Edition · 2023-11-17

    Xuefei Wang, Xudong Leng, Yunseung Kuk, Jihyun Lee, Qun Jing, Kang Min Ok

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  18. A chiral sodium lanthanum sulfate for second-order nonlinear optics and proton conduction

    Inorganic Chemistry Frontiers · 2024-01-01

    Hao Fu, Xiaohui Zhang, Peiyu Liu, Bo Li, Baolin Wu, Ye Tao, Qianshuang Lu, Yingjie Li, Jiaxi Huang, Fangfang Zhang, Tingchao He, Zhi Chen, Heng Wang, Chenliang Su, Hong‐Ying Zang, Xiujun Yu, Xiaopeng Li

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  19. Trithionic guanidine: A novel semi-organic short-wave ultraviolet nonlinear optical sulfate with dimeric heteroleptic tetrahedra

    Chinese Chemical Letters · 2024-03-08

    Hongyuan Sha, Dongling Yang, Yanran Shang, Zujian Wang, Rongbing Su, Chao He, Xiaoming Yang, Xifa Long

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  20. A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units

    Advanced Optical Materials · 2024-04-18

    Huan Zhou, Shan Shu, Abudukadi Tudi, Wenqi Jin, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  21. NaK5La2(SO4)6: Enhanced Birefringence of Multiple-Alkali Metal Sulfate Systems via Rare Earth Metal-Centered Polyhedra

    Inorganic Chemistry · 2024-07-22

    Lehui Liu, Feifei Yuan, Lizhen Zhang, Yisheng Huang, Zhoubin Lin

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  22. The (C2N2H10)[Cu(H2O)4](TX4)2 Structural Family: When Fluoroberyllate, Sulfate, and Selenate Are Full Analogs

    Molecules · 2024-11-14

    Dmitri O. Charkin, Vadim E. Kireev, Dmitri N. Dmitriev, A. M. Banaru, A. A. Kompanchenko, Dina V. Deyneko, Ivan Gundarovich Tananaev, Sergey M. Aksenov

    Read original paper ↗ ·

  23. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

    Inorganic Chemistry · 2024-12-07

    Fanlu Bu, Xiaorong Liu, Hongwei Yu, Runqing Liu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  24. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  25. Structure modulation by cationic modification of sulfates using planar CS(NH 2 ) 2

    Journal of Materials Chemistry C · 2025-01-01

    Qinghe Li, Hanxiang Mi, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Rongbing Su, Bin Su, Chao He

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  26. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  27. Na3Y2F3P2O8 and K4Y3F5P4O14: [YOF] Polyhedra Inducing Birefringence Enhancement in Non-π-Conjugated Phosphate Systems

    Inorganic Chemistry · 2025-02-20

    Jiawei Zhao, Wei Wei, Meihui Chen, Donghai An, Yanna Chen, Hongsheng Shi

    Read original paper ↗ ·

  28. Na2MP3O9 (M = K, Rb): Two Potential Zero-Order Waveplate Materials with DUV Cutoff Edges

    Inorganic Chemistry · 2025-03-04

    Huanhuan Zhao, Chenxu Li, Yi Huang, Qun Jing, Xuebin Yu, Zhaohui Chen

    Read original paper ↗ ·

  29. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  30. A[N(SO 2 NH 2 ) 2 ] (A = Na, K, Rb, and Cs): enhancing birefringence of non π-conjugated deep-ultraviolet crystals via novel dimeric disulfonamide [N(SO 2 NH 2 ) 2 ] − groups

    Inorganic Chemistry Frontiers · 2026-01-01

    Yuchen Yan, Xin Wen, Jindong Chen, Jiyang Wang, Zhanggui Hu, Ning Ye, Guang Peng

    Read original paper ↗ ·

  31. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

    Read original paper ↗ ·

  32. Confinement π‐Conjugated Moiety Tailoring to Achieve Record Deep‐UV Nonlinearity in Sulfates

    Angewandte Chemie · 2026-03-05

    Yujie Fan, Cheng Hu, Li Wu, Chensheng Lin, Chao Wang, Huixin Fan, Tao Yan, Min Luo

    Read original paper ↗ ·

  33. The Achievement of a Strong Second Harmonic Generation Response and a Large Birefringence in Sulfates

    Advanced Functional Materials · 2026-03-16

    Qinghe Li, Lilin Yang, Hongyuan Sha, Dongling Yang, Zujian Wang, Xiaoming Yang, Rongbing Su, Bin Su, Chao He, Xifa Long

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