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RESEARCH PAPER · Chemical Communications · 2021

AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancement

Hongming Liu, Qingchen Wu, Lili Liu, Zheshuai Lin, P. Shiv Halasyamani, Xingguo Chen, Jingui Qin

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AgBi(SO 4 )(IO 3 ) 2 : aliovalent substitution induces structure dimensional upgrade and second harmonic generation enhancementOriginalHg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds39Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units28Two bismuth iodate sulfates with enhanced optical anisotropy17Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant0Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties5Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]10Structure-Properties Relations in Two Iodate Families Studied by Topology-Symmetry Analysis of OD Theory8From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence53Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps28HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Advances in second-order nonlinear optical sulfates38The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)39Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold14[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology20Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 323Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals1ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method8Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41A survey of stereoactive oxysalts for linear and nonlinear optical applications40Innovative pH-buffering strategies for enhanced cycling stability in zinc–iodine flow batteries17UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System16Broadband Green Luminescence and Phase Transition in Low-Dimensional Organic–Inorganic Hybrid Iodate1(C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group13Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Bulk crystal growth and optical properties of a novel organic–inorganic hybrid nonlinear optical thiocyanate: [Mn(CH 3 CONH 2 ) 2 ] [Hg(SCN) 4 ]10Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14Selenoborates: a latent structure resource for infrared functional crystal materials1From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate6Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals1RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design0Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units1Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization0A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response0

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  1. Hg 3 (Te 3 O 8 )(SO 4 ): a new sulfate tellurite with a novel structure and large birefringence explored from d 10 metal compounds

    Chemical Communications · 2021-01-01

    Pengfei Li, Chun‐Li Hu, Ya-Ping Gong, Fang Kong, Jiang‐Gao Mao

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  2. Na 7 (IO 3 )(SO 4 ) 3 : the first noncentrosymmetric alkaline-metal iodate-sulfate with isolated [IO 3 ] and [SO 4 ] units

    Chemical Communications · 2021-01-01

    Mengmeng Ding, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  3. Two bismuth iodate sulfates with enhanced optical anisotropy

    Dalton Transactions · 2021-01-01

    Yilin Li, Chun‐Li Hu, Jin Chen, Jiang‐Gao Mao

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  4. Stabilizing lanthanide periodate compounds by slowing periodate reduction at elevated temperatures with NaBiO3, a sacrificial oxidant

    Polyhedron · 2021-04-18

    Colin N. Reedy, Eric M. Villa

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  5. Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties

    Materials · 2021-06-11

    Aleksandr S. Oreshonkov, Yuriy G. Denisenko

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  6. Synthesis, Structure, Characterization, and Calculation of a Noncentrosymmetric Fluorine-Containing Indium Iodate, Ba[InF3(IO3)2]

    Crystal Growth & Design · 2021-06-24

    Xiaoqing Jiang, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  7. Structure-Properties Relations in Two Iodate Families Studied by Topology-Symmetry Analysis of OD Theory

    Symmetry · 2021-08-12

    Olga Reutova, Elena L. Belokoneva, Anatoly S. Volkov, Olga V. Dimitrova

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  8. From CeF2(SO4)·H2O to Ce(IO3)2(SO4): Defluorinated Homovalent Substitution for Strong Second-Harmonic-Generation Effect and Sufficient Birefringence

    Chemistry of Materials · 2021-11-22

    Tianhui Wu, Xingxing Jiang, Yiran Zhang, Zujian Wang, Hongyuan Sha, Chao Wu, Zheshuai Lin, Zhipeng Huang, Xifa Long, Mark Graeme Humphrey, Chi Zhang

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  9. Cd 2 (IO 3 )(PO 4 ) and Cd 1.62 Mg 0.38 (IO 3 )(PO 4 ): metal iodate-phosphates with large SHG responses and wide band gaps

    Chemical Communications · 2022-01-01

    Qianqian Chen, Chun‐Li Hu, Li-Jia Yao, Jin Chen, Ming‐Yang Cao, Bingxuan Li, Jiang‐Gao Mao

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  10. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

    Inorganic Chemistry · 2022-01-14

    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  11. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  12. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  13. The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)3

    Inorganic Chemistry · 2022-02-22

    Matthias Hämmer, Jakoah Brgoch, Philip Netzsch, Henning A. Höppe

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  14. Second-Harmonic Generation-Positive Na 2 Ga 2 SiS 6 with a Broad Band Gap and a High Laser Damage Threshold

    Inorganic Chemistry · 2022-05-05

    Wenlong Xie, Yihan Yun, Lihan Deng, Guangmao Li, Shilie Pan

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  15. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

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  16. Dramatically improved optical anisotropy by realizing stereochemically active lone pairs in a sulfate system, K 2 SO 4 ·HIO 3

    Inorganic Chemistry Frontiers · 2023-01-01

    Zhiyong Bai, Kang Min Ok

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  17. Universal Method for Determining the Principal Optical Indicatrix Axes in Triclinic Crystals

    Crystal Growth & Design · 2023-02-13

    Jingcheng Feng, Lei Bai, Guochun Zhang

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  18. ε-La(IO3)3: A Polar Iodate with High Thermal Stability and a Large Second-Harmonic-Generation Response Obtained by a Supercritical Hydrothermal Method

    Inorganic Chemistry · 2023-04-17

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  19. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  20. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  21. Innovative pH-buffering strategies for enhanced cycling stability in zinc–iodine flow batteries

    Journal of Materials Chemistry A · 2024-01-01

    Phonnapha Tangthuam, Suttipong Wannapaiboon, Pinit Kidkhunthod, Jeng‐Lung Chen, Chia‐Che Chang, Chih‐Wen Pao, Phitchapa Ausamanwet Zijdemans, Tetsu Yonezawa, Manaswee Suttipong, Soorathep Kheawhom

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  22. UV-Transparent SHG Material Explored in an Alkali Metal Sulfate Selenite System

    Inorganic Chemistry · 2024-03-15

    Xinwei Zhang, Zhixiang Wang, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  23. Broadband Green Luminescence and Phase Transition in Low-Dimensional Organic–Inorganic Hybrid Iodate

    Inorganic Chemistry · 2024-04-17

    Yangwu Guo, Ziwei Yu, Kui Wang, Meiqiu Dong, Xinyi Li, Xinglong Yang, Yù Zhang

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  24. (C4H6N3O)(HSO4): A Cytosinium Bisulfate with Large Birefringence and Moderate Second Harmonic Generation Effect Produced via Combining a Promising Planar Nonlinear Optical-Active Motif with a Tetrahedral Group

    Inorganic Chemistry · 2024-05-31

    Meng-Han Lv, Shu‐Fang Li, Jing Wang, Jiaxin Wang, Ru‐Ling Tang, Hongbo Huang, Bingbing Zhang, Dong Yan

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  25. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

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  26. Bulk crystal growth and optical properties of a novel organic–inorganic hybrid nonlinear optical thiocyanate: [Mn(CH 3 CONH 2 ) 2 ] [Hg(SCN) 4 ]

    Inorganic Chemistry Frontiers · 2025-01-01

    Peiqing Long, Chun‐Li Hu, Xitao Liu, Jiang‐Gao Mao

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  27. Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect

    Chemical Science · 2025-01-01

    Zhenhua Li, Zhengli Liang, Jiahao Wan, Lehui Liu, Chunxiang Wu, Ping Wang, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  28. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  29. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  30. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

    Inorganic Chemistry · 2025-05-23

    Lehui Liu, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  31. A balance in SHG response, band gap and birefringence in a series of rare-earth sulfate-iodate

    Journal of Molecular Structure · 2025-07-01

    Chunxiang Wu, Y. X. Li, Zhengli Liang, Xiao Mei Jiang, Xiao Jiang, Hui Fang, Lixiang Qin, Xingyuan Bai, Lehui Liu, Lehui Liu, Xingxing Jiang, Xingxing Jiang, Hongming Liu, Hongming Liu

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  32. Dual-anion synergy drives remarkable birefringence in sulfate–nitrate crystals

    Inorganic Chemistry Frontiers · 2025-11-24

    LeHui Liu, FeiFei Yuan, YiSheng Huang, LiZhen Zhang, ZhouBin Lin

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  33. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  34. Hydrogen-Bond-Directed Assembly of Polyanionic Cluster [Mo 2 O 5 (IO 3 ) 4 ] 2– for Nonlinear Optical Crystal Design

    Inorganic Chemistry · 2026-07-07

    Yi-Xiang Wang, Shu‐Fang Li, Xin-Ran Hao, Zhixiang Wang, Chu Chu, Bingbing Zhang, Dong Yan

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  35. Non-π-conjugated tetrahedra-based optical crystals: The improvement of the linear and nonlinear optical properties by the combination of trigonal pyramidal [XO3] (X = I, Se, Te) units

    Coordination Chemistry Reviews · 2026-08-12

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  36. Advances in metal selenite nonlinear optical materials: halogens directed structure modulation and property optimization

    Coordination Chemistry Reviews · 2026-08-14

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  37. A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-09-21

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