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RESEARCH PAPER · Inorganic Chemistry · 2021

Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical Materials

Yunxia Song, Xia Hao, Chensheng Lin, Donghong Lin, Min Luo, Ning Ye

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Two Tellurium(IV)-Based Sulfates Exhibiting Strong Second Harmonic Generation and Moderate Birefringence as Promising Ultraviolet Nonlinear Optical MaterialsOriginalSynthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)216Exploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)34K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence10K 2 S 4 O 6 : improving birefringence and nonlinear optical properties with the [O 3 S–S–S–SO 3 ] 2− group5HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Explorations of New SHG Materials in Mercury Iodate Sulfate System**9Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals33The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe232Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)334Synthesis and crystal structure of the first ternary tellurium borate TeB4O83New Ultraviolet Nonlinear Optical Crystal Rb3Hg2(SO4)3Cl3Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses6Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route8AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap5Host–Guest Symmetry and Charge Matching in Glycine-Templated Metal Sulfate–Oxalates Obtained by a Solvent-Free Method9Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring51Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring11AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap20Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect14Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy17Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability8Statistical factorial design for optimum reduction of tellurite and production of tellurium nanostructure by a novel strain Phytobacter diazotrophicus Te13Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence1RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response0

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  1. Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)2

    Inorganic Chemistry · 2021-09-16

    Qi Wu, Can Yang, Jie Ma, Fei Liang, Chunlin Teng, Yeshuang Du

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  2. Exploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)3

    SSRN Electronic Journal · 2022-01-01

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, A. M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  3. K 2 (BeS)O 4 F 2 : a novel fluorosulfate with unprecedented 1D [(BeO 3 F)–(SO 3 F)] ∞ chains exhibiting large birefringence

    Inorganic Chemistry Frontiers · 2022-01-01

    Yingshuang Sun, Chensheng Lin, Shenghao Fang, Haotian Tian, Ning Ye, Min Luo

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  4. K 2 S 4 O 6 : improving birefringence and nonlinear optical properties with the [O 3 S–S–S–SO 3 ] 2− group

    Journal of Materials Chemistry C · 2022-01-01

    Tingting Huang, Yan Xiao, Jiashuo Gu, Ying Wang, Kui Wu, Bingbing Zhang

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  5. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

    Inorganic Chemistry · 2022-01-14

    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

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  6. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

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  7. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  8. A2BeS2O8 (A = NH4, K, Rb, Cs) Deep Ultraviolet Nonlinear Optical Crystals

    Chemistry of Materials · 2022-04-07

    Yingshuang Sun, Chensheng Lin, Haotian Tian, Yuqiao Zhou, Jindong Chen, Shunda Yang, Ning Ye, Min Luo

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  9. The Kurtz-Perry powder technique revisited: A case study on the importance of reference quality and broadband nonlinear optical measurements using LiInSe2

    Journal of Alloys and Compounds · 2022-05-13

    Daniel J. Clark, Jian‐Han Zhang, Andrew J. Craig, Ashley Weiland, Jacilynn A. Brant, Jeong Bin Cho, Yong Soo Kim, Joon Ik Jang, Jennifer A. Aitken

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  10. Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)3

    Molecules · 2022-06-21

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, Alexey M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  11. Synthesis and crystal structure of the first ternary tellurium borate TeB4O8

    Zeitschrift für anorganische und allgemeine Chemie · 2022-10-25

    Raimund Ziegler, Günter Heymann, Hubert Huppertz

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  12. New Ultraviolet Nonlinear Optical Crystal Rb3Hg2(SO4)3Cl

    Journal of Inorganic Materials · 2023-01-01

    Yunxia Song, Yinglei Han, Tao Yan, Min Luo

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  13. Solvent-free synthesis of magnesium phosphite-oxalates that show second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Lisiteng Luo, Xuemei Wen, Juan Cheng, Jing Li, Hongmei Zeng, Guohong Zou, Zhien Lin

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  14. Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route

    Inorganic Chemistry · 2023-04-07

    Xuemei Wen, Ying Long, Daibing Luo, Ling Huang, Hongmei Zeng, Xin Wang, Guohong Zou, Zhien Lin

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  15. AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap

    Inorganic Chemistry · 2023-04-20

    Pengfei Chen, Chun‐Li Hu, Ming-Yang Cao, Xueying Zhang, Jiang‐Gao Mao

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  16. Host–Guest Symmetry and Charge Matching in Glycine-Templated Metal Sulfate–Oxalates Obtained by a Solvent-Free Method

    Inorganic Chemistry · 2023-05-24

    Ying Li, Miao Luo, Ying Long, Ling Huang, Daojiang Gao, Guohong Zou, Zhien Lin, Yan Zhao

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  17. Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra

    Inorganic Chemistry · 2023-05-31

    Jinxuan Ren, Yuqi Chen, Liying Ren, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye

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  18. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie International Edition · 2023-10-27

    Zhiyong Bai, Kang Min Ok

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  19. Designing Sulfate Crystals with Strong Optical Anisotropy through π‐Conjugated Tailoring

    Angewandte Chemie · 2023-10-27

    Zhiyong Bai, Kang Min Ok

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  20. AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2024-01-18

    Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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  21. Different p-block elements induce C 3 [111] octahedral distortion in titanium to generate an intense nonlinear effect

    Chemical Science · 2025-01-01

    Zhenhua Li, Zhengli Liang, Jiahao Wan, Lehui Liu, Chunxiang Wu, Ping Wang, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  22. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  23. Metal Cation Engineered UV Birefringent Crystals in π‐Conjugated Sulfonates with Record‐High Optical Anisotropy

    Small · 2025-04-07

    Zichang Wang, Qing‐Yu Liu, Zhihua Yang, Xueling Hou, Minqiang Gai

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  24. Sb2(TeO4)(SO4): An Anhydrous Tellurite Sulfate with Large Birefringence and Enhanced Thermal Stability

    Inorganic Chemistry · 2025-04-08

    Xi-Ming Dong, Kai Huang, Hui‐Yan Zhao, Chao He, Xing‐Tao An, Qi Wei, Guo‐Yu Yang

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  25. Statistical factorial design for optimum reduction of tellurite and production of tellurium nanostructure by a novel strain Phytobacter diazotrophicus Te1

    Archives of Microbiology · 2025-04-15

    Alaa A Abdel-Samad, Mohamed Ismaeil, Einas H. El‐Shatoury, Ali M. Saeed

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  26. Double second-order Jahn–Teller strategy driven NLO response in sulfate crystal Nb 2 O 2 (TeO 3 ) 2 (SO 4 ) with a large birefringence

    Dalton Transactions · 2026-01-01

    Jingsha Xu, Xiaofeng Zhang, Shanshan Chen, Weiyi Wang, Wenbo Qiu, Weizhao Cai, Liujiang Zhou

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  27. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, Jiarui Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  28. A Hydrogen-Bonded Molecular Crystal with Strong Optical Anisotropy and Large Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-09-21

    Ning Yang, Li Shen, Wenting Lin, Zhenchao Bai, Xitong Song

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