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RESEARCH PAPER · Coordination Chemistry Reviews · 2022

Advances in second-order nonlinear optical sulfates

Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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Advances in second-order nonlinear optical sulfatesOriginal(C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent38Co-crystallization of red emitting (NH 4 ) 3 Sc(SO 4 ) 3 :Eu 3+ microfibers: structure–luminescence relationship for promising application in optical thermometry9Exploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)34Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)334Efficient and Tunable Enhancement of NLO Performance for Indaceno Based Donor Moiety in A-π-D-π-D-π-A Type First DSSC Design by End Capped Acceptors0Cyano-rich donor-acceptor-donor-type NLOphores containing dialkylated triazene and aniline groups18Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses20Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates112Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals5Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge53The second-order nonlinear optical properties of novel triazolo[3,4-b] [1, 3, 4] thiadiazole derivative chromophores using DFT calculations13From Centrosymmetry to Noncentrosymmetry: Precise Structural Regulation and Characterization on ZnHPO3·2H2O Polymorphs13Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide11Synthesis, crystal structure, and spectroscopic characterization of aminoguanidinium thiosulfate, (CN4H7)2S2O35Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O3K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response0Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses4Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties7Guanidinium Vanadate [C(NH2)3]3VO4·2H2O Revealing Enhanced Second-Harmonic Generation and Wide Band Gaps131,3‐Diynes as Precursors for the Synthesis of Triazene‐ and Diethylaniline‐Bearing Push‐Pull NLOphores3From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials9From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials50(C8H6BrN2O)NO3: A Hybrid Nonlinear Optical Crystal With an Appropriate Birefringence12Preparation of novel [Co(SCN) 4 ] hybrid material: crystal structure investigation, DFT mechanistic analysis, antioxidant activity, and molecular docking study for potential inflammatory disorder control7Polar and layered wide-bandgap semiconductors WO 2 Cl 2 and MoO 2 Br 2 with giant birefringence, large second harmonic and ferroelectric photovoltaic effects9A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units6Optical and mechanical stability of Tutton’s salt crystal of Cu2+ doped ammonium cobalt(II) sulfate hexahydrate15Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses6Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances17(C 3 H 5 N 2 ) 3 [Be 2 F 7 ]: the first imidazolium fluoroberyllate with a non-centrosymmetric structure based on linear tetrahedral [Be 2 F 7 ] 3− anions22D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses5Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships13CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications10Crystal chemistry and topology of simple rare-earth sulfates: synthesis, crystal structures, and spectroscopy of compounds with the general formula Ln2(SO4)3•8H2O1An Ultraviolet Transparent Nonlinear Optical Crystal Assembled from a Polarizable Tetrahedral Unit1Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0Stability of uracil in different sulphates under Martian-like UV irradiation0

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  1. (C 3 N 6 H 7 ) 2 SiF 6 ·H 2 O: an ultraviolet birefringent crystal exceeding the intrinsic energy gap of an organic reagent

    Inorganic Chemistry Frontiers · 2022-01-01

    Yaoguo Shen, Yingwu Zhou, Xiaoling Xue, Hualiang Yu, Sangen Zhao, Junhua Luo

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  2. Co-crystallization of red emitting (NH 4 ) 3 Sc(SO 4 ) 3 :Eu 3+ microfibers: structure–luminescence relationship for promising application in optical thermometry

    CrystEngComm · 2022-01-01

    Л.А. Пасечник, Alena O. Peshehonova, Olga A. Lipina, Ирина Сергеевна Медянкина, Andrey N. Enyashin, Alexander Yu. Chufarov, Alexander P. Tyutyunnik

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  3. Exploration of the Crystal Structure, Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(So4)3

    SSRN Electronic Journal · 2022-01-01

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, A. M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  4. Exploration of the Crystal Structure and Thermal and Spectroscopic Properties of Monoclinic Praseodymium Sulfate Pr2(SO4)3

    Molecules · 2022-06-21

    Yuriy G. Denisenko, Victor V. Atuchin∥⊥, Мaxim S. Моlokeev, Alexander E. Sedykh, Nikolay A. Khritokhin, Aleksandr S. Aleksandrovsky, Aleksandr S. Oreshonkov, N. P. Shestakov, S. V. Adichtchev, Alexey M. Pugachev, Elena I. Sal’nikova, О. В. Андреев, Illariia A. Razumkova, Klaus Müller‐Buschbaum

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  5. Efficient and Tunable Enhancement of NLO Performance for Indaceno Based Donor Moiety in A-π-D-π-D-π-A Type First DSSC Design by End Capped Acceptors

    Research Square · 2022-07-12

    Abrar U. Hassan, Sajjad Hussain Sumrra, Ghulam Mustafa, Muhammad Faizan Nazar, Muhammad Nadeem Zafar

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  6. Cyano-rich donor-acceptor-donor-type NLOphores containing dialkylated triazene and aniline groups

    Dyes and Pigments · 2022-11-03

    Flora Mammadova, Fevzi Can Inyurt, Alberto Barsella, Cagatay Dengiz

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  7. Two pairs of chiral Yb III enantiomers presenting distinct NIR luminescence and circularly polarized luminescence performances with giant differences in second-harmonic generation responses

    Dalton Transactions · 2023-01-01

    Xiaodi Du, Zhiqiang Zhang, Congli Gao, Fengcai Li, Xi-Li Li

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  8. Toward Large Second-Harmonic Generation and Deep-UV Transparency in Strongly Electropositive Transition Metal Sulfates

    Journal of the American Chemical Society · 2023-01-12

    Chao Wu, Chunbo Jiang, Guangfeng Wei, Xingxing Jiang, Zujian Wang, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  9. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  10. Machine Learning Regression Model for Predicting the Formation Energy of Nonlinear Optical Crystals

    Advanced Theory and Simulations · 2023-01-29

    Zhen Hong Fan, Zhixin Sun, Ai Wang, Yaohui Yin, Hui Li, Guangyong Jin, Chao Xin

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  11. Recent advances in non-π-conjugated nonlinear optical sulfates with deep-UV absorption edge

    Chinese Journal of Structural Chemistry · 2023-02-24

    Chen Xu, Yanqiang Li, Junhua Luo, Sangen Zhao

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  12. The second-order nonlinear optical properties of novel triazolo[3,4-b] [1, 3, 4] thiadiazole derivative chromophores using DFT calculations

    Structural Chemistry · 2023-05-10

    Balachandar Waddar, Saidi Reddy Parne, Suman Gandi, Gurusiddappa R. Prashanth, Mohammed Yaseen, Mahadevappa Yallappa Kariduraganavar

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  13. From Centrosymmetry to Noncentrosymmetry: Precise Structural Regulation and Characterization on ZnHPO3·2H2O Polymorphs

    Inorganic Chemistry · 2023-07-02

    Xinyu Wei, Xiaoying Wang, Yu Zhang, Shao‐Ming Ying, Jian‐Han Zhang

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  14. Wide band gaps in nonlinear optical materials AMgAgGa6S11 (A = K, Rb) achieved by the incorporation of dual s-block elements in Ag-based sulfide

    Materials Today Physics · 2023-08-09

    Wen‐Fa Chen, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  15. Synthesis, crystal structure, and spectroscopic characterization of aminoguanidinium thiosulfate, (CN4H7)2S2O3

    Zeitschrift für anorganische und allgemeine Chemie · 2023-11-07

    Dmitri O. Charkin, A. M. Banaru, Semen A. Ivanov, Vadim E. Kireev, Dmitri N. Dmitriev, Sergey M. Aksenov

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  16. Form-controlled synthesis of a polymorphic nonlinear optical crystal CsMgPO 4 ·6H 2 O

    CrystEngComm · 2024-01-01

    Sheng Lv, Liangcheng Song, Yanling Xu, Hongyan Cui, Haoyu Cheng, Zhihao Wang, Cun Zhu, Chunhui Yang

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  17. K, Rb-hydroxyborates series with deep-ultraviolet KRbB 5 O 8 (OH) possessing moderate second harmonic generation response

    New Journal of Chemistry · 2024-01-01

    Aihaimaitijiang Ababaikeri, Xueting Pan, Xueling Hou, Jian Wei Han

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  18. Two chiral Co III and Ni II complexes with identical ligands presenting different nonlinear optical responses

    New Journal of Chemistry · 2024-01-01

    Taoyu Wang, Yanhong Peng, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  19. Two chiral Eu III and Sm III enantiomeric pairs with enantiopure N-donor ligands: showing strong third-harmonic generation and photoluminescence properties

    CrystEngComm · 2024-01-01

    Jinliang Zhang, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  20. Guanidinium Vanadate [C(NH2)3]3VO4·2H2O Revealing Enhanced Second-Harmonic Generation and Wide Band Gaps

    Inorganic Chemistry · 2024-02-05

    Zhiyong Bai, Yunseung Kuk, Jihyun Lee, Heewon Kim, Kang Min Ok

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  21. 1,3‐Diynes as Precursors for the Synthesis of Triazene‐ and Diethylaniline‐Bearing Push‐Pull NLOphores

    ChemistrySelect · 2024-02-16

    Fevzi Can Inyurt, Cagatay Dengiz

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  22. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  23. From Cd(SCN) 2 (CH 4 N 2 S) 2 to Cd(SCN) 2 (C 4 H 6 N 2 ) 2 : Controlling Sulfur Content in Thiocyanate Systems Significantly Improves the Overall Performance of UV Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-03-13

    Yuwei Kang, Can Yang, Jie Gou, Yaolong Zhu, Qingwen Zhu, Weilin Xu, Qi Wu

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  24. (C8H6BrN2O)NO3: A Hybrid Nonlinear Optical Crystal With an Appropriate Birefringence

    Advanced Optical Materials · 2024-03-14

    Yaoguo Shen, Wanrui Niu, Yingjie Luo, Yingwu Zhou, Xiaoling Xue, Liqin Liu

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  25. Preparation of novel [Co(SCN) 4 ] hybrid material: crystal structure investigation, DFT mechanistic analysis, antioxidant activity, and molecular docking study for potential inflammatory disorder control

    Journal of Sulfur Chemistry · 2024-03-28

    Jawher Makhlouf, Hitler Louis, Innocent Benjamin, Ismail O. Amodu, Arto Valkonen, Hatem A. Abuelizz, Youness El Bakri, Rashad A. Al‐Salahi, Wajda Smirani Sta

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  26. Polar and layered wide-bandgap semiconductors WO 2 Cl 2 and MoO 2 Br 2 with giant birefringence, large second harmonic and ferroelectric photovoltaic effects

    Physical review. B./Physical review. B · 2024-04-16

    Hao Huo, Xiao Jiang, Lei Kang

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  27. A Universal Design Strategy Achieving Large Birefringence and Short Phase‐Matching Capability of Optical Materials via Dissimilating Non‐π‐Conjugated Units

    Advanced Optical Materials · 2024-04-18

    Huan Zhou, Shan Shu, Abudukadi Tudi, Wenqi Jin, Shilie Pan, Zhihua Yang

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  28. Optical and mechanical stability of Tutton’s salt crystal of Cu2+ doped ammonium cobalt(II) sulfate hexahydrate

    Journal of Materials Science Materials in Electronics · 2024-07-01

    Nallusamy Venkatachalam, J. Christina Rhoda, C. Esther Jayanthi, Karachalacherevu Seetharamiah Nagaraja, C. Karnan, Marimuthu Prabhaharan, Mohamed A. El‐Tayeb, Shaban R.M. Syed

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  29. Chiral mono- and dinuclear CoII and CuII enantiomeric pairs with distinct enantiopure N-donor ligands: Presenting highly enhanced third-harmonic generation responses

    Journal of Molecular Structure · 2024-09-14

    Xiaodi Du, Chunyang Li, Chunyang Li, Zhiqiang Zhang, Congli Gao, Xi-Li Li

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  30. Emergent Mid‐Infrared Nonlinear Optical Candidates With Targeted Balance Performances

    Small · 2024-12-23

    Junben Huang, Ailijiang Abudurusuli, Zhihua Yang, Shilie Pan

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  31. (C 3 H 5 N 2 ) 3 [Be 2 F 7 ]: the first imidazolium fluoroberyllate with a non-centrosymmetric structure based on linear tetrahedral [Be 2 F 7 ] 3− anions

    CrystEngComm · 2025-01-01

    Dmitri O. Charkin, Semen A. Ivanov, Vadim E. Kireev, Alevtina N. Gosteva, A. A. Kompanchenko, A. M. Banaru, Sergey Yu. Stefanovich, Ivan Gundarovich Tananaev, Sergey M. Aksenov

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  32. 2D Chiral Ag(I) Complexes with A-π–A- and D-π–A-Type Dicarboxylic Acid Ligands: Presenting Significant Differences in Nonlinear Optical Responses

    Inorganic Chemistry · 2025-01-10

    Congli Gao, Xiaoyu Cai, Jinying Huang, Qianrong Li, Huajie Kong, Jimei Yao, Yang Wang, Xi-Li Li

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  33. Review of KBe2BO3F2-like second-order nonlinear optical materials and their structure-performance relationships

    Coordination Chemistry Reviews · 2025-04-06

    Junben Huang, Chenglong Zhang, Siying Chen, Ailijiang Abudurusuli

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  34. CsLa(SO 4 ) 2 : A Lanthanum Sulfate Crystal for Nonlinear Optical Applications

    Inorganic Chemistry · 2025-05-23

    Lehui Liu, Feifei Yuan, Yisheng Huang, Lizhen Zhang, Zhoubin Lin

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  35. Crystal chemistry and topology of simple rare-earth sulfates: synthesis, crystal structures, and spectroscopy of compounds with the general formula Ln2(SO4)3•8H2O

    Russian Chemical Bulletin · 2026-01-01

    Yu. A. Vaitieva, D. O. Charkin, E. Yu. Borovikova, Dina V. Deyneko, A. N. Gosteva, S. A. Ivanov, S. N. Volkov, R. K. Rastsvetaeva, V. A. Blatov, S. M. Aksenov

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  36. An Ultraviolet Transparent Nonlinear Optical Crystal Assembled from a Polarizable Tetrahedral Unit

    Inorganic Chemistry · 2026-03-20

    Ning Yang, Li Shen, Zhiyong Bai, Xitong Song

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  37. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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  38. Stability of uracil in different sulphates under Martian-like UV irradiation

    Icarus · 2026-09-05

    Cristina García‐Florentino, Teresa Fornaro, Sole Biancalani, Andrew Alberini, Domenica Marabello, Francesco Renzi, Giovanni Poggiali, Mariano Battistuzzi, Juan Manuel Madariaga, J. Martinez-Frias, J. R. Brucato

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