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RESEARCH PAPER · Journal of Alloys and Compounds · 2021

NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solvents

Die Zhang, Qiang Wang, Ting Zheng, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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NH4Sb2(C2O4)F5: A novel UV nonlinear optical material synthesized in deep eutectic solventsOriginal[C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy40A flexible functional module to regulate ultraviolet optical nonlinearity for achieving a balance between a second-harmonic generation response and birefringence43KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence23Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence0Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects37Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material40Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates58Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy38BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response32A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties10Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials47Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance26Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route8Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity30KHC 2 O 4 · B ( OH ) 3 : A nonlinear optical crystal with large birefringence in the short‐wavelength ultraviolet region9Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials20NaCl·CH4N2O·H2O: An Organic–Inorganic Hybrid Ultraviolet Nonlinear Optical Crystal with Optimized Comprehensive Properties8A survey of stereoactive oxysalts for linear and nonlinear optical applications40C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties14Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates153Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units11Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio7A novel sodium manganese fluorooxalate crystal Na2Mn2(C2O4)2.5F·2H2O: Synthesis, structure, optical and thermal properties2Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O3Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System7Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain10Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning1Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties11(C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption23Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes6Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes10Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals5Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs8[C(NH 2 ) 3 ]SbCl 4 : An NLO Material with Enhanced Second Harmonic Response and Birefringence3The electronic structures, refractive indices and Berry curvature induced by the spin-orbit coupling in BiOX compounds: A first-principles investigation0Enhancing the Performance of Antimony‐Based Materials in Sodium‐Ion Batteries through Synthesis and Modification0

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  1. [C(NH 2 ) 3 ]BiCl 2 SO 4 : an excellent birefringent material obtained by multifunctional group synergy

    Inorganic Chemistry Frontiers · 2022-01-01

    Xuehua Dong, Zhizhuan Zhang, Ling Huang, Guohong Zou

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  2. A flexible functional module to regulate ultraviolet optical nonlinearity for achieving a balance between a second-harmonic generation response and birefringence

    Chemical Science · 2022-01-01

    Liling Cao, Haotian Tian, Donghong Lin, Chensheng Lin, Feng Xu, Yinglei Han, Tao Yan, Jindong Chen, Bingxuan Li, Ning Ye, Min Luo

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  3. KSb(BeF 3 )F 3 : a totally fluorine strategy for achieving wide bandgap and large birefringence

    Journal of Materials Chemistry C · 2022-01-01

    Xuehua Dong, Ying Long, Ling Huang, Liling Cao, Daojiang Gao, Jian Bi, Guohong Zou

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  4. Nain(C2o4)(Hpo4)(H2o)5: An Ultraviolet Transparent Nonlinear Optical Oxalate-Phosphate with Large Birefringence

    SSRN Electronic Journal · 2022-01-01

    Xuqi Zhang, Yanyan Xue, Lei Yang, Chao Wu, Zhipeng Huang, Jun Xu, Mark Graeme Humphrey, Chi Zhang

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  5. Performance of optical materials with the derivative of planar π-conjugated groups: Recent advances and future prospects

    Inorganic Chemistry Frontiers · 2022-01-01

    Huanhuan Cheng, Wenqi Jin, Zhihua Yang, Shilie Pan

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  6. Layered Perovskite-like Nitrate Cs2Pb(NO3)2Br2 as a Multifunctional Optical Material

    Inorganic Chemistry · 2022-02-23

    Ying Long, Xuehua Dong, Hongmei Zeng, Zhien Lin, Guohong Zou

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  7. Cation-anion synergetic interactions achieving tunable birefringence in quasi-one-dimensional antimony(III) fluoride oxalates

    Science China Materials · 2022-07-05

    Die Zhang, Qiang Wang, Ting Zheng, Liling Cao, Kang Min Ok, Daojiang Gao, Jian Bi, Ling Huang, Guohong Zou

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  8. Sharp Enhancement of Birefringence in Antimony Oxalates Achieved by the Cation–Anion Synergetic Interaction Strategy

    Inorganic Chemistry · 2022-07-27

    Die Zhang, Qiang Wang, Liying Ren, Liling Cao, Ling Huang, Daojiang Gao, Jian Bi, Guohong Zou

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  9. BaSb(H2PO2)3Cl2: An excellent UV nonlinear optical hypophosphite exhibiting strong second-harmonic generation response

    Materials Today Physics · 2022-10-05

    Y. Long, X. Dong, Lilian Huang, Hongmei Zeng, Zhien Lin, Liujiang Zhou, Guangtian Zou

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  10. A 0.5 H 2 C 6 N 7 O 3 ·4H 2 O (A = Ca 2+ , Sr 2+ ) iso-cyamelurates with ultra-large π-conjugated group and excellent nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaoguang Du, Fangyan Wang, Fei Liang, Zhanggui Hu, Yicheng Wu, Xinyuan Zhang

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  11. Recent advances on the synthesis of Sb(III)-based inorganic ultraviolet nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Gangji Yi, Guohong Zou

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  12. Deep Eutectic Solvents Synthesis of A2Sb(C2O4)Cl3 (A = NH4, K, Rb) with Superior Optical Performance

    Advanced Optical Materials · 2023-01-17

    Die Zhang, Qiang Wang, Han Luo, Liling Cao, Xuehua Dong, Ling Huang, Daojiang Gao, Guohong Zou

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  13. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  14. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  15. Host–Guest Symmetry Matching in Two Crystalline Magnesium Sulfate Oxalates Obtained Via a Solvent-Free Route

    Inorganic Chemistry · 2023-04-07

    Xuemei Wen, Ying Long, Daibing Luo, Ling Huang, Hongmei Zeng, Xin Wang, Guohong Zou, Zhien Lin

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  16. Sb4O3(TeO3)2(HSO4)(OH): An Antimony Tellurite Sulfate Exhibiting Large Optical Anisotropy Activated by Lone Pair Stereoactivity

    Inorganic Chemistry · 2023-04-21

    Xiaofei Li, Kui Wang, Chao He, Jinhua Li, Xing‐Tao An, Jie Pan, Qi Wei, Guo‐Ming Wang, Guo‐Yu Yang

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  17. KHC 2 O 4 · B ( OH ) 3 : A nonlinear optical crystal with large birefringence in the short‐wavelength ultraviolet region

    Bulletin of the Korean Chemical Society · 2023-05-23

    Yang Li, Jihyun Lee, Kang Min Ok

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  18. Centrosymmetric Rb2Sb(C2O4)2.5(H2O)3 and Noncentrosymmetric RbSb2(C2O4)F5: Two Antimony (III) Oxalates as UV Optical Materials

    Inorganic Chemistry · 2023-08-02

    Weiyi Wang, Xinyue Wang, Lu Xiong Xu, Die Zhang, Jiale Xue, Shuyao Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  19. NaCl·CH4N2O·H2O: An Organic–Inorganic Hybrid Ultraviolet Nonlinear Optical Crystal with Optimized Comprehensive Properties

    Inorganic Chemistry · 2023-08-09

    Tingting Huang, Ying Wang, Daqing Yang, Bingbing Zhang

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  20. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  21. C(NH2)3Cd(C2O4)Cl(H2O)·H2O and BaCd(C2O4)1.5Cl(H2O)2: Two Oxalate Chlorides Obtained by Chemical Scissors Strategy Exhibiting Low-Dimensional Structural Networks and Balanced Overall Optical Properties

    Inorganic Chemistry · 2023-12-19

    Wei Xu, Liang Ma, Yi‐Lei Lv, Siyu Ma, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  22. Recent advances in rational structure design for nonlinear optical crystals: leveraging advantageous templates

    Chemical Society Reviews · 2024-01-01

    Ziting Yan, Jinbin Fan, Shilie Pan, Min Zhang

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  23. Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units

    Chinese Journal of Structural Chemistry · 2024-04-13

    Dong‐Xue Jiao, Huili Zhang, Chao He, Siyu Chen, Ke Wang, Xiaohan Zhang, Li Wei, Qi Wei

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  24. Gradual Increase in Birefringence of Antimony Oxalates through Precise Tuning of the Sb3+/[C2O4]2– Ratio

    Inorganic Chemistry · 2024-07-11

    Dan Wang, Han Luo, Tingyu Wang, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  25. A novel sodium manganese fluorooxalate crystal Na2Mn2(C2O4)2.5F·2H2O: Synthesis, structure, optical and thermal properties

    Journal of Solid State Chemistry · 2024-09-27

    Sen Ji, Lei Kang, Yanyang Han, Shanshan Liu, Ye Liu, Ye Liu, Xin Yang, Kai Feng

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  26. Synthesis, structure and characterizations of the first alkali-metal/alkaline-earth-metal oxalatophosphate Na4Mg3(HPO4)4(C2O4)·2H2O

    Journal of Solid State Chemistry · 2024-11-01

    Sen Ji, Bo Xiao, Yanyang Han, Shanshan Liu, Ye Liu, Ye Liu, Xin Yang, Kai Feng

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  27. Unveiling Noncentrosymmetric Pyridine Carboxylates from Centrosymmetric Templates through Motif Configuration Modulation in Zero-Dimensional System

    Inorganic Chemistry · 2024-11-12

    Qingwen Zhu, Yong Tao, Can Yang, Jie Gou, Yaolong Zhu, Xuefei Wang, Qi Wu

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  28. Harnessing the dual role of DMSO in the synthesis of SbOCl·DMSO: an excellent nonlinear optical crystal with unique 1D spiral chain

    Inorganic Chemistry Frontiers · 2025-01-01

    Xiande Peng, Xiangyuan Li, Yingzi Zhang, Xuehua Dong, Ling Huang, Liling Cao, Daojiang Gao, Guohong Zou

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  29. Structural chemistry of antimony( iii ) oxalates with lone pairs: polyhedral distortion [SbO 4 F 2 ], π-conjugation [C 2 O 4 ], and birefringence tuning

    Dalton Transactions · 2025-01-01

    Yunxiao Zhang, Guangsheng Xu, Ke Li, Wei Jia, Xiaoyu Dong

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  30. Zwitterionic Glycine-Based Antimony Fluorides with Exceptional Ultraviolet Nonlinear Optical Properties

    Chemistry of Materials · 2025-01-20

    Yunseung Kuk, Zhiyong Bai, Yang Li, Kang Min Ok

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  31. (C6H10N2)ZnX4·H2O (X=Cl and Br): Excellent nonlinear optical properties and temperature induced photoluminescence for encryption

    Chemical Engineering Journal · 2025-03-09

    Chuanying Shen, Chenyi Zhang, Chenyi Zhang, Qiwei Xing, Defu Sun, Kui Wu, Bingbing Zhang, Jiyang Wang, Jiyang Wang, Duanliang Wang

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  32. Designing hybrid zinc-based ultraviolet nonlinear optical crystal with strong NLO response and dual-color luminescence via the integration of two different SHG-active genes

    Materials Today Chemistry · 2025-07-24

    Kang Yang, Duanliang Wang, Chuanrui Zhu, Kui Wu, Guangxia Liu, Jiyang Wang, Chuanying Shen

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  33. Designing Hybrid Sb-Based Nonlinear Optical Crystals with Large Birefringence by Combining the Lone Pair and π-Conjugated Genes

    Inorganic Chemistry · 2025-07-28

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  34. Hydrogen Bond-Assisted Structural Regulation Enables Large Birefringence in Two Antimony Oxalofluoride Crystals

    Inorganic Chemistry · 2025-08-05

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  35. Recent Progress in the Design and Synthesis of Nonlinear Optical Crystals with Stereochemically Active Lone Pairs

    European Journal of Inorganic Chemistry · 2025-08-26

    Xuehua Dong, Ling Huang, Guohong Zou

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  36. [C(NH 2 ) 3 ]SbCl 4 : An NLO Material with Enhanced Second Harmonic Response and Birefringence

    Inorganic Chemistry · 2026-01-23

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  37. The electronic structures, refractive indices and Berry curvature induced by the spin-orbit coupling in BiOX compounds: A first-principles investigation

    Physics Letters A · 2026-04-16

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  38. Enhancing the Performance of Antimony‐Based Materials in Sodium‐Ion Batteries through Synthesis and Modification

    Batteries & Supercaps · 2026-05-18

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