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RESEARCH PAPER · Inorganic Chemistry · 2022

The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)3

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The Role of the Bi3+ Lone Pair Effect in Bi(H3O)(SO4)2, Bi(HSO4)3, and Bi2(SO4)3OriginalHg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra27Crystal structure, optical properties and thermal properties of M 2 [W 2 O 3 (SO 4 ) 6 ] (M = Y, Eu, Tb, Lu, Bi)8Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence50AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems9Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )5Mössbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior1Mößbauer‐Spektroskopie an Antimon‐Borosulfaten belegt deren schwache Koordinationskraft1Metal cation effects on the structural, optical and thermal properties of double tungstates AM(WO 4 ) 2 (A = Li, Na, K; M = Y, La, Ce, Pr, Nd, Sm, Bi)0Isolation and Structural Elucidation of the Pnictogen Polysulfate Compounds As 2 [S 2 O 7 ] 2 [S 3 O 10 ] and [SeCl 3 ][Pn(S 2 O 7 ) 2 ] (Pn = Sb, Bi)0

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  1. Hg3(SeO3)2(SO4): A UV Nonlinear Optical Mercury Selenite Sulfate Constructed by Neat [Hg6O8(SeO3)4]∞ Layers and SO4 Tetrahedra

    Inorganic Chemistry · 2023-05-31

    Jinxuan Ren, Yuqi Chen, Liying Ren, Yuqiao Zhou, Xuehua Dong, Daojiang Gao, Ling Huang, Liling Cao, Ning Ye

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  2. Crystal structure, optical properties and thermal properties of M 2 [W 2 O 3 (SO 4 ) 6 ] (M = Y, Eu, Tb, Lu, Bi)

    Dalton Transactions · 2024-01-01

    Vivien Wessels, Sofia Kügle, Henning A. Höppe

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  3. Metal Methanesulfonates with Mixed Anionic Groups with Large Band Gaps and Enhanced Birefringence

    Chemistry of Materials · 2024-02-16

    Mingli Liang, Yujie Zhang, Eugene Izvarin, Michael J. Waters, James M. Rondinelli, P. Shiv Halasyamani

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  4. AYSO4F2 (A = K, Rb): [YO4F4] Polyhedra Enhancement of Birefringence in Non-π-Conjugated Sulfate Systems

    Inorganic Chemistry · 2024-02-27

    Zhencheng Wu, Huimin Li, Xueling Hou, Zhihua Yang, Hongsheng Shi

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  5. Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )

    Chemistry - A European Journal · 2025-10-05

    Erich Turgunbajew, Matthias Hämmer, Lkhamsuren Bayarjargal, Florian Pielnhofer, Henning A. Höppe

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  6. Mössbauer Spectroscopy on Antimony Borosulfates Reveals Weak Coordination Behavior

    Angewandte Chemie International Edition · 2025-12-12

    Erich Turgunbajew, Gwendolyn Buchner, Aylin Koldemir, Theresa Block, Rainer Pöttgen, David Hemker, Richard Dronskowski, Henning A. Höppe

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  7. Mößbauer‐Spektroskopie an Antimon‐Borosulfaten belegt deren schwache Koordinationskraft

    Angewandte Chemie · 2025-12-12

    Erich Turgunbajew, Gwendolyn Buchner, Aylin Koldemir, Theresa Block, Rainer Pöttgen, David Hemker, Richard Dronskowski, Henning A. Höppe

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  8. Metal cation effects on the structural, optical and thermal properties of double tungstates AM(WO 4 ) 2 (A = Li, Na, K; M = Y, La, Ce, Pr, Nd, Sm, Bi)

    Dalton Transactions · 2026-01-01

    Vivien Wessels, Matthias Hämmer, Florian Becker, Anja Sandner, Narayan Simrit Kaur, Henning A. Höppe

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  9. Isolation and Structural Elucidation of the Pnictogen Polysulfate Compounds As 2 [S 2 O 7 ] 2 [S 3 O 10 ] and [SeCl 3 ][Pn(S 2 O 7 ) 2 ] (Pn = Sb, Bi)

    Zeitschrift für anorganische und allgemeine Chemie · 2026-07-13

    Jan Langwald, Luisa Ebels, Marios Symeonidis, Jörn Bruns, Antonio Frontera, Mathias Siegfried Wickleder

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