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RESEARCH PAPER · CrystEngComm · 2021

Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterization

Chao Wu, Lin Lin, Tianhui Wu, Zhipeng Huang, Chi Zhang

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Deep-ultraviolet transparent alkali metal–rare earth metal sulfate NaY(SO 4 ) 2 ·H 2 O as a nonlinear optical crystal: synthesis and characterizationOriginalHydrothermal Synthesis, Crystal Structure, and Spectroscopic Properties of Pure and Eu3+-Doped NaY[SO4]2 ∙ H2O and Its Anhydrate NaY[SO4]212Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties5Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)216Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures8Advances in second-order nonlinear optical sulfates38Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence50Defect engineering of second-harmonic generation in nonlinear optical semiconductors18Study of Zinc Oxide Varistors by Incorporating Alkaline-Earth and Rare-Earth Metal Nanofillers0A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency7Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra10Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal16Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation41Optimized arrangement of non-π-conjugated PO 3 NH 3 units leads to enhanced ultraviolet optical nonlinearity in NaPO 3 NH 328RbY(SO4)2·4H2O: A new ultraviolet birefringent crystal3Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal11[C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence10Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission3Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy6Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges0Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )5Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal9Na3RE(PO4)2 with a Glaserite-Like Structure: The Effect of Cation on Structural Evolution2Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges1BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution0RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design2Synthesis of Chinleite(Ce) composite through ceric ammonium nitrate, graphite and its conversion to CeO2/RGO for removal of crystal violet from water0Stability of uracil in different sulphates under Martian-like UV irradiation0

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  1. Hydrothermal Synthesis, Crystal Structure, and Spectroscopic Properties of Pure and Eu3+-Doped NaY[SO4]2 ∙ H2O and Its Anhydrate NaY[SO4]2

    Crystals · 2021-05-21

    Constantin Buyer, David Enseling, Thomas Jüstel, Thomas Schleid

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  2. Structural Features of Y2O2SO4 via DFT Calculations of Electronic and Vibrational Properties

    Materials · 2021-06-11

    Aleksandr S. Oreshonkov, Yuriy G. Denisenko

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  3. Synthesis, Crystal Structure, and Nonlinear Optical Property of an Anhydrous Sulfate KTb(SO4)2

    Inorganic Chemistry · 2021-09-16

    Qi Wu, Can Yang, Jie Ma, Fei Liang, Chunlin Teng, Yeshuang Du

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  4. Li 3 [Al(PO 4 ) 2 (H 2 O) 1.5 ] and Na[AlP 2 O 7 ]: from 2D layered polar to 3D centrosymmetric framework structures

    CrystEngComm · 2022-01-01

    Xinlei Li, Yang Zhang, Yang Pan, Yucheng Hao, Yuan Hua Lin, Haijian Li, Minghua Li, Changzeng Fan, Evgeny V. Alekseev

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  5. Advances in second-order nonlinear optical sulfates

    Coordination Chemistry Reviews · 2022-02-17

    Yaoguo Shen, Wenyue Tang, Xiaoxin Lin

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  6. Two Metal Phosphate Nonlinear Optical Materials Simultaneously Exhibiting Ultraviolet Transparence and a Large Birefringence

    Chemistry of Materials · 2022-06-24

    Jiarong Lv, Yanyan Qian, Qun Jing, Xinmei Wang, Ming‐Hsien Lee, Zhaohui Chen

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  7. Defect engineering of second-harmonic generation in nonlinear optical semiconductors

    Cell Reports Physical Science · 2022-11-01

    Pei Li, Xiao Jiang, Menglin Huang, Lei Kang, Shiyou Chen, Ádám Gali, Bing Qiang Huang

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  8. Study of Zinc Oxide Varistors by Incorporating Alkaline-Earth and Rare-Earth Metal Nanofillers

    Nanosistemi Nanomateriali Nanotehnologii · 2022-12-01

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  9. A lithium–scandium sulfate with second-harmonic generation response and deep-ultraviolet transparency

    Dalton Transactions · 2023-01-01

    Zilong Geng, Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xin‐Tao Wu

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  10. Enhancing birefringence of non-π-conjugated sulfate systems through rare-earth metal-centered polyhedra

    CrystEngComm · 2023-01-01

    Jingdong Yan, Dongdong Chu, Fangfang Zhang, Zhihua Yang, Shilie Pan, Xueling Hou

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  11. Li2.9Cs1.1(SO4)2: An Ultraviolet Transparent Sulfate as a Nonlinear Optical Crystal

    Crystal Growth & Design · 2023-06-27

    Wen Zhi Yang, Lehui Liu, Lizhen Zhang, Yisheng Huang, Feifei Yuan, Zhoubin Lin

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  12. Nonlinear optical inorganic sulfates: The improvement of the phase matching ability driven by the structural modulation

    Coordination Chemistry Reviews · 2023-08-02

    Yanran Shang, Junxin Xu, Hongyuan Sha, Zujian Wang, Chao He, Rongbing Su, Xiaoming Yang, Xifa Long

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  13. Optimized arrangement of non-π-conjugated PO 3 NH 3 units leads to enhanced ultraviolet optical nonlinearity in NaPO 3 NH 3

    Inorganic Chemistry Frontiers · 2024-01-01

    Lingli Wu, Haotian Tian, Chensheng Lin, Xin Yi Zhao, Huixin Fan, Pengxiang Dong, Shunda Yang, Ning Ye, Min Luo

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  14. RbY(SO4)2·4H2O: A new ultraviolet birefringent crystal

    Journal of Solid State Chemistry · 2024-01-24

    Wencheng Lu, Yaoguo Shen, Qiong Sen Wu

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  15. Deep-Ultraviolet Bialkali–Rare Earth Metal Anhydrous Sulfate Birefringent Crystal

    Inorganic Chemistry · 2024-05-31

    Yunqi Zhao, Yipeng Song, Yanqiang Li, Wei Liu, Zhou Yang, Weiqi Huang, Junhua Luo, Sangen Zhao, Belal Ahmed

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  16. [C(NH2)3]10(MoO3)10(PO4)2(HPO4)2·5H2O: Synergy effect of multiple functional units results in significant birefringence

    Journal of Solid State Chemistry · 2024-06-12

    Yang Zhang, Yang Zhang, Meng-Han Lv, Shu‐Fang Li, Hongbo Huang, Bingbing Zhang, Dong Yan

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  17. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  18. NH4Y(SO4)2·H2O and NH4YSO4F2: Two New Ammonium‐Rare Earth Metal Sulfates with Enhanced Optical Anisotropy and Deep Ultraviolet Transmission

    Crystal Research and Technology · 2024-07-19

    Luyong Zhang, Shibin Wang, Zhencheng Wu, Xueling Hou, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  19. Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

    Inorganic Chemistry · 2024-10-07

    Zichang Wang, Jianyi Zuo, Qing‐Yu Liu, Xueling Hou, Minqiang Gai

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  20. Exploring Novel Mixed Metal Sulfate Hydrates with Short UV Cut-Off Edges

    SSRN Electronic Journal · 2025-01-01

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  21. Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2 Sb 4 S 10 (S 2 )

    Inorganic Chemistry Frontiers · 2025-01-01

    Jingdong Yan, Xiangran Kong, Shichao Cheng, Tao Liu, Hongwei Leng, Yunfei Shang, Zuotao Lei, Chunhui Yang

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  22. Designing a 3‐Hydroxypropane‐1‐Sulfonate Deep‐Ultraviolet Nonlinear Optical Crystal

    Small · 2025-05-02

    Yuexin Zhang, Zhengnan Yuan, Yanqiang Li, Yipeng Song, Weiqi Huang, Yao Yao, Ji Qi, Zhiyong Bai, Sangen Zhao, Junhua Luo

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  23. Na3RE(PO4)2 with a Glaserite-Like Structure: The Effect of Cation on Structural Evolution

    Inorganic Chemistry · 2025-05-29

    Mei Hu, Xinmei Wang, Hongheng Chen, Qun Jing, Zhaohui Chen

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  24. Rational design of novel mixed metal sulfates with diverse dimensional structures and short UV cutoff edges

    Journal of Molecular Structure · 2025-11-22

    Bingchen Xiao, Yanyan Ding, Jindan Tian, Lei Hou, Ming Xi, Ruoyan Qv, Yaoqing Chu, Lili Liu

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  25. BiCe(SO 4 ) 3 (H 2 O) 3 : a non-centrosymmetric bismuth cerium( iii ) sulfate with second-order nonlinear optical activity arising from strategic heterovalent cationic substitution

    Chemical Communications · 2026-01-01

    Zheng-Yu Yang, C. Z. Chen, Bing-Wei Miao, Yi‐Lei Lv, Wenfeng Zhou, Ming‐Yang Cao, Ru‐Ling Tang

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  26. RbLa(SO 4 ) 2 : A KBBF-like Deep-UV Transparent Rare Earth Sulfate with Strong SHG Response and High Thermal Stability Enabled by Multicomponent Structural Design

    Inorganic Chemistry · 2026-02-02

    Ye Tao, Xiaohui Zhang, Chenglong Xu, Qianshuang Lu, J. N. Tan, Yingjie Li, Junzi Li, Jianke Pan, Feng Su, Tingchao He, Haifeng Dong, Heng Wang, Zhi Chen, Chengmin Ji, Xiujun Yu, Xiaopeng Li

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  27. Synthesis of Chinleite(Ce) composite through ceric ammonium nitrate, graphite and its conversion to CeO2/RGO for removal of crystal violet from water

    Chemical Papers · 2026-06-29

    Pooja Yadav, Neeru Dabas

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  28. Stability of uracil in different sulphates under Martian-like UV irradiation

    Icarus · 2026-09-05

    Cristina García‐Florentino, Teresa Fornaro, Sole Biancalani, Andrew Alberini, Domenica Marabello, Francesco Renzi, Giovanni Poggiali, Mariano Battistuzzi, Juan Manuel Madariaga, J. Martinez-Frias, J. R. Brucato

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