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RESEARCH PAPER · Inorganic Chemistry · 2012

Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba)

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Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A = Sr, Pb, and Ba)OriginalNoncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity52Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)450ChemInform Abstract: Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A: Sr, Pb, and Ba).0Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)28Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)47Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)33Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement117ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)247New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO69New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76K[AsW2O9], the first member of the arsenate–tungsten bronze family: Synthesis, structure, spectroscopic and non-linear optical properties47Hydrothermal Synthesis of Zn2(MoO4)(SeO3) and Photocatalytic Applications0A new phase in the MnII–SeIV–MoVI–O system, Mn(MoO3)(SeO3)(H2O): Hydrothermal synthesis, crystal structure and properties2New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)613VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Second harmonic generation by micropowders: a revision of the Kurtz–Perry method and its practical application40Strong enhancement of second harmonic generation in nonlinear optical crystals: 2-amino-3-nitropyridinium halides (Cl, Br, I)20Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites18Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F5Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33A series of new silver selenites with d 0 -TM cations19KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO1057LiSc(SeO3)2·xH2O (0 ≤ x ≤ 1): New Selenites Revealing Water Molecule-Driven Extremely High Temperature Single-Crystal-to-Single-Crystal Transformations16Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation382Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Variable dimensionality and framework found in a series of quaternary zinc selenites, A 2 Zn 3 (SeO 3 ) 4 · x H 2 O (A = Na, Rb, and Cs; 0≤ x ≤1) and Cs 2 Zn 2 (SeO 3 ) 3 ·2H 2 O7Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Organically templated inorganic–organic hybrid metal (Zn and Cd) Sulfite–oxalates with layered and three-dimensional structures7Structural diversities induced by cation sizes in a series of fluorogermanophosphates: A 2 [GeF 2 (HPO 4 ) 2 ] (A = Na, K, Rb, NH 4 , and Cs)4Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)13Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Designing Deep‐UV Birefringent Crystals by Cation Regulation57Mo6+ Cation Enrichment of the Structure Chemistry of Iodates: Syntheses, Structures, and Calculations of Ba(MoO2)2(IO3)4O, Ba3[(MoO2)2(IO3)4O(OH)4]·2H2O, and Sr[(MoO2)6(IO4)2O4]·H2O24Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4CO(NH 2 ) 2 ·NH 4 Cl: an ultraviolet birefringent material with conjugated CO groups16The crystal structure of visible light absorbing piezoelectric semiconductor SrNb 2 V 2 O 11 revisited: high-resolution X-ray diffraction, vibrational spectroscopy and computational study4Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8A new barium-containing alkali metal silicate fluoride NaBa3Si2O7F with deep-UV optical property12Hexagonal tungsten oxides with large bandgaps synthesized by a chemical substitution method31Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Volume Modulation of Nonlinear Optical Properties by Cation Substitution8A 3 BBi(P 2 O 7 ) 2 (A = Rb, Cs; B = Pb, Ba): Isovalent Cation Substitution to Sustain Large Second-Harmonic Generation Responses106Ba(MoO2F)2(XO3)2 (X = Se and Te): First Cases of Noncentrosymmetric Fluorinated Molybdenum Oxide Selenite/Tellurite Through Unary Substitution for Enlarging Band Gaps and Second Harmonic Generation34Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution73An Effective Strategy for Designing Nonlinear Optical Crystals by Combining the Structure‐Directing Property of Oxyfluorides with Chemical Substitution10Novel structural transformation in K3ReP2S8 thiophosphates originating from the rare-earth (Re) cation sizes induced local coordination asymmetry25Effect of strain on the band structure and optical properties of Na2Bi2(SeO3)3F21Mg 2 Pb 2 Si 2 O 7 F 2 : a new lead-containing alkali earth metal silicate fluoride with a short cutoff edge2Noncentrosymmetric γ-Cs2I4O11 Obtained from IO4 Polyhedral Rearrangements in the Centrosymmetric β-Phase16Designing a Strong Second-Harmonic Generation Polar Iodate by the Structure-Directing Properties of the “Tumbler-like” [Zn(IO3)(I2O5(OH))] Polyanions20Exploring a new short-wavelength nonlinear optical fluoride material featuring unprecedented polar cis -[Zr 6 F 34 ] 10− clusters48Reticular chemistry-aided effective design of new second-order nonlinear optical selenites11Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10InO6X (X = Cl, Br): distinct functional motif family for nonlinear optical materials5

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  1. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    Journal of Solid State Chemistry · 2012-06-20

    J. Palmer West, Shiou‐Jyh Hwu

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  2. Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4

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  3. ChemInform Abstract: Influence of the Cation Size on the Framework Structures and Space Group Centricities in AMo2O5(SeO3)2 (A: Sr, Pb, and Ba).

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  4. Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)

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  5. Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

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  6. Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)

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    Seung‐Jin Oh, Yiseul Shin, T. Thao Tran, Dong Woo Lee, Anne Yoon, P. Shiv Halasyamani, Kang Min Ok

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  7. Pb2TiOF(SeO3)2Cl and Pb2NbO2(SeO3)2Cl: small changes in structure induced a very large SHG enhancement

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    Xue‐Li Cao, Chun‐Li Hu, Xiang Xu, Fang Kong, Jiang‐Gao Mao

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  8. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

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    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  9. Synthesis, Structure, and Characterization of Two New Polar Sodium Tungsten Selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)2

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  10. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

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  11. Large scale synthesis, second-harmonic generation, and piezoelectric properties of a noncentrosymmetric vanadium phosphate, Li2VPO6

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  12. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

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  13. K[AsW2O9], the first member of the arsenate–tungsten bronze family: Synthesis, structure, spectroscopic and non-linear optical properties

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  14. Hydrothermal Synthesis of Zn2(MoO4)(SeO3) and Photocatalytic Applications

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  15. A new phase in the MnII–SeIV–MoVI–O system, Mn(MoO3)(SeO3)(H2O): Hydrothermal synthesis, crystal structure and properties

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  16. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

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  17. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

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  18. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

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  19. From an Open Framework to a Layered and a Hexagonal Tungsten Oxide Structure: Controlled Transformation Reactions of an Extended Solid-State Material, Cs3Ga7(SeO3)12 to Ga(OH)(SeO3) and KGa3(SeO4)2(OH)6

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  20. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

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  21. Second harmonic generation by micropowders: a revision of the Kurtz–Perry method and its practical application

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  22. Strong enhancement of second harmonic generation in nonlinear optical crystals: 2-amino-3-nitropyridinium halides (Cl, Br, I)

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  23. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

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  24. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

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  26. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

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  27. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

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  28. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

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  29. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

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  30. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

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  31. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

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  32. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

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  33. Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O8

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  34. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

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  35. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

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  36. Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)

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  37. pH Controlled Pathway and Systematic Hydrothermal Phase Diagram for Elaboration of Synthetic Lead Nickel Selenites

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  38. Synthesis, Crystal Structure, and Properties of the Sodium Molybdate Fluoride Na3MoO4F

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  39. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

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  40. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

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  41. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

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  42. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

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  43. A series of new silver selenites with d 0 -TM cations

    RSC Advances · 2016-01-01

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  44. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

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