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RESEARCH PAPER · Inorganic Chemistry · 2014

Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

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Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)OriginalChemInform Abstract: Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A: Na, K, Rb, and Cs).0Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations9A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Editorial for the ACS Select Collection on Solid-State Chemistry1Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites16Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Synthesis, Crystal Structures, and Optical Properties of AM2(OH)(SeO3)2 (A = Na, Rb; M = Mg, Zn)4Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)15Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response96IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge109Diverse Lanthanide Coordination and Selective Ion Exchange in the Microporous Selenites Na4Ln4(SeO3)7O·nH2O (Ln = Gd, Tb, Dy, Ho, Er, Tm, and Yb)5Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)33Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO1057BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)17Variable dimensionality and framework found in a series of quaternary zinc selenites, A 2 Zn 3 (SeO 3 ) 4 · x H 2 O (A = Na, Rb, and Cs; 0≤ x ≤1) and Cs 2 Zn 2 (SeO 3 ) 3 ·2H 2 O7Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures36Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5Hydrothermal Synthesis and Crystal Structures of Na2Be3(SeO3)4·H2O and Cs2[Mg(H2O)6]3(SeO3)45A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides14Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge4Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 913LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition12IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes15Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Structure, Photoluminescence Emissions, and Photocatalytic Activity of Ag2SeO3: A Joint Experimental and Theoretical Investigation23Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds36Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag 2 SeO 4 : combining experimental data and theoretical insights10The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap5Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds20A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation41Ferromagnetic Mn3+ Sawtooth Chains in A2(Mn2O)(SeO3)3 (A = K, Rb) Quaternary Selenites0Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response3A generative material transformer using Wyckoff representation9

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  1. ChemInform Abstract: Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A: Na, K, Rb, and Cs).

    ChemInform · 2014-06-20

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  2. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  3. Sr3Bi2(SeO3)6·H2O: A novel anionic layer consisting of second-order Jahn–Teller (SOJT) distortive cations

    Journal of Solid State Chemistry · 2014-09-30

    Hyun Sun Ahn, Eun Pyo Lee, Hong‐Young Chang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  4. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·
  5. Editorial for the ACS Select Collection on Solid-State Chemistry

    Inorganic Chemistry · 2014-10-20

    P. Shiv Halasyamani

    Read original paper ↗ ·
  6. Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O8

    Inorganic Chemistry · 2014-12-17

    Youngkwon Kim, Dong Woo Lee, Kang Min Ok

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  7. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

    Inorganic Chemistry Frontiers · 2015-01-01

    Yeong Hun Kim, T. Thao Tran, P. Shiv Halasyamani, Kang Min Ok

    Read original paper ↗ ·
  8. Structural and magnetic studies on three new mixed metal copper( ii ) selenites and tellurites

    Dalton Transactions · 2015-01-01

    Xue‐Li Cao, Fang Kong, Zhangzhen He, Jiang‐Gao Mao

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  9. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·
  10. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

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  11. Synthesis, Crystal Structures, and Optical Properties of AM2(OH)(SeO3)2 (A = Na, Rb; M = Mg, Zn)

    Zeitschrift für anorganische und allgemeine Chemie · 2015-07-22

    Yunsheng Liu, Dajiang Mei, Jingli Xu, Yuandong Wu

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  12. Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)

    Journal of Solid State Chemistry · 2015-10-02

    Yunsheng Liu, Dajiang Mei, Jingli Xu, Yuandong Wu

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  13. Oxychalcogenide BaGeOSe2: Highly Distorted Mixed-Anion Building Units Leading to a Large Second-Harmonic Generation Response

    Chemistry of Materials · 2015-11-25

    Bin‐Wen Liu, Xiao‐Ming Jiang, Guan‐E Wang, Hui‐Yi Zeng, Mingjian Zhang, Shu‐Fang Li, Wei‐Huan Guo, Guo‐Cong Guo

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  14. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

    Springer mineralogy · 2016-01-01

    Nikita V. Chukanov, A. D. Chervonnyi

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  15. KPb 2 (PO 3 ) 5 : a novel nonlinear optical lead polyphosphate with a short deep-UV cutoff edge

    Journal of Materials Chemistry C · 2016-01-01

    Maierhaba Abudoureheman, Shujuan Han, Bing‐Hua Lei, Zhihua Yang, Xifa Long, Shilie Pan

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  16. Diverse Lanthanide Coordination and Selective Ion Exchange in the Microporous Selenites Na4Ln4(SeO3)7O·nH2O (Ln = Gd, Tb, Dy, Ho, Er, Tm, and Yb)

    Crystal Growth & Design · 2016-01-14

    Teresa M. Eaton, Ryan A. Groom, Mark A. Silver, Thomas E. Albrecht‐Schmitt

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  17. Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)

    Journal of Solid State Chemistry · 2016-01-16

    Shujuan Han, Chunyan Bai, Bingbing Zhang, Zhihua Yang, Shilie Pan

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  18. New Series of Polar and Nonpolar Platinum Iodates A2Pt(IO3)6 (A = H3O, Na, K, Rb, Cs)

    Inorganic Chemistry · 2016-02-05

    Bing‐Ping Yang, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  19. Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO10

    Chemistry of Materials · 2016-03-23

    Hyung Gu Kim, T. Thao Tran, Woongjin Choi, Tae‐Soo You, P. Shiv Halasyamani, Kang Min Ok

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  20. BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution

    Journal of the American Chemical Society · 2016-07-18

    Mingli Liang, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  21. Syntheses, characterization and theoretical studies of three apatite-type phosphates MPb4(PO4)3 (M = K, Rb, Cs)

    Journal of Alloys and Compounds · 2016-08-20

    Maierhaba Abudoureheman, Shujuan Han, Xiaoyu Dong, Bing‐Hua Lei, Ying Wang, Zhihua Yang, Xifa Long, Shilie Pan

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  22. Variable dimensionality and framework found in a series of quaternary zinc selenites, A 2 Zn 3 (SeO 3 ) 4 · x H 2 O (A = Na, Rb, and Cs; 0≤ x ≤1) and Cs 2 Zn 2 (SeO 3 ) 3 ·2H 2 O

    Journal of Solid State Chemistry · 2016-10-07

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  23. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  24. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

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  25. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  26. New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )

    Journal of Solid State Chemistry · 2017-02-16

    Mingli Liang, Matthew L. Marsh, Xian-Xing Shang, Jiang‐Gao Mao, Thomas E. Albrecht‐Schmitt, Fang Kong

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  27. A3Sr2P7O21 (A = Rb, Cs): Two Polyphosphates Based on Different Types of P–O Chains and Ring Structures

    Inorganic Chemistry · 2017-03-15

    Maierhaba Abudoureheman, Shujuan Han, Ying Wang, Bing‐Hua Lei, Zhihua Yang, Shilie Pan

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  28. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  29. Hydrothermal Synthesis and Crystal Structures of Na2Be3(SeO3)4·H2O and Cs2[Mg(H2O)6]3(SeO3)4

    Zeitschrift für anorganische und allgemeine Chemie · 2017-07-27

    Chen Shen, Dajiang Mei, Chuanling Sun, Yunsheng Liu, Yuandong Wu

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  30. A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides

    Dalton Transactions · 2018-01-01

    Shuangshuang Shi, Min Luo, Chensheng Lin, Ning Ye

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  31. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  32. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

    Inorganic Chemistry · 2018-03-07

    Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  33. Noncentrosymmetric cubic RbBSi2O6 polymorph with deep ultraviolet cut-off edge

    Solid State Sciences · 2018-12-01

    Kun Chai, Hongyi Li, Mingyuan Zhu, Bin Dai

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  34. Synthesis and nonlinear optical properties of new gallium thiophosphate Rb 2 Ga 2 P 2 S 9

    New Journal of Chemistry · 2019-01-01

    Qichang Hu, Kaibin Ruan, Yuzhu Wang, Kai Ding, Yong Nan Xu

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  35. LiBa2MIIIQ4 (MIII = Al, Ga, In; Q = S, Se): A Series of Metal Chalcogenides with a Structural Transition

    Inorganic Chemistry · 2019-09-12

    Ailijiang Abudurusuli, Kui Wu, Junjie Li, Alimujiang Yalikun, Zhihua Yang, Shilie Pan

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  36. IR Spectra of Minerals and Related Compounds, and Reference Samples Data

    Springer mineralogy · 2019-11-28

    Nikita V. Chukanov, Marina F. Vigasina

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  37. Unexpected Roles of Alkali-Metal Cations in the Assembly of Low-Valent Uranium Sulfate Molecular Complexes

    Inorganic Chemistry · 2020-02-04

    Zenghui Yue, Xiaofeng Guo, Mei‐Ling Feng, Yue‐Jian Lin, Yu Ju, Xiao Lin, Zhi‐Hui Zhang, Xiao-Jing Guo, Jian Hung Lin, Yuying Huang, Jian‐Qiang Wang

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  38. Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.5

    Chemical Communications · 2021-01-01

    Shuangshuang Shi, Chensheng Lin, Dan Zhao, Min Luo, Liling Cao, Guang Peng, Ning Ye

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  39. Structure, Photoluminescence Emissions, and Photocatalytic Activity of Ag2SeO3: A Joint Experimental and Theoretical Investigation

    Inorganic Chemistry · 2021-03-26

    Ivo M. Pinatti, Aline B. Trench, Ana C. M. Tello, Paula F. S. Pereira, Josiane Carneiro Souza, Marcio Daldin Teodoro, Ieda L. V. Rosa, Juán Andrés, E. Longo, Alexandre Zirpoli Simoes

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  40. Hg 2 (SeO 3 )(SO 4 ): the first sulfate selenite with large birefringence explored from d 10 transition metal compounds

    Materials Chemistry Frontiers · 2022-01-01

    Pengfei Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  41. Towards a relationship between photoluminescence emissions and photocatalytic activity of Ag 2 SeO 4 : combining experimental data and theoretical insights

    Dalton Transactions · 2022-01-01

    Ivo M. Pinatti, Ana C. M. Tello, Paula F. S. Pereira, Aline B. Trench, Marcio Daldin Teodoro, Ieda L. V. Rosa, Albérico B. F. da Silva, E. Longo, Juán Andrés, Alexandre Zirpoli Simoes

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  42. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 4

    Angewandte Chemie International Edition · 2023-02-27

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  43. The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)4

    Angewandte Chemie · 2023-02-27

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  44. AKTeO2(CO3) (A = Li, Na): The First Carbonatotellurites Featuring a Zero-Dimensional [Te2C2O10]4– Cluster and a Wide Band Gap

    Inorganic Chemistry · 2023-04-20

    Pengfei Chen, Chun‐Li Hu, Ming-Yang Cao, Xueying Zhang, Jiang‐Gao Mao

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  45. Y(HSeO3)(SeO3)(H2O)·(H2O) and Y2(SeO3)2(SeO4)(H2O)2·(H2O)0.75: Two yttrium selenites with a short UV cut-off edge explored from pure selenite compounds

    Journal of Alloys and Compounds · 2023-05-15

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  46. A UV non-hydrogen pure selenite nonlinear optical material for achieving balanced properties through framework-optimized structural transformation

    Materials Horizons · 2024-01-01

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  47. Ferromagnetic Mn3+ Sawtooth Chains in A2(Mn2O)(SeO3)3 (A = K, Rb) Quaternary Selenites

    Inorganic Chemistry · 2024-05-24

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  48. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

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  49. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

    Inorganic Chemistry · 2024-10-08

    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  50. A-Site Cation Substitution toward Structural Transformation in Phosphates Exhibiting Short UV Transparency and Second Harmonic Response

    Inorganic Chemistry · 2025-08-11

    Hanjing Huang, Xianghao Kong, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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