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RESEARCH PAPER · RSC Advances · 2013

ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building unitsOriginalThe role of dipole moment in determining the nonlinear optical behavior of materials: ab initio studies on quaternary molybdenum tellurite crystals123A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation121How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism19Growth and characterization of nonlinear optical telluromolybdate CoTeMoO 6 single crystals17Microscopic Origins of Optical Second Harmonic Generation in Noncentrosymmetric–Nonpolar Materials87Relationship between structure and cleavage behavior in the nonlinear optical crystal MnTeMoO 610Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Top-seeded solution crystal growth of noncentrosymmetric and polar Zn2TeMoO7 (ZTM)32Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis441New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14169Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)11Thermal Expansion and Second Harmonic Generation Response of the Tungsten Bronze Pb2AgNb5O1515LiNa 5 Mo 9 O 30 : Crystal Growth, Linear, and Nonlinear Optical Properties79Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Synthesis, crystal structure, optical property and theoretical studies of a noncentrosymmetric telluromolybdate CoTeMoO66Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)326PbTeGeO 6 : polar rosiaite-type germanate featuring a two dimensional layered structure24The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation14Controlled Growth of Layered Acentric CdTeMoO6 Single Crystals with Linear and Nonlinear Optical Properties50Investigations into anisotropic properties of the nonlinear optical material CdTeMoO6 with quasi-two-dimensional structure16Recent advances and future perspectives on infrared nonlinear optical metal halides223The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation26Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 128MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range66Recent progress in selenite and tellurite based SHG materials32AE2[Ni(Te4O10)Cl2] (AE = Ca, Sr, Ba, Pb): A New Type of Inorganic Compound Synthesized through the Recombination of Tellurium(IV) Oxide Anion Fragments by Introducing Post-transition-metal Halide NiCl22Microwave dielectric properties and chemical compatibility with alumina electrode of two novel ultra-low temperature firing ATeMoO6 (A = Mg, Zn) ceramics47A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)319Ca3(TeO3)2(MO4) (M = Mo, W): Mid-Infrared Nonlinear Optical Tellurates with Ultrawide Transparency Ranges and Superhigh Laser-Induced Damage Thresholds46LiNbTeO5: A High-Performance Multifunctional Crystal Material with a Very Large Second-Harmonic Generation Response and Piezoelectric Coefficient52Recent advances in tellurite molybdate/tungstate crystals15Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 1418Coordination metal effect on the nonlinear optical properties and biological activity of double selenates8Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap9A new stable polymorph of Li 2 TeMo 3 O 12 with wide mid-infrared transparency and a large Raman response17Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability40The effect of co-substitution of heterovalent ions Ga 3+ and Sb 5+ on nonlinear optical properties of phosphate crystals0Van der Waals quaternary oxides for tunable low-loss anisotropic polaritonics47La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra4K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window2Na Nonstoichiometric Modifications Unraveling the Sodium Ion Mobility and Transport Mechanism in Sodium Solid Electrolyte NaxZn2TeO65GLASS FORMATION AND PHASE TRANSFORMATIONS IN THE TeO2–ZnO–MoO3 SYSTEM0Glass Formation and Phase Transformations in the TeO2–ZnO–MoO3 System0Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy36Thermal expansion mismatch-driven high-pressure growth of 2D non-centrosymmetric MnTeMoO6 with giant nonlinear optical properties2DFT and hirshfeld surface analysis of the structural, vibrational, and electronic properties of noncentrosymmetric quaternary molybdenum oxides RTeMoO6 (R = Cd, Zn, Mg)0A promising mid-infrared nonlinear optical crystal with well-balanced properties0Regulating second harmonic generation of telluromolybdate materials by atomic substitution0中红外氧化物非线性光学晶体研究进展（特邀）0Origin of Large Second-Harmonic Generation in Nonpolar Molybdenum Tellurite Compounds0Simultaneous Strengthening and Toughening of Epoxy Resins via a Novel Inorganic Filler With Two‐Dimensional Nanostructure0A Telluromolybdate Mid-Infrared Nonlinear Optical Crystal with Wide Transparency and Strong Second-Harmonic Generation Response0

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  1. The role of dipole moment in determining the nonlinear optical behavior of materials: ab initio studies on quaternary molybdenum tellurite crystals

    Journal of Materials Chemistry C · 2013-11-06

    Xingxing Jiang, Sangen Zhao, Zheshuai Lin, Junhua Luo, Paul D. Bristowe, Xiangguo Guan, Chuangtian Chen

    Read original paper ↗ ·

  2. A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation

    Inorganic Chemistry · 2014-02-10

    Sangen Zhao, Jia Zhang, Shuquan Zhang, Zhihua Sun, Zheshuai Lin, Yicheng Wu, Maochun Hong, Junhua Luo

    Read original paper ↗ ·

  3. How Lewis Acidity of the Cationic Framework Affects KNaNbOF5 Polymorphism

    Inorganic Chemistry · 2014-06-12

    Kelvin B. Chang, Anastasiya I. Vinokur, Rachelle Ann F. Pinlac, Matthew R. Suchomel, Michael R. Marvel, Kenneth Reinhard Poeppelmeier

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  4. Growth and characterization of nonlinear optical telluromolybdate CoTeMoO 6 single crystals

    Journal of Solid State Chemistry · 2014-08-28

    Mirosław Mączka, K. Hermanowicz, A. Majchrowski, Łukasz Kroenke, A. Pietraszko, Maciej Ptak

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  5. Microscopic Origins of Optical Second Harmonic Generation in Noncentrosymmetric–Nonpolar Materials

    Chemistry of Materials · 2014-09-19

    Antonio Cammarata, Weiguo Zhang, P. Shiv Halasyamani, James M. Rondinelli

    Read original paper ↗ ·

  6. Relationship between structure and cleavage behavior in the nonlinear optical crystal MnTeMoO 6

    Journal of Crystal Growth · 2015-03-05

    Chengguo Jin, Lingxiong Huang, Junsheng Yang, Mingjie Wan, Zhen Li, Qilong Cao, Duohui Huang, Juxiang Shao, Fanhou Wang

    Read original paper ↗ ·

  7. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

    Inorganic Chemistry · 2015-08-26

    Seong‐eun Bang, Kang Min Ok

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  8. Top-seeded solution crystal growth of noncentrosymmetric and polar Zn2TeMoO7 (ZTM)

    Journal of Solid State Chemistry · 2015-08-31

    Weiguo Zhang, P. Shiv Halasyamani

    Read original paper ↗ ·

  9. Metal Thiophosphates with Good Mid-infrared Nonlinear Optical Performances: A First-Principles Prediction and Analysis

    Journal of the American Chemical Society · 2015-09-23

    Lei Kang, Molin Zhou, Jiyong Yao, Zheshuai Lin, Yicheng Wu, Chuangtian Chen

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  10. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  11. Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14

    Journal of the American Chemical Society · 2015-12-20

    Hongwei Yu, Weiguo Zhang, Joshua Young, James M. Rondinelli, P. Shiv Halasyamani

    Read original paper ↗ ·

  12. Synthesis, structure and optical properties of two isotypic crystals, Na3MO4Cl (M=W, Mo)

    Journal of Solid State Chemistry · 2016-01-16

    Shujuan Han, Chunyan Bai, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  13. Thermal Expansion and Second Harmonic Generation Response of the Tungsten Bronze Pb2AgNb5O15

    Inorganic Chemistry · 2016-02-29

    Kun Lin, Pifu Gong, Jing Wei Sun, Hongqiang Ma, You Wang, Li You, Jinxia Nancy Deng, Jun Chen, Zheshuai Lin, Kenichi Kato, Hui Wu, Qingzhen Huang, Xianran Xing

    Read original paper ↗ ·

  14. LiNa 5 Mo 9 O 30 : Crystal Growth, Linear, and Nonlinear Optical Properties

    Chemistry of Materials · 2016-06-09

    Weiguo Zhang, Hongwei Yu, Jacqueline Cantwell, Hongping Wu, Kenneth Reinhard Poeppelmeier, P. Shiv Halasyamani

    Read original paper ↗ ·

  15. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017-01-01

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

    Read original paper ↗ ·

  16. Synthesis, crystal structure, optical property and theoretical studies of a noncentrosymmetric telluromolybdate CoTeMoO6

    Journal of Alloys and Compounds · 2017-06-16

    Chengguo Jin, Zhen Li

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  17. Pb@Pb8 Basket-like-Cluster-Based Lead Tellurate–Nitrate Kleinman-Forbidden Nonlinear-Optical Crystal: Pb9Te2O13(OH)(NO3)3

    Inorganic Chemistry · 2017-06-26

    Yi-Gang Chen, Nan Qing Yang, Xingxing Jiang, Yao Guo, Xian‐Ming Zhang

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  18. PbTeGeO 6 : polar rosiaite-type germanate featuring a two dimensional layered structure

    Dalton Transactions · 2018-01-01

    Zhen Jia, Xingxing Jiang, Zheshuai Lin, Mingjun Xia

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  19. The relationship between covalent bonds and the optical response in a nonpolar family ATeMoO 6 (A=Mg, Zn, Cd): A Berry-phase investigation

    Journal of Solid State Chemistry · 2018-04-26

    Qiaoqiao Zhang, Qun Jing, Haiming Duan, Haibin Cao

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  20. Controlled Growth of Layered Acentric CdTeMoO6 Single Crystals with Linear and Nonlinear Optical Properties

    Crystal Growth & Design · 2018-05-02

    Conggang Li, Xiangxin Tian, Zeliang Gao, Qian Wu, Peng Zhao, Youxuan Sun, Chengqian Zhang, Shao-Jun Zhang, Deliang Cui, Xutang Tao

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  21. Investigations into anisotropic properties of the nonlinear optical material CdTeMoO6 with quasi-two-dimensional structure

    Journal of Alloys and Compounds · 2018-10-08

    Conggang Li, Zeliang Gao, Xiangxin Tian, Qian Wu, Fuan Liu, Xiaoli Du, Dongyang Huang, Youxuan Sun, Deliang Cui, Xutang Tao

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  22. Recent advances and future perspectives on infrared nonlinear optical metal halides

    Coordination Chemistry Reviews · 2018-10-23

    Pifu Gong, Fei Liang, Lei Kang, Xingguo Chen, Jingui Qin, Yicheng Wu, Zheshuai Lin

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  23. The linear and nonlinear optical response of CsGeX3 (X=Cl, Br, and I): The finite field and first-principles investigation

    Optik · 2018-10-25

    Qiaoqiao Zhang, Hahaer Mushahali, Haiming Duan, Ming‐Hsien Lee, Qun Jing

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  24. Investigation into the optimized growth, anisotropic properties and theoretical calculations of the polar material Cs 2 TeW 3 O 12

    CrystEngComm · 2019-01-01

    Conggang Li, Peng Zhao, Zeliang Gao, Qian Wu, Xiangxin Tian, Dianxing Ju, Weiqun Lu, Youxuan Sun, Deliang Cui, Xutang Tao

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  25. MnSiP2: A New Mid-IR Ternary Phosphide with Strong SHG Effect and Ultrabroad Transparency Range

    Chemistry of Materials · 2019-02-12

    Tongtong Yu, Shanpeng Wang, Xiang Zhang, Chenning Li, Jie Qiao, Ning Jia, Bing Q. Han, Sheng‐Qing Xia, Xutang Tao

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  26. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

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  27. AE2[Ni(Te4O10)Cl2] (AE = Ca, Sr, Ba, Pb): A New Type of Inorganic Compound Synthesized through the Recombination of Tellurium(IV) Oxide Anion Fragments by Introducing Post-transition-metal Halide NiCl2

    Crystal Growth & Design · 2020-02-06

    Chang‐Yu Meng, Feng Feng Huang, Qin Yao Li, Lei Geng

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  28. Microwave dielectric properties and chemical compatibility with alumina electrode of two novel ultra-low temperature firing ATeMoO6 (A = Mg, Zn) ceramics

    Ceramics International · 2020-07-07

    Mingyang Yu, Ying Tang, Jie Li, Weishuang Fang, Lian Duan, Liang Fang

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  29. A new nonlinear optical sulfate of layered structure: Cs2Zn2(SO4)3

    Inorganic Chemistry Communications · 2020-12-07

    Youchao Liu, Yanqiang Li, Yang Zhou, Qingran Ding, Yangxin Chen, Sangen Zhao, Junhua Luo

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  30. Ca3(TeO3)2(MO4) (M = Mo, W): Mid-Infrared Nonlinear Optical Tellurates with Ultrawide Transparency Ranges and Superhigh Laser-Induced Damage Thresholds

    Inorganic Chemistry · 2021-11-07

    Qian Wu, Jingfang Zhou, Xiaomeng Liu, Xingxing Jiang, Qiaoxin Zhang, Zheshuai Lin, Mingjun Xia

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  31. LiNbTeO5: A High-Performance Multifunctional Crystal Material with a Very Large Second-Harmonic Generation Response and Piezoelectric Coefficient

    Chemistry of Materials · 2021-12-17

    Kaichuang Chen, Chensheng Lin, Guang Peng, Yu Chen, Haizhou Huang, Enze Chen, Yunxiao Min, Tao Yan, Min Luo, Ning Ye

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  32. Recent advances in tellurite molybdate/tungstate crystals

    CrystEngComm · 2022-01-01

    Xiaojie Guo, Zeliang Gao, Xutang Tao

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  33. Two new tellurite halides with cationic layers: syntheses, structures, and characterizations of CdPb 2 Te 3 O 8 Cl 2 and Cd 13 Pb 8 Te 14 O 42 Cl 14

    Inorganic Chemistry Frontiers · 2022-01-01

    Chen Bai, Yu Chu, Jiazheng Zhou, Linan Wang, Ling Luo, Shilie Pan, Junjie Li

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  34. Coordination metal effect on the nonlinear optical properties and biological activity of double selenates

    Journal of Molecular Structure · 2022-07-13

    Rumyana Yankova, Ivaylo Tankov, Dencho Mihov, Aneliya S. Kostadinova

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  35. Growth and Characterization of a Nonlinear Optical Crystal Cd3Te2WO10 Decorated by WO4 Tetrahedra Showing a Large Band Gap

    Crystal Growth & Design · 2022-09-27

    Qiaoxin Zhang, Qian Wu, Jingfang Zhou, Chuan Yi Tang, Mingjun Xia

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  36. A new stable polymorph of Li 2 TeMo 3 O 12 with wide mid-infrared transparency and a large Raman response

    Inorganic Chemistry Frontiers · 2023-01-01

    Yuheng She, Fei Liang, Jinmiao Jiao, Wenli Zhao, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  37. Cd2Nb2Te4O15: A Novel Pseudo‐Aurivillius‐Type Tellurite with Unprecedented Nonlinear Optical Properties and Excellent Stability

    Small · 2023-05-28

    Qiang Wang, Xuehua Dong, Ling Huang, Kang Min Ok, Zhien Lin, Guohong Zou

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  38. The effect of co-substitution of heterovalent ions Ga 3+ and Sb 5+ on nonlinear optical properties of phosphate crystals

    Materials Advances · 2024-01-01

    Yutong Zhang, Biao Wang, Xinhui Jia, Xi Chong, Jing Li, Bingbing Zhang, Jiyang Wang

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  39. Van der Waals quaternary oxides for tunable low-loss anisotropic polaritonics

    Nature Nanotechnology · 2024-03-01

    Tian Sun, Runkun Chen, Weiliang Ma, Han Wang, Qizhi Yan, Junhua Luo, Sangen Zhao, Xinliang Zhang, Peining Li

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  40. La3Ga5M0.5Sn0.5O14, (M = Ge, Si): Design and Synthesis of Two Langasite Nonlinear Optical Materials with Large Second Harmonic Generation and Birefringence Induced by Distorted (Sn/M)O6 Octahedra

    Inorganic Chemistry · 2024-07-25

    Jingxuan Hou, Jiajia Wang, Fei Liang, Shihui Ma, Hongwei Yu, Hongping Wu, Ning Ye, Zhanggui Hu, Yicheng Wu

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  41. K4Cd3Ge4O13: A Congruent-Melting Germanate Nonlinear Optical Crystal with a Moderate Second-Harmonic Generation Intensity and Broad Transparent Window

    Inorganic Chemistry · 2024-09-30

    Yujun Wang, Jing Chai, Jinmiao Jiao, Xianghao Kong, Tinghui Zhang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  42. Na Nonstoichiometric Modifications Unraveling the Sodium Ion Mobility and Transport Mechanism in Sodium Solid Electrolyte NaxZn2TeO6

    Chemical Research in Chinese Universities · 2025-01-21

    Huangyijia Sun, Xiaohui Li, Xiaoling Zeng, Jian Liu, Aydar I. Rakhmatullin, Chenjie Lou, Mingxue Tang, Alberto José Fernández-Carrión, Xiaojun Kuang

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  43. GLASS FORMATION AND PHASE TRANSFORMATIONS IN THE TeO2–ZnO–MoO3 SYSTEM

    Steklo i Keramika · 2025-02-01

    O. A. Zamyatin, Z. K. Nosov, M.V. Krasnov

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  44. Glass Formation and Phase Transformations in the TeO2–ZnO–MoO3 System

    Glass and Ceramics · 2025-05-01

    O. A. Zamyatin, Z. K. Nosov, М. В. Краснов

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  45. Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

    Journal of the American Chemical Society · 2025-05-15

    Tinghui Zhang, Fei Liang, Conggang Li, Ning Ye, Zhanggui Hu

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  46. Thermal expansion mismatch-driven high-pressure growth of 2D non-centrosymmetric MnTeMoO6 with giant nonlinear optical properties

    Matter · 2025-07-02

    Zhi-Yuan Zhang, Jingwei Wang, Yunhao Zhang, Jiarong Liu, Yujie Sun, Shengnan Li, Jiqing Nie, Jiahui Zhang, Qiangmin Yu, Xiao Wang, Bilu Liu

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  47. DFT and hirshfeld surface analysis of the structural, vibrational, and electronic properties of noncentrosymmetric quaternary molybdenum oxides RTeMoO6 (R = Cd, Zn, Mg)

    Optical and Quantum Electronics · 2025-07-11

    Saleem I. Qashou, Ziad Y. Khattari

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  48. A promising mid-infrared nonlinear optical crystal with well-balanced properties

    Inorganic Chemistry Frontiers · 2026-01-01

    Yujun Wang, Yuning Qi, Yongkuan Xu, Ning Ye, Zhanggui Hu, Conggang Li

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  49. Regulating second harmonic generation of telluromolybdate materials by atomic substitution

    Physical Chemistry Chemical Physics · 2026-01-01

    Hongsheng Liu, Qiutong Zhao, Shi Qiu, Luneng Zhao, Anbing Zhang, Fuwen Qin, Chunyu Ma, Junfeng Gao

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  50. 中红外氧化物非线性光学晶体研究进展（特邀）

    Chinese Journal of Lasers · 2026-01-01

    李浩辰 Li Haochen, 吴倩 Wu Qian, 王天予 Wang Tianyu, 刘弘睿 Liu Hongrui, 李兵 Li Bing, 田皓天 Tian Haotian, 夏明军 Xia Mingjun, 王晓洋 Wang XiaoYang

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