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RESEARCH PAPER · Journal of Solid State Chemistry · 2012

Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

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Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarityOriginalChemInform Abstract: Noncentrosymmetric Salt Inclusion Oxides: Role of Salt Lattices and Counter Ions in Bulk Polarity0Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation85Synthesis of LaMnO3 in molten chlorides: effect of preparation conditions26Flux Growth and Magnetoresistance Behavior of Rare Earth Zintl Phase EuMgSn21New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles56New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]32Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response30Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials680Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials58BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion8Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Single-Crystal Growth and Size Control of Three Novel Polar Intermetallics: Eu2.94(2)Ca6.06In8Ge8, Eu3.13(2)Ca5.87In8Ge8, and Sr3.23(3)Ca5.77In8Ge8 with Crystal Structure, Chemical Bonding, and Magnetism Studies8M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)15Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method50Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra13Room-temperature catalytic oxidation of alcohols with the polyoxovanadate salt Cs 5 (V 14 As 8 O 42 Cl)21Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials340Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates9Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products38K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate24Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates61The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16BaBOF 3 : a new aurivillius-like borate containing two types of F atoms32Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties12Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials238Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials24Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6Synthesis and crystal structure of [(Cs6F)(Cs3AgF)][Ge14O32] through alkali halide flux growth13Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra10Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space7Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides21[ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering270Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution42Incorporation of iodine into uranium oxyhydroxide phases9[ASr 4 Cl][Ge 3 S 10 ] (A = Na, K) and [KBa 4 Cl][Ge 3 S 10 ]: new salt-inclusion infrared nonlinear optical crystals with zero-dimensional [Ge 3 S 9 ] clusters32Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide15Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F7Reactivity of FeMoO4 in CsCl Fluxes and Formation of the Salt-Inclusion Type of Compounds3Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)5A new family of rare earth – strontium tellurite chlorides, SrLn4(TeO3)4Cl6 (Ln = Ce, Nd, Sm): Synthesis, crystal structures, possible polytypism, and crystal-chemical relationships5A non-centrosymmetric chalcohalide synthesized through the combination of chemical tailoring with aliovalent substitution12Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation12Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs6Cu2Si9O230Breaking the Inherent Interarrangement of [B3O6] Clusters for Nonlinear Optics with Orbital Hybridization Enhancement142Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers3Structural chemistry of organically templated transition metal phosphite chlorides, [BH2][M(H2PO3)2Cl2] (B = diamine, M = Mn–Ni, Cd) as new analogs of “hydroselenite halides”7Pb9Si8O22Cl6 and Pb3.07Ca1.93Si3O11: Two Ultraviolet Nonlinear Optical Materials Exhibit a Moderate Second Harmonic Generation Response1Crystal Chemistry of Silver Borates with Salt Inclusion Structure2

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  1. ChemInform Abstract: Noncentrosymmetric Salt Inclusion Oxides: Role of Salt Lattices and Counter Ions in Bulk Polarity

    ChemInform · 2012-11-08

    J. Palmer West, Shiou‐Jyh Hwu

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  2. Molecular Germanium Selenophosphate Salts: Phase-Change Properties and Strong Second Harmonic Generation

    Journal of the American Chemical Society · 2012-11-16

    Collin D. Morris, In Jae Chung, Sungoh Park, Connor M. Harrison, Daniel J. Clark, Joon Ik Jang, Mercouri G. Kanatzidis

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  3. Synthesis of LaMnO3 in molten chlorides: effect of preparation conditions

    Physical Chemistry Chemical Physics · 2013-01-01

    Leonid Vradman, Jonatan Zana, Alon Y. Kirschner, Mordechay Herskowitz

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  4. Flux Growth and Magnetoresistance Behavior of Rare Earth Zintl Phase EuMgSn

    Inorganic Chemistry · 2013-03-07

    Xiaowei Ma, Jun Lü, Jeffrey B. Whalen, Susan E. Latturner

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  5. New Salt-Inclusion Borate, Li3Ca9(BO3)7·2[LiF]: A Promising UV NLO Material with the Coplanar and High Density BO3 Triangles

    Inorganic Chemistry · 2013-04-12

    Hongwei Yu, Hongping Wu, Shilie Pan, Ying Wang, Zhihua Yang, Xin Su

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  6. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

    Dong Woo Lee, Kang Min Ok

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  7. High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a Salt-Inclusion Mixed-Valence Uranium(V,VI) Silicate: [Na9F2][(UVO2)(UVIO2)2(Si2O7)2]

    Inorganic Chemistry · 2013-05-31

    Yu‐Chih Chang, Wen‐Jung Chang, S. Boudin, Kwang‐Hwa Lii

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  8. Sr3B6O11F2: a promising polar fluoroborate with short UV absorption edge and moderate second harmonic generation response

    Scripta Materialia · 2013-05-31

    Zhenjun Huang, Xin Su, Shilie Pan, Xiaoyu Dong, Shujuan Han, Hongwei Yu, Min Zhang, Yun Mo Yang, Sifang Cui, Zhihua Yang

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  9. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

    Crystal Growth & Design · 2013-07-01

    Hongwei Yu, Shilie Pan, Hongping Wu, Zhihua Yang, Lingyun Dong, Xin Su, Bingbing Zhang, Hongyi Li

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  10. Metal Chalcogenides: A Rich Source of Nonlinear Optical Materials

    Chemistry of Materials · 2013-08-09

    In Jae Chung, Mercouri G. Kanatzidis

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  11. Ba4(BO3)3(SiO4)·Ba3X (X = Cl, Br): new salt-inclusion borosilicate halides as potential deep UV nonlinear optical materials

    Journal of Materials Chemistry C · 2014-01-01

    Xiaoxia Nina Lin, Fangfang Zhang, Fangfang Zhang, Shilie Pan, Hongwei Yu, Fangyuan Zhang, Fangyuan Zhang, Xiaoyu Dong, Shujuan Han, Lingyun Dong, Chunyan Bai, Zheng Wang

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  12. BaPbSi 2 O 6 ·BaSO 4 : the first mixed anionic compound synthesized via BaSO 4 salt-inclusion

    CrystEngComm · 2014-01-01

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Qiang Bian, Zhihua Yang, Hongping Wu, Min Zhang

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  13. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

    Shujuan Han, Ying Wang, Shilie Pan, Xiaoyu Dong, Hongping Wu, Jian Wei Han, Yun Mo Yang, Hongwei Yu, Chunyan Bai

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  14. Single-Crystal Growth and Size Control of Three Novel Polar Intermetallics: Eu2.94(2)Ca6.06In8Ge8, Eu3.13(2)Ca5.87In8Ge8, and Sr3.23(3)Ca5.77In8Ge8 with Crystal Structure, Chemical Bonding, and Magnetism Studies

    Inorganic Chemistry · 2014-04-22

    Hyein Woo, Gnu Nam, Eunyoung Jang, Jin Kim, Yunho Lee, Kyunghan Ahn, Tae‐Soo You

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  15. M3(P2O7)22–-Type Open Frameworks Featuring [M2O8] and [M3O12] Multinuclear Transition-Metal Oxide Units. Serendipitous Synthesis of Six Polymorphic Salt-Inclusion Magnetic Solids: Na2M3(P2O7)2·ACl (M = Mn, Fe; A = Rb, Cs) and K2M3(P2O7)2·CsCl (M = Fe, Mn)

    Inorganic Chemistry · 2014-11-21

    Jianhua Gao, Jian Li, Dino Sulejmanovic, Shiou‐Jyh Hwu

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  16. Borate Fluoride and Fluoroborate in Alkali-Metal Borate Prepared by an Open High-Temperature Solution Method

    Inorganic Chemistry · 2014-12-01

    Hongping Wu, Hongwei Yu, Qiang Bian, Zhihua Yang, Shujuan Han, Shilie Pan

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  17. Na 3 B 4 O 7 X (X = Cl, Br): two new borate halides with a 1D Na-X (X = Cl, Br) chain formed by the face-sharing XNa 6 octahedra

    RSC Advances · 2015-01-01

    Chunyan Bai, Shujuan Han, Shilie Pan, Bingbing Zhang, Yun Mo Yang, Lin Li, Zhihua Yang

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  18. Room-temperature catalytic oxidation of alcohols with the polyoxovanadate salt Cs 5 (V 14 As 8 O 42 Cl)

    Catalysis Science & Technology · 2015-12-08

    McKenzie L. Campbell, Dino Sulejmanovic, Jacqueline B. Schiller, Emily M. Turner, S. J. Hwu, Daniel C. Whitehead

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  19. Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2015-12-30

    Ying Wang, Shilie Pan

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  20. Frequency-Doubling Oxide Fluorides, Borate Fluorides, and Fluorooxoborates

    Elsevier eBooks · 2016-01-01

    Shilie Pan, Y. Wang, Kenneth Reinhard Poeppelmeier

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  21. Flux Growth of [NaK6F][(UO2)3(Si2O7)2] and [KK6Cl][(UO2)3(Si2O7)2]: The Effect of Surface Area to Volume Ratios on Reaction Products

    Crystal Growth & Design · 2016-02-02

    Gregory W. Morrison, Hans‐Conrad zur Loye

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  22. K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate

    Inorganic Chemistry · 2016-03-14

    Gregory W. Morrison, T. Thao Tran, P. Shiv Halasyamani, Hans‐Conrad zur Loye

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  23. Understanding the Formation of Salt-Inclusion Phases: An Enhanced Flux Growth Method for the Targeted Synthesis of Salt-Inclusion Cesium Halide Uranyl Silicates

    Journal of the American Chemical Society · 2016-05-24

    Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  24. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

    Dalton Transactions · 2017-01-01

    Miriding Mutailipu, Min Zhang, Yanna Chen, Xiaoquan Lu, Shilie Pan

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  25. BaBOF 3 : a new aurivillius-like borate containing two types of F atoms

    Dalton Transactions · 2018-01-01

    Dequan Jiang, Ying Wang, Hao Li, Zhihua Yang, Shilie Pan

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  26. Two halide-containing cesium manganese vanadates: synthesis, characterization, and magnetic properties

    Dalton Transactions · 2018-01-01

    Tiffany M. Smith Pellizzeri, Michael A. McGuire, Colin D. McMillen, Yimei Wen, George D. Chumanov, Joseph W. Kolis

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  27. Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials

    Angewandte Chemie International Edition · 2018-03-07

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  28. Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials

    Angewandte Chemie · 2018-03-07

    Hongwei Yu, Nathan Z. Koocher, James M. Rondinelli, P. Shiv Halasyamani

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  29. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  30. Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method

    Dalton Transactions · 2019-01-01

    Jinjie Zhou, Hongping Wu, Hongwei Yu, Zhanggui Hu, Yicheng Wu

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  31. Synthesis and crystal structure of [(Cs6F)(Cs3AgF)][Ge14O32] through alkali halide flux growth

    Solid State Sciences · 2019-08-16

    Nicholas R. Spagnuolo, Gregory W. Morrison, Hans‐Conrad zur Loye

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  32. Ba 6 BO 3 Cl 9 and Pb 6 BO 4 Cl 7 : structural insights into ortho -borates with uncondensed BO 4 tetrahedra

    Chemical Communications · 2020-01-01

    Wei Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  33. Targeted crystal growth of uranium gallophosphates via the systematic exploration of the UF 4 –GaPO 4 –ACl (A = Cs, Rb) phase space

    CrystEngComm · 2020-01-01

    Christian A. Juillerat, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  34. Bridging the Salt-Inclusion and Open-Framework Structures: The Case of Acentric Ag 4 B 4 O 7 X 2 (X = Br, I) Borate Halides

    Inorganic Chemistry · 2020-02-12

    Sergey N. Volkov, Dmitri O. Charkin, M. Yu. Arsent’ev, Alexey V. Povolotskiy, Sergey Yu. Stefanovich, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Vladimir Vladimirovich Shilovskikh, Р. С. Бубнова

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  35. [ABa2Cl][Ga4S8] (A = Rb, Cs): Wide-Spectrum Nonlinear Optical Materials Obtained by Polycation-Substitution-Induced Nonlinear Optical (NLO)-Functional Motif Ordering

    Journal of the American Chemical Society · 2020-05-29

    Bin‐Wen Liu, Xiao‐Ming Jiang, Hui‐Yi Zeng, Guo‐Cong Guo

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  36. Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates

    Crystal Growth & Design · 2020-11-12

    Gregory W. Morrison, Hans‐Conrad zur Loye

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  37. [GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

    Chemical Science · 2021-01-01

    Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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  38. Incorporation of iodine into uranium oxyhydroxide phases

    Dalton Transactions · 2021-01-01

    Gabriel L. Murphy, Philip Kegler, Martina Klinkenberg, Andreas Wilden, Maximilian Henkes, Dimitri Schneider, Evgeny V. Alekseev

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  39. [ASr 4 Cl][Ge 3 S 10 ] (A = Na, K) and [KBa 4 Cl][Ge 3 S 10 ]: new salt-inclusion infrared nonlinear optical crystals with zero-dimensional [Ge 3 S 9 ] clusters

    Inorganic Chemistry Frontiers · 2022-01-01

    Yu‐Fei Song, Shaoxin Cui, Zhen Qian, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  40. Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide

    CrystEngComm · 2022-01-01

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  41. Synthesis, Structure Determination, and Characterizations of a Polar Salt-Inclusion Scandium Germanate, Rb10Li3Sc4Ge12O36F

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  42. Reactivity of FeMoO4 in CsCl Fluxes and Formation of the Salt-Inclusion Type of Compounds

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  43. Syntheses, structures, and characterization of new heteroanionic chalcohalides: Na2Ba17In8Q21F18 (Q = S, Se), KBa2InQ3F2 (Q = S, Se)

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  44. A new family of rare earth – strontium tellurite chlorides, SrLn4(TeO3)4Cl6 (Ln = Ce, Nd, Sm): Synthesis, crystal structures, possible polytypism, and crystal-chemical relationships

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  45. A non-centrosymmetric chalcohalide synthesized through the combination of chemical tailoring with aliovalent substitution

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  46. Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation

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  47. Flux Synthesis, UV–vis Absorbance, and Magnetism of Cesium Copper Silicates with an Isolated Super-Super Exchange Spin Dimer in Cs6Cu2Si9O23

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  48. Breaking the Inherent Interarrangement of [B3O6] Clusters for Nonlinear Optics with Orbital Hybridization Enhancement

    Journal of the American Chemical Society · 2023-10-24

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  49. Pb3[O10Pb20](SiO4)4X10 (X = Cl, Br): The First Pb-Containing Halogen Silicates with Mirror-Symmetric Pseudo-Aurivillius Bilayers

    Inorganic Chemistry · 2024-03-06

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  50. Structural chemistry of organically templated transition metal phosphite chlorides, [BH2][M(H2PO3)2Cl2] (B = diamine, M = Mn–Ni, Cd) as new analogs of “hydroselenite halides”

    Structural Chemistry · 2024-09-23

    Dmitri O. Charkin, Vadim E. Kireev, Dmitri N. Dmitriev, A. M. Banaru, Dina V. Deyneko, Sergey M. Aksenov

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