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RESEARCH PAPER · Inorganic Chemistry · 2013

α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive CationsOriginalChemInform Abstract: α‐ScVSe2O8, β‐ScVSe2O8, ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second‐Order Jahn—Teller Distortive Cations.0Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O813Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Ba2Cu2Te2P2O13: A new telluro-phosphate with S=1/2 Heisenberg chain6[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds18New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Structural variety in zinc telluro-phosphates: syntheses, crystal structures and characterizations of Sr 2 Zn 3 Te 2 P 2 O 14 , Pb 2 Zn 3 Te 2 P 2 O 14 and Ba 2 Zn 2 TeP 2 O 1119Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism16Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO1057Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)13Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Synthesis, crystal structures, and magnetic properties of one-dimensional alkali metal copper chlor-tellurites A(NH 4 )Cu 4 Te 2 O 6 Cl 6 (A = K, Cs), NaCu 4 Te 2 Cl 5 O 6 and Rb 3 (NH 4 ) 2 Cu 12 Te 6 Cl 16.5 O 18 (OH) 0.52Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3Effects of M Cations on Crystal Structure and Optical Properties of Mte3o8 Tellurites2Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1[Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption5Suppressing Second‐Order Jahn–Teller Distortion in VO 2 (B): A Dissolution‐Resistant Electrode for Durable Aqueous Energy Storage0LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion3

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  1. ChemInform Abstract: α‐ScVSe2O8, β‐ScVSe2O8, ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second‐Order Jahn—Teller Distortive Cations.

    ChemInform · 2013-12-02

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  2. Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 6

    Dalton Transactions · 2014-01-01

    Hyun Sun Ahn, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  3. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

    Inorganic Chemistry · 2014-01-02

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  4. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  5. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

    Inorganic Chemistry · 2014-05-07

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  6. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  7. New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O

    Inorganic Chemistry · 2014-09-11

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  8. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

    Read original paper ↗ ·

  9. New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O8

    Journal of Alloys and Compounds · 2015-03-05

    Yeong Hun Kim, Beom‐Yong Jeon, Tae‐Soo You, Kang Min Ok

    Read original paper ↗ ·

  10. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

    Read original paper ↗ ·

  11. Ba2Cu2Te2P2O13: A new telluro-phosphate with S=1/2 Heisenberg chain

    Journal of Solid State Chemistry · 2015-07-02

    Mingjun Xia, Shipeng Shen, Jun Lü, Young Sun, Rukang K. Li

    Read original paper ↗ ·

  12. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-08-07

    Vadim M. Kovrugin, Sergey V. Krivovichev, Olivier Mentré, Marie Colmont

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  13. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

    Read original paper ↗ ·

  14. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

    Springer mineralogy · 2016-01-01

    Nikita V. Chukanov, A. D. Chervonnyi

    Read original paper ↗ ·

  15. Structural variety in zinc telluro-phosphates: syntheses, crystal structures and characterizations of Sr 2 Zn 3 Te 2 P 2 O 14 , Pb 2 Zn 3 Te 2 P 2 O 14 and Ba 2 Zn 2 TeP 2 O 11

    Dalton Transactions · 2016-01-01

    Mingjun Xia, Rukang K. Li

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  16. Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain

    Inorganic Chemistry · 2016-01-14

    Su‐whan Bae, Jisun Yoo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

    Read original paper ↗ ·

  17. Exploration of Vanadate Selenites Solid Phase Space, Crystal Structures, and Polymorphism

    Crystal Growth & Design · 2016-03-15

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Sergey V. Krivovichev, Olivier Mentré

    Read original paper ↗ ·

  18. Two New Non-centrosymmetric n = 3 Layered Dion–Jacobson Perovskites: Polar RbBi2Ti2NbO10 and Nonpolar CsBi2Ti2TaO10

    Chemistry of Materials · 2016-03-23

    Hyung Gu Kim, T. Thao Tran, Woongjin Choi, Tae‐Soo You, P. Shiv Halasyamani, Kang Min Ok

    Read original paper ↗ ·

  19. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  20. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

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  21. New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )

    Journal of Solid State Chemistry · 2017-02-16

    Mingli Liang, Matthew L. Marsh, Xian-Xing Shang, Jiang‐Gao Mao, Thomas E. Albrecht‐Schmitt, Fang Kong

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  22. Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)

    Inorganic Chemistry · 2017-04-25

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Suheon Lee, Kwang‐Yong Choi, Yang Yu, Kang Min Ok

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  23. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

    Read original paper ↗ ·

  24. New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 4

    Journal of Solid State Chemistry · 2017-09-14

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

    Read original paper ↗ ·

  25. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

    Read original paper ↗ ·

  26. IR Spectra of Minerals and Related Compounds, and Reference Samples Data

    Springer mineralogy · 2019-11-28

    Nikita V. Chukanov, Marina F. Vigasina

    Read original paper ↗ ·

  27. Synthesis, crystal structures, and magnetic properties of one-dimensional alkali metal copper chlor-tellurites A(NH 4 )Cu 4 Te 2 O 6 Cl 6 (A = K, Cs), NaCu 4 Te 2 Cl 5 O 6 and Rb 3 (NH 4 ) 2 Cu 12 Te 6 Cl 16.5 O 18 (OH) 0.5

    Dalton Transactions · 2020-01-01

    Bei Zhu, Jianhua Jiang, Tianyu Zhu, Haoming Yang, Yong Jin, Minfeng Lü

    Read original paper ↗ ·

  28. Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)

    Journal of Alloys and Compounds · 2020-08-28

    Hye‐Eun Lee, Hongil Jo, Min Hyung Lee, Kang Min Ok

    Read original paper ↗ ·

  29. Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

    Journal of Solid State Chemistry · 2021-02-06

    Dong Woo Lee, Hye Ran Noh, Tae-Hyeong Kim, Jeongmook Lee, Jong‐Yun Kim, Kyung‐Tae Ko, Sang Ho Lim

    Read original paper ↗ ·

  30. Effects of M Cations on Crystal Structure and Optical Properties of Mte3o8 Tellurites

    SSRN Electronic Journal · 2022-01-01

    Arreerat Jiamprasertboon, Anurak Waehayee, Sarunya Sertwatsana, Supinya Nijpanich, Wutthikrai Busayaporn, Tanachat Eknapakul, Narong Chanlek, Atipong Bootchanont, Chanipon Sunkhunthod, Athis Watwiangkham, Hideki Nakajima, Jun Li, Mas A. Subramanian, Suwit Suthirakun, Theeranun Siritanon

    Read original paper ↗ ·

  31. Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph

    Journal of Solid State Chemistry · 2022-01-22

    Honggang Wang, Jian‐Han Zhang, Ming-Shui Lin, Tianyu Wang, Zhijian Zhang, Shufeng Yan, Shao‐Ming Ying

    Read original paper ↗ ·

  32. [Cd2((S,S)-IBPhe)2(2,2′-bipy)2]·2H2O and [Cd2((R,R)-IBPhe)2(2,2′-bipy)2]·2H2O (IBPhe = Isophthaloyl-bis-phenylalanine): One-Dimensional Chiral Coordination Polymers with Selective Dye Adsorption

    Crystal Growth & Design · 2024-02-05

    Jinsoo Koh, Kang Min Ok

    Read original paper ↗ ·

  33. Suppressing Second‐Order Jahn–Teller Distortion in VO 2 (B): A Dissolution‐Resistant Electrode for Durable Aqueous Energy Storage

    Small · 2025-10-13

    Minghui Gu, Tailong Zhang, Jin Chun Li, Cuixia Xu, Yanchen Liu, Kairun Bo, Ji-Kun Li, Shenglong Li, Teng Zhai, Hui Xia

    Read original paper ↗ ·

  34. LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion

    Small · 2025-12-26

    Qiuyuan Feng, Jialong Wang, Qun Jing, Xiaoyu Dong, Shilie Pan

    Read original paper ↗ ·
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