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RESEARCH PAPER · Materials Research Bulletin · 2014

Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

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Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16OriginalDie Borosulfate K4[BS4O15(OH)], Ba[B2S3O13] und Gd2[B2S6O24]19The Borosulfates K4[BS4O15(OH)], Ba[B2S3O13], and Gd2[B2S6O24]45Structural and physical systematization of the nonlinear-optical borate crystals1Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals16RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures19Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures10Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds53Ni[B2(SO4)4] and Co[B2(SO4)4]: Unveiling Systematic Trends in Phyllosilicate Analogue Borosulfates15Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure7Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy6Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )0The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )7Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )5Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid0Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0LiK4B(SO4)4: a potential optical crystal for deep ultraviolet zero-order waveplates1

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  1. Die Borosulfate K4[BS4O15(OH)], Ba[B2S3O13] und Gd2[B2S6O24]

    Angewandte Chemie · 2016-02-29

    Peter Groß, Arno Kirchhain, Henning A. Höppe

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  2. The Borosulfates K4[BS4O15(OH)], Ba[B2S3O13], and Gd2[B2S6O24]

    Angewandte Chemie International Edition · 2016-02-29

    Peter Groß, Arno Kirchhain, Henning A. Höppe

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  3. Structural and physical systematization of the nonlinear-optical borate crystals

    International Forum on Strategic Technology · 2016-06-01

    Vladimir K. Makukha, Boris I. Kidyarov

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  4. Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals

    Crystals · 2017-04-12

    Boris I. Kidyarov

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  5. RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures

    Inorganic Chemistry · 2017-12-14

    Wenwen Wang, Xiang Xu, Jin-Tao Kong, Jiang‐Gao Mao

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  6. Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures

    Journal of Solid State Chemistry · 2018-01-30

    Tingting Ruan, Wenwen Wang, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  7. Borosulfates—Synthesis and Structural Chemistry of Silicate Analogue Compounds

    Chemistry - A European Journal · 2020-01-14

    Jörn Bruns, Henning A. Höppe, Michael Daub, Harald Hillebrecht, Hubert Huppertz

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  8. Ni[B2(SO4)4] and Co[B2(SO4)4]: Unveiling Systematic Trends in Phyllosilicate Analogue Borosulfates

    Chemistry - A European Journal · 2020-06-17

    Leonard C. Pasqualini, Oliver Janka, Selina Olthof, Hubert Huppertz, Klaus Roman Liedl, Rainer Pöttgen, Maren Podewitz, Jörn Bruns

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  9. Two UV optical crystals with strong optical anisotropy, large band gaps and an α-BBO type structure

    Dalton Transactions · 2023-01-01

    Lehui Liu, Feifei Yuan, Yisheng Huang, Zhoubin Lin, Lizhen Zhang

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  10. Li2NaB3S2O12: A Deep-UV Transparent Borosulfate with Moderate Birefringence Derived from the [B3S2O12]∞ Infinite Chain Designed by the High Boron-to-Sulfur Ratio Strategy

    Inorganic Chemistry · 2024-10-07

    Zichang Wang, Jianyi Zuo, Qing‐Yu Liu, Xueling Hou, Minqiang Gai

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  11. Die ersten Antimon‐Borosulfate offenbaren das Baukastensystem M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie · 2025-02-12

    Erich Turgunbajew, Henning A. Höppe

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  12. The First Antimony Borosulfates Unveil a Modular System M III M I [B(SO 4 ) 2 ] 4 (M III =Bi 3+ , Sb 3+ , Lu 3+ ; M I =H 3 O + , NO 2 + , Li + , Na + , K + , Rb + , Cs + )

    Angewandte Chemie International Edition · 2025-02-12

    Erich Turgunbajew, Henning A. Höppe

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  13. Variability of a Non‐Centrosymmetric Tecto‐Borosulfate: Introduction of Various Molecular Cations into BiX[B(SO 4 ) 2 ] 4 (X = H 3 O + , NO 2 + , NH 4 + , NO + )

    Chemistry - A European Journal · 2025-10-05

    Erich Turgunbajew, Matthias Hämmer, Lkhamsuren Bayarjargal, Florian Pielnhofer, Henning A. Höppe

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  14. Synthesis and Crystal Structure of Rb[B(SO 4 ) 2 ]: A Borosulfate Obtained from a Reaction with Chlorosulfuric Acid

    Zeitschrift für anorganische und allgemeine Chemie · 2025-10-11

    Jasper Nickelsen, Arthur Edelmann, Marios Symeonidis, Jörn Bruns

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  15. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  16. LiK4B(SO4)4: a potential optical crystal for deep ultraviolet zero-order waveplates

    Journal of Molecular Structure · 2026-03-14

    Jianji Yao, Qianzhen Zhang, Xiaoyu Wu, Xifa Long, Yun Mo Yang

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