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RESEARCH PAPER · Inorganic Chemistry · 2012

Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4

Dong Woo Lee, Dan‐bee Bak, Saet Byeol Kim, Jiwon Kim, Kang Min Ok

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Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4OriginalChemInform Abstract: Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4.0Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)33Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units20New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+14New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment22VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)24A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Trigonal pyramidal oxyanions as structure-directing templates for the synthesis of silver dithiolate clusters18Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)31Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)15IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8A review of the structural architecture of tellurium oxycompounds170Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond21Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis36IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Raman Spectra of Minerals13Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 1413Recent progress in selenite and tellurite based SHG materials32MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings23Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates37NaTePO5, SrTeP2O8 and Ba2TeP2O9: Three tellurite-phosphates with large birefringence22Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence37Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)10KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework2Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O627Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra20Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal19Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap16S = 1/2 Trimers Driving the Magnetism in Two Li2Cu3(SeO3)4 Polymorphs0

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  1. ChemInform Abstract: Effect of the Framework Flexibility on the Centricities in Centrosymmetric In2Zn(SeO3)4 and Noncentrosymmetric Ga2Zn(TeO3)4.

    ChemInform · 2012-09-07

    Dong Woo Lee, Dan‐bee Bak, Saet Byeol Kim, Jiwon Kim, Kang Min Ok

    Read original paper ↗ ·

  2. Structure–Property Relationships in Solid Solutions of Noncentrosymmetric Aurivillius Phases, Bi4–xLaxTi3O12 (x = 0–0.75)

    Inorganic Chemistry · 2012-09-17

    Seung‐Jin Oh, Yiseul Shin, T. Thao Tran, Dong Woo Lee, Anne Yoon, P. Shiv Halasyamani, Kang Min Ok

    Read original paper ↗ ·

  3. Na2Cd7B8O20: a new noncentrosymmetric compound with special [B3O7] units

    CrystEngComm · 2013-01-01

    Lin Zhou, Shilie Pan, Xiaoyu Dong, Hongwei Yu, Hongping Wu, Fangfang Zhang, Zhongxiang Zhou

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  4. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

    Dong Woo Lee, Kang Min Ok

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  5. Na1.4InTe3.6O9.4: New Variant of a Hexagonal Tungsten Oxide (HTO)-Like Layered Framework Containing Both a Main-Group Cation, In3+, and a Lone-Pair Cation, Te4+

    Inorganic Chemistry · 2013-05-15

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  6. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

    Inorganic Chemistry · 2013-08-16

    Dong Woo Lee, Kang Min Ok

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  7. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  8. Y2MoSe3O12 and Y2MoTe3O12: Solid-state synthesis, structure determination, and characterization of two new quaternary mixed metal oxides containing asymmetric coordination environment

    Journal of Solid State Chemistry · 2013-10-10

    Seong‐eun Bang, Zhi Quan Pan, Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  9. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

    Inorganic Chemistry · 2013-11-21

    Yiseul Shin, Dong Woo Lee, Kwang‐Yong Choi, Hyun‐Joo Koo, Kang Min Ok

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  10. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

    Inorganic Chemistry · 2014-01-02

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  11. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

    Shujuan Han, Ying Wang, Shilie Pan, Xiaoyu Dong, Hongping Wu, Jian Wei Han, Yun Mo Yang, Hongwei Yu, Chunyan Bai

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  12. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

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  13. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

    Inorganic Chemistry · 2014-05-07

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  14. Effect of polarizable lone pair cations on the second-harmonic generation (SHG) properties of noncentrosymmetric (NCS) Bi 2−x Y x TeO 5 (x = 0–0.2)

    Dalton Transactions · 2014-05-09

    Hongil Jo, Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  15. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

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  16. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

    Materials Research Bulletin · 2014-11-25

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

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  17. Trigonal pyramidal oxyanions as structure-directing templates for the synthesis of silver dithiolate clusters

    Journal of Structural Chemistry · 2014-12-01

    H. -W. Chang, Jian‐Hong Liao, B. Li, Y. -J. Chen, C. W. Liu

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  18. Effect of the cation size on the framework structures of magnesium tungstate, A 4 Mg(WO 4 ) 3 (A = Na, K), R 2 Mg 2 (WO 4 ) 3 (R = Rb, Cs)

    Dalton Transactions · 2015-01-01

    Shujuan Han, Ying Wang, Qun Jing, Hongping Wu, Shilie Pan, Zhihua Yang

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  19. Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)

    Journal of Materials Chemistry C · 2015-01-01

    Hyung Gu Kim, Jae Soo Yoo, Kang Min Ok

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  20. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

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  21. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

    Inorganic Chemistry · 2015-08-26

    Seong‐eun Bang, Kang Min Ok

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  22. Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)

    Journal of Solid State Chemistry · 2015-10-02

    Yunsheng Liu, Dajiang Mei, Jingli Xu, Yuandong Wu

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  23. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

    Springer mineralogy · 2016-01-01

    Nikita V. Chukanov, A. D. Chervonnyi

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  24. Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)

    Journal of Alloys and Compounds · 2016-02-24

    Hongil Jo, Jae Soo Yoo, Kang Min Ok

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  25. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

    Andrew G. Christy, Stuart J. Mills, Anthony R. Kampf

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  26. Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

    Inorganic Chemistry · 2016-05-26

    Hongil Jo, Kang Min Ok

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  27. Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

    Inorganic Chemistry · 2016-11-09

    Yuquan Feng, Hui‐Tao Fan, Zhiguo Zhong, Hongwei Wang, Dongfang Qiu

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  28. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  29. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017-01-01

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

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  30. Noncentrosymmetric (NCS) solid solutions: elucidating the structure–nonlinear optical (NLO) property relationship and beyond

    Dalton Transactions · 2017-01-01

    Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  31. Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions

    Journal of Solid State Chemistry · 2017-05-04

    Hoyong Jung, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  32. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  33. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  34. Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data

    Journal of Solid State Chemistry · 2019-04-29

    Carlos Alberto López, E. Bâati, María Teresa Fernández-Díaz, Felix O. Saouma, Joon Ik Jang, J. A. Alonso

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  35. Ag4Hg(SeO3)2(SeO4): a novel SHG material created in mixed valent selenium oxides by in situ synthesis

    Science China Materials · 2019-10-22

    Xiaoxue Wang, Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  36. IR Spectra of Minerals and Related Compounds, and Reference Samples Data

    Springer mineralogy · 2019-11-28

    Nikita V. Chukanov, Marina F. Vigasina

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  37. Raman Spectra of Minerals

    Springer mineralogy · 2019-11-28

    Н. В. Чуканов, Marina F. Vigasina

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  38. Lone-pair self-containment in pyritohedron-shaped closed cavities: optimized hydrothermal synthesis, structure, magnetism and lattice thermal conductivity of Co 15 F 2 (TeO 3 ) 14

    Dalton Transactions · 2020-01-01

    Minfeng Lü, Jianhua Jiang, Bei Zhu, Yuwei Zhao, Tianyu Zhu, Haoming Yang, Yong Jin, Houria Kabbour, Kwang‐Yong Choi, William T. A. Harrison

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  39. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

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  40. MII2M3IIIF3(Te6F2O16) (MII = Pb, Ba; MIII = Al, Ga): New mixed anionic tellurites with isolated Te6 coplanar rings

    Journal of Solid State Chemistry · 2020-02-29

    Pengfei Li, Fang Kong, Jiang‐Gao Mao

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  41. Dimensionality–Band Gap–Third-Harmonic Generation Property Relationship in Novel Main-Group Metal Iodates

    Chemistry of Materials · 2020-04-07

    Geonju Park, Hye Ryung Byun, Joon Ik Jang, Kang Min Ok

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  42. NaTePO5, SrTeP2O8 and Ba2TeP2O9: Three tellurite-phosphates with large birefringence

    Journal of Alloys and Compounds · 2020-09-17

    Min Zhao, Yingjie Sun, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  43. Ba3Sb2(PO4)4 and Cd3Sb2(PO4)4(H2O)2: Two New Antimonous Phosphates with Distinct [Sb(PO4)2] Structure Types and Enhanced Birefringence

    Inorganic Chemistry · 2021-01-12

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  44. Synthesis, Crystal Structures, and Thermal Analyses of Two New Antimony Tellurite Sulfates: [Sb2(TeO4)](SO4) and [Sb2(TeO3)2](SO4)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-05-06

    Jiayuan Zhang, Xiao Zhao, Yuandong Wu, Dajiang Mei, Shaoguo Wen, Thomas Doert

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  45. KIn0.33IIITe0.67VITe2IVO7: Zirconolite-like Mixed-Valent Metal Oxide with a 3D Framework

    Inorganic Chemistry · 2021-09-29

    Dong Woo Lee, Tae-Hyeong Kim, Jeongmook Lee, Jung-Hwan Park, Jong‐Yun Kim, Kang Min Ok, Sang Ho Lim

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  46. Investigations on the Synthesis, Crystal Structure, Linear- and Nonlinear-Optical Properties of the Zinc Germanate Rb2ZnGe2O6

    Inorganic Chemistry · 2021-12-22

    Tao Han, Conggang Li, Wenli Zhao, Yuheng She, Jinmiao Jiao, Fei Liang, Zhanggui Hu, Yicheng Wu

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  47. Lead Tellurite Crystals BaPbTe2O6 and PbVTeO5F with Large Nonlinear-/Linear-Optical Responses due to Active Lone Pairs and Distorted Octahedra

    Inorganic Chemistry · 2022-01-10

    Yuanyu Yang, Yao Guo, Bingbing Zhang, Ting Wang, Yi-Gang Chen, Xiaohui Hao, Xiaoxiu Yu, Xian‐Ming Zhang

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  48. Shedding Light on the Structure and Characterization of K2ZnGe2O6: A Phase-Matchable Nonlinear Optical Crystal

    Inorganic Chemistry · 2022-07-13

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  49. Noncentrosymmetric tellurite halides created by a depolymerization strategy: toward strong SHG intensity and wide bandgap

    Chemical Science · 2024-01-01

    Dandan Zhou, Chun‐Li Hu, Xinwei Zhang, Jiang‐Gao Mao, Fang Kong

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  50. S = 1/2 Trimers Driving the Magnetism in Two Li2Cu3(SeO3)4 Polymorphs

    Inorganic Chemistry · 2026-07-21

    Shoushuang Li, Mingming Hang, Minfeng Lü, Ambre Theron, Rui Cui, Xiedong Cheng, Feifan Li, Hexiang Liu, Zhenglong Zhu, Zirui Zuo, Qingqing Huang, Yaping Li, Olivier Mentré

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