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RESEARCH PAPER · Inorganic Chemistry · 2014

Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3OriginalChemInform Abstract: Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed‐Valent Selenite—Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3.0Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B2Se3O109Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se752Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds9Molecular structure, vibrational spectra, MEP, HOMO-LUMO and NBO analysis of Hf(SeO3)(SeO4)(H2O)425Synthesis and characterization of Hf(SO4)2(H2O)4 and Hf(SeO3)(SeO4)(H2O)48A review of the structural architecture of tellurium oxycompounds170Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold302YCu(TeO3)2(NO3)(H2O)3: a novel layered tellurite3Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Th(H2O)(IVO3)2[IVII0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites9Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters8Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses78Incorporation of Sulfate or Selenate Groups into Oxotellurates(IV): I. Calcium, Cadmium, and Strontium Compounds20Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)13Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43MgSiAs: An Unexplored System with Promising Nonlinear Optical Properties53Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides7Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites35Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios4Cobalt selenate pentahydrate: Thermal decomposition intermediates and their properties dependence on temperature changes5The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2 RE 3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)4In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 219Zn(H 2 C 3 N 3 O 3 ) 2 ·3H 2 O: the first single- d 10 transition metal based ultraviolet hydroisocyanurate crystal with large birefringence18New Crystal Structures of Rare‐Earth Metal(III) Oxotellurates(IV) RE2Te3O9: A1‐Type (RE=La, Ce) and A2‐Type (RE=Pr, Nd)8Single-Crystal Structure of HP-Sc2TeO6 Prepared by High-Pressure/High-Temperature Synthesis4Synthesis and crystal structure of two scandium oxotellurates(IV): Sc2Te3O9 and Sc2Te4O111A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co 3 (SeO 3 )(SeO 4 )(OH) 2 with kagomé-like Co 2+ ion layer arrangements: the importance of identifying a correct spin lattice4From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties27Fabrication of novel oxochalcogens halides of manganese and tin nanocomposites as highly efficient photocatalysts for dye degradation and excellent antimicrobial activity7Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF42First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation2RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6From Ca 3 Be(SeO 3 ) 4 to SrBe(SeO 3 ) 2 : two unprecedented alkaline earth metal beryllium selenites with large band gaps and enhanced birefringence4Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations2Synthesis, structure and magnetic properties of two selenites, Li2Mn2.5(SeO3)4 and Li2Co3(SeO3)4 with a one-dimensional spin-chain1The rare earth metal(III) oxotellurates(IV) RE 2 Te 3 O 9 in the B -type structure with RE = Y and Sm–Er1[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1

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  1. ChemInform Abstract: Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed‐Valent Selenite—Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3.

    ChemInform · 2014-08-14

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·

  2. Synthesis, Crystal Structure, and Spectroscopy of the Mixed-Valent Boroseleniteselenate B2Se3O10

    Inorganic Chemistry · 2015-02-19

    Michael Daub, Harald Scherer, Harald Hillebrecht

    Read original paper ↗ ·

  3. Synthesis and Characterization of Mid-Infrared Transparency Compounds: Acentric BaHgS2 and Centric Ba8Hg4S5Se7

    Inorganic Chemistry · 2015-03-05

    Kui Wu, Xin Su, Shilie Pan, Zhihua Yang

    Read original paper ↗ ·

  4. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

    Read original paper ↗ ·

  5. Cu3(SeO4)2(SeO3OH)2(H2O)16 – The First Example of a Linear Octahedral–Tetrahedral Heptamer in Inorganic Compounds

    European Journal of Inorganic Chemistry · 2015-10-16

    Vladislav V. Gurzhiy, Alexander Al‐Shuray, Sergey N. Britvin, Sergey V. Krivovichev

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  6. Molecular structure, vibrational spectra, MEP, HOMO-LUMO and NBO analysis of Hf(SeO3)(SeO4)(H2O)4

    Journal of Molecular Structure · 2015-10-31

    Rumyana Yankova, Svetlana D. Genieva, Nenko Halachev, Ginka Dimitrova

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  7. Synthesis and characterization of Hf(SO4)2(H2O)4 and Hf(SeO3)(SeO4)(H2O)4

    Journal of Thermal Analysis and Calorimetry · 2016-02-09

    Svetlana D. Genieva, Rumyana Yankova, Ginka Baikusheva-Dimitrova, Nenko Halachev

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  8. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

    Andrew G. Christy, Stuart J. Mills, Anthony R. Kampf

    Read original paper ↗ ·

  9. Na 2 ZnGe 2 S 6 : A New Infrared Nonlinear Optical Material with Good Balance between Large Second-Harmonic Generation Response and High Laser Damage Threshold

    Journal of the American Chemical Society · 2016-05-19

    Guangmao Li, Kui Wu, Qiong Liu, Zhihua Yang, Shilie Pan

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  10. YCu(TeO3)2(NO3)(H2O)3: a novel layered tellurite

    Acta Crystallographica Section E Crystallographic Communications · 2016-07-19

    Stuart J. Mills, DUNSTAN Maja Anna, Andrew G. Christy

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  11. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  12. Th(H2O)(IVO3)2[IVII0.6V1.76O7(OH)]: A Mixed-Valent Iodine Compound Containing Periodate Stabilized by Crystallographically Compatible Lattice Sites

    Inorganic Chemistry · 2016-11-17

    Yaxing Wang, Linjuan Zhang, Lanhua Chen, Weifeng Li, Xing Dai, Juan Diwu, Jian‐Qiang Wang, Zhifang Chai, Shuao Wang

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  13. Li 3 Ge 3 Se 6 : the first ternary lithium germanium selenide with interesting ∞ [Ge 6 Se 12 ] n chains constructed by ethane-like [Ge 2 Se 6 ] 6− clusters

    Dalton Transactions · 2017-01-01

    Guangmao Li, Ni Zhen, Yu Chu, Zhongxiang Zhou

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  14. Na 2 CdGe 2 Q 6 (Q = S, Se): two metal-mixed chalcogenides with phase-matching abilities and large second-harmonic generation responses

    Dalton Transactions · 2017-01-01

    Guangmao Li, Qiong Liu, Kui Wu, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  15. Incorporation of Sulfate or Selenate Groups into Oxotellurates(IV): I. Calcium, Cadmium, and Strontium Compounds

    Zeitschrift für anorganische und allgemeine Chemie · 2017-01-12

    Matthias Weil, Mahdi Shirkhanlou

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  16. Syntheses, Structures, and Characterization of Quaternary Tellurites, Li3MTe4O11 (M = Al, Ga, and Fe)

    Inorganic Chemistry · 2017-04-25

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Suheon Lee, Kwang‐Yong Choi, Yang Yu, Kang Min Ok

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  17. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  18. New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 4

    Journal of Solid State Chemistry · 2017-09-14

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  19. MgSiAs: An Unexplored System with Promising Nonlinear Optical Properties

    Advanced Functional Materials · 2018-05-21

    Katherine E. Woo, Jian Wang, Kui Wu, Kathleen Lee, Juli‐Anna Dolyniuk, Shilie Pan, Kirill A. Kovnir

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  20. Synthesis and structural variety of first Mn and Bi selenites and selenite chlorides

    Zeitschrift für Kristallographie - Crystalline Materials · 2018-10-16

    Vadim M. Kovrugin, Marie Colmont, Oleg I. Siidra, Dmitry O. Charkin, Almaz Aliev, Sergey V. Krivovichev, Olivier Mentré

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  21. Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis

    Dalton Transactions · 2019-01-01

    Abudukadi Tudi, Shujuan Han, Ailijiang Abudurusuli, Haohai Yu, Zhihua Yang, Shilie Pan

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  22. Exploration of New Birefringent Crystals in Bismuth d0 Transition Metal Selenites

    Chemistry - A European Journal · 2019-01-13

    Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  23. Band-Gap Modulation of Nonlinear-Optical Fluorooxoborates by Controlling the F/B Ratios

    Inorganic Chemistry · 2020-01-14

    Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  24. Cobalt selenate pentahydrate: Thermal decomposition intermediates and their properties dependence on temperature changes

    Thermochimica Acta · 2020-04-24

    Rafael de Godoi Machado, Caroline Gaglieri, Rafael Turra Alarcon, Aniele de Moura, Amanda Cosmo de Almeida, Flávio Júnior Caires, Massao Ionashiro

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  25. The complete series of sodium rare-earth metal(III) chloride oxotellurates(IV) Na2 RE 3Cl3[TeO3]4 (RE = Y, La–Nd, Sm–Lu)

    Zeitschrift für Kristallographie - Crystalline Materials · 2020-08-01

    Stefan Greiner, Sabine Zitzer, Sabine Strobel, Peter S. Berdonosov, Thomas Schleid

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  26. In situ hydrothermal synthesis of polar second-order nonlinear optical selenate Na 5 (SeO 4 )(HSeO 4 ) 3 (H 2 O) 2

    Inorganic Chemistry Frontiers · 2021-01-01

    Chao Wu, Xingxing Jiang, Lin Lin, Tianhui Wu, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  27. Zn(H 2 C 3 N 3 O 3 ) 2 ·3H 2 O: the first single- d 10 transition metal based ultraviolet hydroisocyanurate crystal with large birefringence

    Dalton Transactions · 2021-01-01

    Dandan Wang, Xinyuan Zhang, Fei Liang, Zhanggui Hu, Yicheng Wu

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  28. New Crystal Structures of Rare‐Earth Metal(III) Oxotellurates(IV) RE2Te3O9: A1‐Type (RE=La, Ce) and A2‐Type (RE=Pr, Nd)

    Zeitschrift für anorganische und allgemeine Chemie · 2021-02-11

    Sheng‐Chun Chou, Patrick Höss, Philip L. Russ, Sabine Strobel, Thomas Schleid

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  29. Single-Crystal Structure of HP-Sc2TeO6 Prepared by High-Pressure/High-Temperature Synthesis

    Crystals · 2021-12-13

    Raimund Ziegler, Martina Tribus, Clivia Hejny, Günter Heymann

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  30. Synthesis and crystal structure of two scandium oxotellurates(IV): Sc2Te3O9 and Sc2Te4O11

    Zeitschrift für Naturforschung B · 2022-11-16

    Sheng‐Chun Chou, Sabine Zitzer, Philip L. Russ, Thomas Schleid

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  31. A cascade of magnetic phase transitions and a 1/3-magnetization plateau in selenite–selenate Co 3 (SeO 3 )(SeO 4 )(OH) 2 with kagomé-like Co 2+ ion layer arrangements: the importance of identifying a correct spin lattice

    Dalton Transactions · 2023-01-01

    Alisher F. Murtazoev, Peter S. Berdonosov, Konstantin Alexandrovich Lyssenko, В. А. Долгих, Michael Y. Geidorf, О. С. Волкова, H.-J. Koo, Myung‐Hwan Whangbo, Alexander N. Vasiliev

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  32. From AgTeO 2 F and Ag 2 (TeO 2 F 2 ) to Ag 3 F 3 (TeF 6 )(TeO 2 ) 12 : the first silver tellurite oxyfluorides with linear and nonlinear optical properties

    Inorganic Chemistry Frontiers · 2023-01-01

    Bo Zhang, Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Fang Kong, Jiang‐Gao Mao

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  33. Fabrication of novel oxochalcogens halides of manganese and tin nanocomposites as highly efficient photocatalysts for dye degradation and excellent antimicrobial activity

    Frontiers in Materials · 2023-02-27

    Misbah Umar, Sana Mansoor, Mohsin Javed, Nadia Hussain, Majed A. Bajaber, Shahid Iqbal, Ahmad Alhujaily, Ayesha Mohyuddin, Humayun Ajaz, Abdul Rauf, Ali Bahadur, Foziah F. Al-Fawzan, Eslam B. Elkaeed

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  34. Two Purely Inorganic Cationic Tellurite Materials Based on Group IB Metal Tetrafluoroborates with Similar Lamellar Cationic Layers: [Cu2F(Te2O5)](BF4) and [Ag18O2(Te4O9)4(Te3O8)(BF4)2]·2HBF4

    Inorganic Chemistry · 2023-06-14

    Tong Su, Meiqiao Wei, Hanqing Liu, Yun-Shan Fang, Qiong Wu, Zhehui Weng, Jie Ling, Renjie Chen, Yulan Wang, Xiusha Zhao, Haidong Ju

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  35. First copper (II) oxo-selenite-sulfate Cu4O(SeO3)(SO4)2 and the role of a lone electron pair in open framework crystal structure formation

    Solid State Sciences · 2024-09-20

    Alisher F. Murtazoev, Konstantin Alexandrovich Lyssenko, Alexey N. Kuznetsov∥, В. А. Долгих, Peter S. Berdonosov

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  36. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

    Inorganic Chemistry · 2024-10-08

    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  37. From Ca 3 Be(SeO 3 ) 4 to SrBe(SeO 3 ) 2 : two unprecedented alkaline earth metal beryllium selenites with large band gaps and enhanced birefringence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinyi Wang, Xin Wen, Yuchen Yan, Jindong Chen, Guangsai Yang, Guang Peng, Ning Ye

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  38. Studies on Three 3D Bimetallic Tellurates: Including a Second-Order NLO Material with d10-Zn2+ and SOJT-Effect Te4+/Mo6+ Cations

    Inorganic Chemistry · 2025-08-14

    Yuquan Feng, Zhiguo Zhong, Shuyang Chen, Sujuan Jin, Zhaohui Meng, Hongwei Wang

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  39. Synthesis, structure and magnetic properties of two selenites, Li2Mn2.5(SeO3)4 and Li2Co3(SeO3)4 with a one-dimensional spin-chain

    Journal of Solid State Chemistry · 2025-12-24

    Mingming Huang, Shoushuang Li, Rui Cui, Laura C.J. Pereira, Ambre Theron, Olivier Mentré, Xiedong Cheng, Feifan Li, Hui Shao, Minfeng Lü

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  40. The rare earth metal(III) oxotellurates(IV) RE 2 Te 3 O 9 in the B -type structure with RE = Y and Sm–Er

    Zeitschrift für Naturforschung B · 2026-01-01

    Sheng-Chun Chou, Ralf J. C. Locke, Philip L. Russ, Katja Engel, Thomas Schleid

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  41. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

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