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RESEARCH PAPER · Inorganic Chemistry · 2014

Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

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Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation LinkersOriginalDimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 619ChemInform Abstract: Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers.1Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O21Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework36Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O833Editorial for the ACS Select Collection on Solid-State Chemistry1Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O823Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates82Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)30New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O813Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework19[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds18RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material341Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain19Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)8A review of the structural architecture of tellurium oxycompounds170Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity38BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution207Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials259Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 108Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions3Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations12A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl26Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+90Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O8Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data8IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Raman Spectra of Minerals13Na2Mg1−xZnxSiO4 (0 ≤ x ≤ 1): Noncentrosymmetric Sodium Metal Silicate Solid Solutions with Ultraviolet Nonlinear Optical Properties71Recent progress in selenite and tellurite based SHG materials32Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response63Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)15Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence36Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties0Structural characterization of quaternary selenites of tungsten(VI), A 2W3SeO12 (A = NH4, Cs, Rb, K or Tl)1Nonlinear optical properties of a new polar bismuth tellurium oxide fluoride, Bi3F(TeO3)(TeO2F2)315Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO 3 ) 2 and Y 3 F(SeO 3 ) 485The First UV Nonlinear Optical Selenite Material: Fluorination Control in CaYF(SeO3)2 and Y3F(SeO3)47Syntheses, Crystal Structure, and Second Harmonic Generation Response of Noncentrosymmetric Layered Selenites and Tellurites of Antimony(V), ASb 3 X 2 O 12 (A = K, Rb, Cs, Tl; X = Se, Te)17Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6Pb2TeV2O10: A Lead Vanadate Tellurate with Wide Mid-IR Transparency and Large Birefringence Induced by Multiple Birefringence-Active Groups11Synthesis and Characterization of (H7C5N2)6(V10O28)·2H2O with Edge-Sharing VO6 Octahedra Exhibiting Large Birefringence2Tuning birefringence in alkaline-earth metal oxyhalides through diverse mixed-cation coordination architectures1Synthesis, crystal growth, properties of a new neodymium-niobium-tellurite NdNbTe2O8 and comparison with compounds of same structural type0High-selectivity fluoride capture by purely inorganic copper tellurite of Cu7F2(TeO3)6: Adsorption performance and mechanistic insights0

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  1. Dimensionality variations in new zirconium iodates: hydrothermal syntheses, structural determination, and characterization of BaZr(IO 3 ) 6 and K 2 Zr(IO 3 ) 6

    Dalton Transactions · 2014-01-01

    Hyun Sun Ahn, Dong Woo Lee, Kang Min Ok

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  2. ChemInform Abstract: Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers.

    ChemInform · 2014-03-14

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  3. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

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  4. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

    Inorganic Chemistry · 2014-05-07

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

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  5. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

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  6. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  7. New Polymorphs of Ternary Sodium Tellurium Oxides: Hydrothermal Synthesis, Structure Determination, and Characterization of β-Na2Te4O9 and Na2Te2O6·1.5H2O

    Inorganic Chemistry · 2014-09-11

    Dong Woo Lee, Kang Min Ok

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  8. Effect of Halogen (Cl, Br) on the Symmetry of Flexible Perovskite-Related Framework

    Inorganic Chemistry · 2014-09-26

    Chunyan Bai, Hongwei Yu, Shujuan Han, Shilie Pan, Bingbing Zhang, Ying Wang, Hongping Wu, Zhihua Yang

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  9. Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8

    Inorganic Chemistry · 2014-10-08

    Su‐whan Bae, Choong-Yeol Kim, Dong Woo Lee, Kang Min Ok

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  10. Editorial for the ACS Select Collection on Solid-State Chemistry

    Inorganic Chemistry · 2014-10-20

    P. Shiv Halasyamani

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  11. Rich Structural Chemistry in New Alkali Metal Yttrium Tellurites: Three-Dimensional Frameworks of NaYTe4O10, KY(TeO3)2, RbY(TeO3)2, and a Novel Variant of Hexagonal Tungsten Bronze, CsYTe3O8

    Inorganic Chemistry · 2014-12-17

    Youngkwon Kim, Dong Woo Lee, Kang Min Ok

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  12. Macroscopic polarity control with alkali metal cation size and coordination environment in a series of tin iodates

    Inorganic Chemistry Frontiers · 2015-01-01

    Yeong Hun Kim, T. Thao Tran, P. Shiv Halasyamani, Kang Min Ok

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  13. Second-harmonic generation (SHG) and photoluminescence properties of noncentrosymmetric (NCS) layered perovskite solid solutions, CsBi 1−x Eu x Nb 2 O 7 (x = 0, 0.1, and 0.2)

    Journal of Materials Chemistry C · 2015-01-01

    Hyung Gu Kim, Jae Soo Yoo, Kang Min Ok

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  14. New quaternary oxides with both families of second-order Jahn–Teller (SOJT) distortive cations: Solid-state synthesis, structure determination, and characterization of YNbTe2O8 and YNbSe2O8

    Journal of Alloys and Compounds · 2015-03-05

    Yeong Hun Kim, Beom‐Yong Jeon, Tae‐Soo You, Kang Min Ok

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  15. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  16. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

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  17. Ba2B6O11, a Member of the BaO‐B2O3 Family, Featuring a Layer Framework

    European Journal of Inorganic Chemistry · 2015-06-24

    Lili Liu, Yun Mo Yang, Xiaoyu Dong, Lei Chen, Shujuan Han, Shilie Pan

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  18. [NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

    Zeitschrift für Kristallographie - Crystalline Materials · 2015-08-07

    Vadim M. Kovrugin, Sergey V. Krivovichev, Olivier Mentré, Marie Colmont

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  19. RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material

    Journal of the American Chemical Society · 2015-08-10

    T. Thao Tran, Jiangang He, James M. Rondinelli, P. Shiv Halasyamani

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  20. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

    Inorganic Chemistry · 2015-08-26

    Seong‐eun Bang, Kang Min Ok

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  21. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  22. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

    Springer mineralogy · 2016-01-01

    Nikita V. Chukanov, A. D. Chervonnyi

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  23. Synthesis and Characterization of Three New Layered Vanadium Tellurites, MVTe2O8 (M = Al, Ga, and Mn): Three-Dimensional (3-D) Antiferromagnetic Behavior of MnVTe2O8 with a Zigzag S = 2 Spin Chain

    Inorganic Chemistry · 2016-01-14

    Su‐whan Bae, Jisun Yoo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  24. Nonlinear optical (NLO) properties and temperature-dependent photoluminescence in activator-doped noncentrosymmetric (NCS) bismuth tellurite solid solutions, Bi2−Ln TeO5 (Ln = Ce and Eu)

    Journal of Alloys and Compounds · 2016-02-24

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  25. A review of the structural architecture of tellurium oxycompounds

    Mineralogical Magazine · 2016-05-01

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  26. Polar Noncentrosymmetric ZnMoSb2O7 and Nonpolar Centrosymmetric CdMoSb4O10: d10 Transition Metal Size Effect Influencing the Stoichiometry and the Centricity

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  27. BiFSeO 3 : An Excellent SHG Material Designed by Aliovalent Substitution

    Journal of the American Chemical Society · 2016-07-18

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  28. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

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  29. Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials

    Journal of the American Chemical Society · 2016-12-24

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  30. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017-01-01

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

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  31. New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )

    Journal of Solid State Chemistry · 2017-02-16

    Mingli Liang, Matthew L. Marsh, Xian-Xing Shang, Jiang‐Gao Mao, Thomas E. Albrecht‐Schmitt, Fang Kong

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  32. Syntheses and structural characterization of vanado-tellurites and vanadyl-selenites: SrVTeO 5 (OH), Cd 2 V 2 Te 2 O 11 , Ca 3 VSe 4 O 13 ·H 2 O and Ba 2 VSe 3 O 10

    Journal of Solid State Chemistry · 2017-02-21

    Satish Konatham, Kanamaluru Vidyasagar

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  33. Synthesis, second-harmonic generations (SHG), and photoluminescence (PL) properties of Ca 4 Bi 6-x Ln x O 13 (Ln=La and Eu) solid solutions

    Journal of Solid State Chemistry · 2017-05-04

    Hoyong Jung, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

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  34. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  35. Lanthanide Inorganic Solids Based on Main Group Borates and Oxyanions of Lone Pair Cations

    Chinese Journal of Chemistry · 2017-11-17

    Fang Kong, Yun‐Xiang Ma, Jiang‐Gao Mao

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  36. A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron

    Dalton Transactions · 2017-12-18

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  37. Crystal structures and characterizations of two new selenite chlorides: 1D Ba2Zn(SeO3)2Cl2 and 2D BaZn2(SeO3)2Cl2

    Journal of Solid State Chemistry · 2018-05-26

    Qiang Li, Lei Geng, Hong‐Yan Lu, Kai Dai, Wen‐Dan Cheng

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  38. Functional layered materials with heavy metal lone pair cations, Pb 2+ , Bi 3+ , and Te 4+

    Chemical Communications · 2019-01-01

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  39. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

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  40. Two Deep Ultraviolet Hydrated Borate Crystals: Centrosymmetric LiRbB5O8(OH)·H2O and Non-Centrosymmetric K2B5O8(OH)·2H2O

    Crystal Growth & Design · 2019-04-03

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  41. Crystal structure and second harmonic generation in Bi2TeO5: An X-N study from synchrotron and neutron diffraction data

    Journal of Solid State Chemistry · 2019-04-29

    Carlos Alberto López, E. Bâati, María Teresa Fernández-Díaz, Felix O. Saouma, Joon Ik Jang, J. A. Alonso

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  42. IR Spectra of Minerals and Related Compounds, and Reference Samples Data

    Springer mineralogy · 2019-11-28

    Nikita V. Chukanov, Marina F. Vigasina

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  43. Raman Spectra of Minerals

    Springer mineralogy · 2019-11-28

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  44. Na2Mg1−xZnxSiO4 (0 ≤ x ≤ 1): Noncentrosymmetric Sodium Metal Silicate Solid Solutions with Ultraviolet Nonlinear Optical Properties

    Bulletin of the Korean Chemical Society · 2019-12-15

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  45. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

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  46. Bi 3 (SeO 3 ) 3 (Se 2 O 5 )F: A Polar Bismuth Selenite Fluoride with Polyhedra of Highly Distortive Lone Pair Cations and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2020-07-01

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  47. Unique synthesis, structure determination, and optical properties of seven new layered rare earth tellurite nitrates, RE(TeO3)(NO3) (RE = La, Nd, Eu, Gd, Dy, Er, and Y)

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  48. Y 2 (Te 4 O 10 )(SO 4 ): a new sulfate tellurite with a unique Te 4 O 10 polyanion and large birefringence

    Inorganic Chemistry Frontiers · 2020-10-26

    Pengfei Li, Chun‐Li Hu, Fang Kong, Shao‐Ming Ying, Jiang‐Gao Mao

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  49. Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

    Journal of Solid State Chemistry · 2021-02-06

    Dong Woo Lee, Hye Ran Noh, Tae-Hyeong Kim, Jeongmook Lee, Jong‐Yun Kim, Kyung‐Tae Ko, Sang Ho Lim

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  50. New Solids in As-O-Mo, As(P)-O-Mo(W) and As(P)-O-Nb(W) Systems That Exhibit Nonlinear Optical Properties

    Molecules · 2021-03-09

    Nikolay Gerasimchuk, Lauri Kivijärvi, Bruce C. Noll, Meriem Goudjil, S. Khanra, Ping Yu, Miles Pearson, Frank Röminger

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