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RESEARCH PAPER · Inorganic Chemistry · 2015

Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite SystemOriginalNew niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion10A series of new silver selenites with d 0 -TM cations19ChemInform Abstract: Explorations of New SHG Materials in the Alkali‐Metal—Nb5+—Selenite System.0A(II)GeTeO6 (A = Mn, Cd, Pb): Non-Centrosymmetric Layered Tellurates with PbSb2O6-Related Structure25Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0(H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer19Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation27Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores14Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties37Recent progress in selenite and tellurite based SHG materials32Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution58Synthesis and characterization of binary selenides of transition metals to investigate its photocatalytic, antimicrobial and anticancer efficacy51BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses63Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites23Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]8Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization3Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph1From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency21A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15Syntheses and characterization of quaternary selenites and tellurite of antimony, NaSbSe2O7, AgSbSe2O7 and Na2Sb4Te2O140A survey of stereoactive oxysalts for linear and nonlinear optical applications40Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds22AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap20Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites56RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps6Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite10LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion3

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  1. New niobium selenites, ANbO(SeO3)2 (A = Na, K, Rb, and Cs): Effect of alkali metal cation size on the dimensionality and intraoctahedral distortion

    Journal of Alloys and Compounds · 2015-12-17

    Youngkwon Kim, Bongsu Kim, Kang Min Ok

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  2. A series of new silver selenites with d 0 -TM cations

    RSC Advances · 2016-01-01

    Qian Qian, Fang Kong, Jiang‐Gao Mao

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  3. ChemInform Abstract: Explorations of New SHG Materials in the Alkali‐Metal—Nb5+—Selenite System.

    ChemInform · 2016-01-01

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  4. A(II)GeTeO6 (A = Mn, Cd, Pb): Non-Centrosymmetric Layered Tellurates with PbSb2O6-Related Structure

    Inorganic Chemistry · 2017-07-24

    Sun Woo Kim, Zheng Deng, Shuang Yu, Haricharan Padmanabhan, Weiguo Zhang, Venkatraman Gopalan, Changqing Jin, M. Greenblatt

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  5. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  6. A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron

    Dalton Transactions · 2017-12-18

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  7. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

    Inorganic Chemistry · 2018-03-07

    Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

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  8. Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals

    International Scientific-Technical Conference on Actual Problems of Electronic Instrument Engineering (APEIE) · 2018-10-01

    Boris I. Kidyarov, Макуха Владимир Карпович

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  9. (H 3 O)HCs 2 Nb(IO 3 ) 9 and SrNbO(IO 3 ) 5 : a facile synthetic method using hydrofluoric acid as a solubilizer

    Chemical Communications · 2019-01-01

    Fei‐Fei Mao, Chun‐Li Hu, Jin Chen, Ru‐Ling Tang, Bao-Lin Wu, Jiang‐Gao Mao

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  10. Pb 2 Cd(SeO 3 ) 2 X 2 (X = Cl and Br): two halogenated selenites with phase matchable second harmonic generation

    Inorganic Chemistry Frontiers · 2019-01-01

    Ya-Ping Gong, Chun‐Li Hu, Yun‐Xiang Ma, Jiang‐Gao Mao, Fang Kong

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  11. Bi2Te2O6(NO3)2(OH)2(H2O): A layered bismuth tellurium nitrate hydroxide with multiple noncentrosymmetric chromophores

    Journal of Solid State Chemistry · 2019-01-11

    Soyon Lee, Hongil Jo, Kang Min Ok

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  12. Layered Bismuth Oxyfluoride Nitrates Revealing Large Second-Harmonic Generation and Photocatalytic Properties

    Inorganic Chemistry · 2019-01-16

    Eun Jeong Cho, Seung‐Jin Oh, Hongil Jo, Junsu Lee, Tae‐Soo You, Kang Min Ok

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  13. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

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  14. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

    Dalton Transactions · 2020-01-01

    Huanke Zhao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  15. Enhancement of Second-Order Optical Nonlinearity in a Lutetium Selenite by Monodentate Anion Partial Substitution

    Chemistry of Materials · 2020-03-16

    Chao Wu, Longhua Li, Lin Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  16. Synthesis and characterization of binary selenides of transition metals to investigate its photocatalytic, antimicrobial and anticancer efficacy

    Applied Nanoscience · 2020-03-21

    S. Altaf, Humayun Ajaz, M. Imran, Anwar Ul‐Hamid, M. Naz, M. Aqeel, Anum Shahzadi, Atif Shahbaz, Muhammad Ikram

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  17. BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution

    Inorganic Chemistry · 2020-05-09

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  18. AGa 3 F 6 (SeO 3 ) 2 (A = Rb, Cs): A New Type of Phase-Matchable Hexagonal Tungsten Oxide Material with Strong Second-Harmonic Generation Responses

    Chemistry of Materials · 2020-06-23

    Chao Wu, Xingxing Jiang, Lin Lin, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  19. Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response

    Chemistry of Materials · 2020-11-04

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  20. Role of fluorine on the structure and second-harmonic-generation property of inorganic selenites and tellurites

    Chemical Communications · 2021-01-01

    Fang Kong, Ting-Kun Jiang, Jiang‐Gao Mao

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  21. Systematic centricity control using a chiral template: novel noncentrosymmetric polar niobium oxyfluorides and tantalum fluorides directed by chiral histidinium cations, [( l -hisH 2 )NbOF 5 ], [( d -hisH 2 )NbOF 5 ], [( l -hisH 2 )TaF 7 ], and [( d -hisH 2 )TaF 7 ]

    Inorganic Chemistry Frontiers · 2021-01-01

    HeeJung Choi, Kang Min Ok

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  22. Mixed-valent titanium tellurium oxides, Ti1-xTexTe3O8+x (x = 0, 0.1, and 0.12): Hydrothermal synthesis, structure, and characterization

    Journal of Solid State Chemistry · 2021-02-06

    Dong Woo Lee, Hye Ran Noh, Tae-Hyeong Kim, Jeongmook Lee, Jong‐Yun Kim, Kyung‐Tae Ko, Sang Ho Lim

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  23. Flux synthesis, crystal structure, and characterization of a gamma-vanadate selenite polymorph

    Journal of Solid State Chemistry · 2022-01-22

    Honggang Wang, Jian‐Han Zhang, Ming-Shui Lin, Tianyu Wang, Zhijian Zhang, Shufeng Yan, Shao‐Ming Ying

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  24. From CdPb 8 (SeO 3 ) 4 Br 10 to Pb 3 (TeO 3 )Br 4 : the first tellurite bromide exhibiting an SHG response and mid-IR transparency

    Inorganic Chemistry Frontiers · 2023-01-01

    Pengfei Li, Chun‐Li Hu, Bing-Xuan Li, Jiang‐Gao Mao, Fang Kong

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  25. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

    Materials Today Physics · 2023-06-01

    Jingru Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  26. Syntheses and characterization of quaternary selenites and tellurite of antimony, NaSbSe2O7, AgSbSe2O7 and Na2Sb4Te2O14

    Journal of Solid State Chemistry · 2023-07-27

    Rintu Robert, Shilpa Mangalassery, D. Narayana Rao, Kanamaluru Vidyasagar

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  27. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

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  28. Four UV Transparent Linear and Nonlinear Optical Materials Explored from Pure Selenite Compounds

    Advanced Optical Materials · 2023-09-01

    Pengfei Li, Ya-Ping Gong, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  29. AX·(H2SeO3)n (A = K, Cs; X = Cl, Br; n = 1, 2): A Series of Ionic Cocrystals as Promising UV Birefringent Materials with Large Birefringence and Wide Band Gap

    Inorganic Chemistry · 2024-01-18

    Mengmeng Zhu, Junbo Wang, Lei Hou, Yiwen Yuan, Lili Liu, Yaoqing Chu, Chunmei Huang

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  30. Old tree blossoms anew: Research progress on the structures and optical properties of ultraviolet selenites

    Coordination Chemistry Reviews · 2024-06-15

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  31. RE(HSeO3)(SeO3)(H2O)·(H2O) (RE = Y, Gd): Two Rare-Earth Selenite Nonlinear Optical Crystals with Wide Band Gaps

    Inorganic Chemistry · 2024-10-08

    Junjiang Li, Huanke Zhao, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Yicheng Wu

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  32. Chemical Substitution‐Driven Design of a High‐Performance Noncentrosymmetric Bismuth Molybdenum Selenite

    Advanced Optical Materials · 2025-01-17

    Hieu Minh Ngo, Yunseung Kuk, Jihyun Lee, Jiachen Lu, Zhiyong Bai, Chun‐Li Hu, Kang Min Ok

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  33. LiV 3 Se 2 O 12 : A Promising Giant‐Birefringent Crystal Enabled by Significant Structural Distortion

    Small · 2025-12-26

    Qiuyuan Feng, Jialong Wang, Qun Jing, Xiaoyu Dong, Shilie Pan

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