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RESEARCH PAPER · Inorganic Chemistry · 2012

Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)

Sau Doan Nguyen, P. Shiv Halasyamani

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Synthesis, Structure, and Characterization of New Li+ – d0 –Lone-Pair – Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3(SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+)OriginalChemInform Abstract: Synthesis, Structure, and Characterization of New Li+—d0—Lone‐Pair — Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3 (SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M: Mo6+ or W6+).0The new nickel tellurite chloride compound Ni 15 Te 12 O 34 Cl 10 – synthesis, crystal structure and magnetic properties11Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide11ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units53New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O2239Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br350A new phase in the MnII–SeIV–MoVI–O system, Mn(MoO3)(SeO3)(H2O): Hydrothermal synthesis, crystal structure and properties2Crystal Structure and Magnetic Properties of FeSeO3F—Alternating Antiferromagnetic S = 5/2 chains42Acentric Pseudo-Kagome Structures: The Solid Solution (Co 1– x Ni x ) 3 Sb 4 O 6 F 625Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons67A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations18Phase identification and structure determination from multiphase crystalline powder samples by rotation electron diffraction34Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra67Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates14Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)315Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System33IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data21Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal21Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations85Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Hydrothermal Synthesis of the Oxofluoride FeSbO2F2—An Anti-ferromagnetic Spin S = 5/2 Compound16Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties26A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron33Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions26Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations32Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)16Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)21Second-order nonlinear optical crystals with mixed anions250Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals0Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties19Crystal Structure of the Disordered Non-Centrosymmetric Compound Fe0.43Mo2.56SbO9.53New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br17IR Spectra of Minerals and Related Compounds, and Reference Samples Data3Recent progress in selenite and tellurite based SHG materials32Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)218Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)22Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates10BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution19Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response69Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)27A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations5Investigation of the Ferroelectric, Magnetic and Magnetoelectric Properties in Honeycomb-Layered YCrTeO62Data-Driven High-Throughput Screening and Experimental Realization of Ag2B(IV)B′(VI)O6 under Negative Chemical-Pressure1Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials10Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials1

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  1. ChemInform Abstract: Synthesis, Structure, and Characterization of New Li+—d0—Lone‐Pair — Oxides: Noncentrosymmetric Polar Li6(Mo2O5)3 (SeO3)6 and Centrosymmetric Li2(MO3)(TeO3) (M: Mo6+ or W6+).

    ChemInform · 2012-10-18

    Sau Doan Nguyen, P. Shiv Halasyamani

    Read original paper ↗ ·

  2. The new nickel tellurite chloride compound Ni 15 Te 12 O 34 Cl 10 – synthesis, crystal structure and magnetic properties

    Dalton Transactions · 2012-10-24

    Dong Zhang, Mats Johnsson, Sven Lidin, Reinhard Karl Kremer

    Read original paper ↗ ·

  3. Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide

    Dalton Transactions · 2013-01-01

    Shichao Hu, Mats Johnsson

    Read original paper ↗ ·

  4. ZnTeMoO6: a strong second-harmonic generation material originating from three types of asymmetric building units

    RSC Advances · 2013-01-01

    Sangen Zhao, Junhua Luo, Pan Zhou, Shuquan Zhang, Zhihua Sun, Maochun Hong

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  5. New Molybdenum(VI) Phosphates: Synthesis, Characterization, and Calculations of Centrosymmetric RbMoO2PO4and Noncentrosymmetric Rb4Mo5P2O22

    Inorganic Chemistry · 2013-01-15

    Ying Wang, Shilie Pan, Xin Su, Zhihua Yang, Lingyun Dong, Min Zhang

    Read original paper ↗ ·

  6. Effect of Rigid Units on the Symmetry of the Framework: Design and Synthesis of Centrosymmetric NaBa4(B5O9)2F2Cl and Noncentrosymmetric NaBa4(AlB4O9)2Br3

    Crystal Growth & Design · 2013-07-01

    Hongwei Yu, Shilie Pan, Hongping Wu, Zhihua Yang, Lingyun Dong, Xin Su, Bingbing Zhang, Hongyi Li

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  7. A new phase in the MnII–SeIV–MoVI–O system, Mn(MoO3)(SeO3)(H2O): Hydrothermal synthesis, crystal structure and properties

    Solid State Sciences · 2013-08-09

    Yanzhong Zhen, Danjun Wang, Bin Liu, Feng Fu, Ganglin Xue

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  8. Crystal Structure and Magnetic Properties of FeSeO3F—Alternating Antiferromagnetic S = 5/2 chains

    Inorganic Chemistry · 2014-03-31

    Shichao Hu, Mats Johnsson, Joseph M. Law, Jerry L. Jr. Bettis, Myung‐Hwan Whangbo, Reinhard Karl Kremer

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  9. Acentric Pseudo-Kagome Structures: The Solid Solution (Co 1– x Ni x ) 3 Sb 4 O 6 F 6

    Chemistry of Materials · 2014-05-30

    Shichao Hu, Mats Johnsson, P. Lemmens, Daniel Schmid, Dirk Мenzel, Joshua H. Tapp, Angela Möller

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  10. Pb 4 V 6 O 16 (SeO 3 ) 3 (H 2 O), Pb 2 VO 2 (SeO 3 ) 2 Cl, and PbVO 2 (SeO 3 )F: New Lead(II)–Vanadium(V) Mixed-Metal Selenites Featuring Novel Anionic Skeletons

    Inorganic Chemistry · 2014-08-07

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Xiang Xu, Jiang‐Gao Mao

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  11. A series of novel mercury( i ) selenites and tellurites containing SOJT Mo 6+ cations

    Inorganic Chemistry Frontiers · 2014-10-15

    Xue‐Li Cao, Fang Kong, Chun‐Li Hu, Jiang‐Gao Mao

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  12. Phase identification and structure determination from multiphase crystalline powder samples by rotation electron diffraction

    Journal of Applied Crystallography · 2014-11-28

    Yifeng Yun, Wei Wan, Faiz Rabbani, Jie Su, Hongyi Xu, Sven Hovmöller, Mats Johnsson, Xiaodong Zou

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  13. Cs(TaO 2 ) 3 (SeO 3 ) 2 and Cs(TiOF) 3 (SeO 3 ) 2 : Structural and Second Harmonic Generation Changes Induced by the Different d 0 -TM Coordination Octahedra

    Inorganic Chemistry · 2015-04-02

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  14. Effects of Te(IV) Oxo-Anion Incorporation into Thorium Molybdates and Tungstates

    Inorganic Chemistry · 2015-05-28

    Bin Xiao, Martina Klinkenberg, Dirk Bosbach, Evgeny V. Suleimanov, Evgeny V. Alekseev

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  15. Structure-Directing Effect of Alkali Metal Cations in New Molybdenum Selenites, Na2Mo2O5(SeO3)2, K2Mo2O5(SeO3)2, and Rb2Mo3O7(SeO3)3

    Inorganic Chemistry · 2015-08-26

    Seong‐eun Bang, Kang Min Ok

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  16. Explorations of New SHG Materials in the Alkali-Metal–Nb5+–Selenite System

    Inorganic Chemistry · 2015-10-29

    Xue‐Li Cao, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  17. IR Spectra of Minerals and Related Compounds, and Reference Samples’ Data

    Springer mineralogy · 2016-01-01

    Nikita V. Chukanov, A. D. Chervonnyi

    Read original paper ↗ ·

  18. Second order nonlinear optical properties of Cs_2TeW_3O_12 single crystal

    Optical Materials Express · 2016-01-14

    Peng Zhao, Qian Wu, Chunlong Li, Shao-Jun Zhang, Youxuan Sun, Chengqian Zhang, Sheng‐Qing Xia, Zeliang Gao, Xutang Tao

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  19. Cd3(MoO4)(TeO3)2: A Polar 3D Compound Containing d10–d0 SCALP-Effect Cations

    Inorganic Chemistry · 2016-11-09

    Yuquan Feng, Hui‐Tao Fan, Zhiguo Zhong, Hongwei Wang, Dongfang Qiu

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  20. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017-01-01

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

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  21. Hydrothermal Synthesis of the Oxofluoride FeSbO2F2—An Anti-ferromagnetic Spin S = 5/2 Compound

    Inorganic Chemistry · 2017-03-24

    S. Ali, Reinhard Karl Kremer, Mats Johnsson

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  22. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

    Read original paper ↗ ·

  23. Zn 3 Sb 4 O 6 F 6 : Hydrothermal synthesis, crystal structure and nonlinear optical properties

    Journal of Solid State Chemistry · 2017-08-25

    S. Ali, Weiguo Zhang, P. Shiv Halasyamani, Mats Johnsson

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  24. A(VO 2 F)(SeO 3 ) (A = Sr, Ba) and Ba(MOF 2 )(TeO 4 ) (M = Mo, W): first examples of alkali-earth selenites/tellurites with a fluorinated d 0 -TM octahedron

    Dalton Transactions · 2017-12-18

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  25. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

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  26. A Large Family of Centrosymmetric and Chiral f-Element-Bearing Iodate Selenates Exhibiting Coordination Number and Dimensional Reductions

    Inorganic Chemistry · 2018-01-18

    Meiying Qie, Jian Hung Lin, Fang Kong, Mark A. Silver, Zenghui Yue, Xiaomei Wang, Linjuan Zhang, Hongliang Bao, Thomas E. Albrecht‐Schmitt, Jian‐Qiang Wang

    Read original paper ↗ ·

  27. Li6M(SeO3)4 (M = Co, Ni, and Cd) and Li2Zn(SeO3)2: Selenites with Late Transition-Metal Cations

    Inorganic Chemistry · 2018-03-07

    Hongil Jo, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

    Read original paper ↗ ·

  28. Three new d10 transition metal selenites containing PO4 tetrahedron: Cd7(HPO4)2(PO4)2(SeO3)2, Cd6(PO4)1.34(SeO3)4.66 and Zn3(HPO4)(SeO3)2(H2O)

    Journal of Solid State Chemistry · 2018-03-28

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  29. Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates BiMTeO6 (M = Al, Ga)

    Inorganic Chemistry · 2018-06-15

    Fenghua Ding, Matthew Lander Nisbet, Hongwei Yu, Weiguo Zhang, Liyuan Chai, P. Shiv Halasyamani, Kenneth Reinhard Poeppelmeier

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  30. Second-order nonlinear optical crystals with mixed anions

    Coordination Chemistry Reviews · 2018-08-06

    Yu Pan, Sheng‐Ping Guo, Bin‐Wen Liu, Huaiguo Xue, Guo‐Cong Guo

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  31. Interrelationship «Composition - Structure - Property» for Acentric Selenite Crystals

    International Scientific-Technical Conference on Actual Problems of Electronic Instrument Engineering (APEIE) · 2018-10-01

    Boris I. Kidyarov, Vladimir K. Makukha

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  32. Expansion of the structural diversity of f-element bearing molybdate iodates: synthesis, structures, and optical properties

    Dalton Transactions · 2019-01-01

    Jian Hung Lin, Qi Liu, Zenghui Yue, Kariem Diefenbach, Liwei Cheng, Yue‐Jian Lin, Jian‐Qiang Wang

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  33. Crystal Structure of the Disordered Non-Centrosymmetric Compound Fe0.43Mo2.56SbO9.5

    Crystals · 2019-01-15

    S. Ali, Sven Lidin, Mats Johnsson

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  34. New cadmium-selenium-oxyhalides: Noncentrosymmetric Cd5(SeO3)4Cl2(H2O) and centrosymmetric Cd2(SeO3)F2, Cd2(SeO3)(OH)Br

    Journal of Solid State Chemistry · 2019-02-27

    Meng Shang, Lili Liu, P. Shiv Halasyamani

    Read original paper ↗ ·

  35. IR Spectra of Minerals and Related Compounds, and Reference Samples Data

    Springer mineralogy · 2019-11-28

    Nikita V. Chukanov, Marina F. Vigasina

    Read original paper ↗ ·

  36. Recent progress in selenite and tellurite based SHG materials

    Dalton Transactions · 2020-01-01

    Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  37. Structural Diversity of Molybdate Iodate and Fluoromolybdate: Syntheses, Structures, and Calculations on Na3(MoO4)(IO3) and Na3Cs(MoO2F4)2

    Inorganic Chemistry · 2020-02-13

    Tingting Shi, Fangfang Zhang, Yahui Li, Le Gao, Zhihua Yang, Shilie Pan

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  38. Mixed-valent selenium compounds: Noncentrosymmetric Cd3(SeO3)2(SeO4) and Hg3(SeO3)2(SeO4) and centrosymmetric Pb2(SeO3) (SeO4)

    Journal of Solid State Chemistry · 2020-03-02

    Meng Shang, P. Shiv Halasyamani

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  39. Effect of Mo/P Ratios on Dimensions: Syntheses, Structures, and Properties of Three New Molybdophosphates

    Inorganic Chemistry · 2020-04-03

    Haonan Liu, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  40. BiGa(SeO3)3: A Phase Matchable SHG Material Achieved by Cation Substitution

    Inorganic Chemistry · 2020-05-09

    Yun‐Xiang Ma, Ya-Ping Gong, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  41. Ba(MoO 2 F) 2 (QO 3 ) 2 (Q = Se, Te): Partial Fluorination of MoO 6 Octahedra Enabling Two Polar Solids with Strong and Phase Matchable SHG Response

    Chemistry of Materials · 2020-11-04

    Mingli Liang, Yun‐Xiang Ma, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

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  42. Study of Integer Spin S = 1 in the Polar Magnet β-Ni(IO3)2

    Molecules · 2021-11-28

    Ebube E. Oyeka, Michal Jerzy Winiarski, T. Thao Tran

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  43. A 6 Mo 2 P 4 O 19 (A = Rb, Cs) and Rb 2 MoP 2 O 9 : new molybdophosphates with distinct polyanionic configurations

    Dalton Transactions · 2021-12-13

    Maierhaba Abudoureheman, Juanjuan Zheng, Peng Wang, Bo Wei, Zhiyong Guo, Zhaohui Chen, Yanna Chen

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  44. Investigation of the Ferroelectric, Magnetic and Magnetoelectric Properties in Honeycomb-Layered YCrTeO6

    Journal of Electronic Materials · 2023-04-07

    Raja Altaf U Rahman, Nazir Ahmad Mala, Mehraj ud Din Rather, Gowher Hameed Rather, Ishfaq Ahmad Parray, Asma Shahzadi, Sonabar Saqib, Shahid Husain, Basharat Ahmad Want

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  45. Data-Driven High-Throughput Screening and Experimental Realization of Ag2B(IV)B′(VI)O6 under Negative Chemical-Pressure

    Chemistry of Materials · 2024-07-09

    Zhongxiong Sun, Jinjin Yang, Yifeng Han, Man‐Rong Li

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  46. Recent achievements of d0 transition-metal-based oxyfluorides: Crystal chemistry and application in second-order NLO materials

    Coordination Chemistry Reviews · 2025-11-06

    Tianhui Wu, Jiahang Liu, Meiqi Liu, Xuan Li, Miao Zhang, Weiwei Cao, Jianmin Gu, Desong Wang

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  47. Cation-driven symmetry breaking in rare-earth borates toward ultraviolet nonlinear optical materials

    Materials Today Physics · 2026-07-04

    D K Li, Yujie Zhang, H Liu, Hongping Wu, Zhanggui Hu, Hongwei Yu

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