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RESEARCH PAPER · Inorganic Chemistry · 2012

Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)

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Cation Size Effect on the Framework Structures in a Series of New Alkali-Metal Indium Selenites, AIn(SeO3)2 (A = Na, K, Rb, and Cs)OriginalChemInform Abstract: Cation Size Effect on the Framework Structure in a Series of New Alkali‐Metal Indium Selenites, AIn(SeO3)2 (A: Na, K. Rb, and Cs).0Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites21New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)53New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities76New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O16α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations34VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations15Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers63Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property50Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)51Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)252Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)341Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O833Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O1616Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)41Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)15Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures601Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )6Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations1Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations5New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 43A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides14Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties10Designing Deep‐UV Birefringent Crystals by Cation Regulation57Hexagonal tungsten oxides with large bandgaps synthesized by a chemical substitution method31Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.518Innovative and sustainable separation and recovery of valuable metals in spent CIGS materials50Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5

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  1. ChemInform Abstract: Cation Size Effect on the Framework Structure in a Series of New Alkali‐Metal Indium Selenites, AIn(SeO3)2 (A: Na, K. Rb, and Cs).

    ChemInform · 2012-09-27

    Dong Woo Lee, Saet Byeol Kim, Kang Min Ok

    Read original paper ↗ ·
  2. Syntheses, crystal structures of a series of novel alkali metal or alkaline earth metal phosphites

    CrystEngComm · 2013-01-01

    Xi-Jia Wang, Jian‐Han Zhang, Jun‐Ling Song, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·
  3. New Bismuth Selenium Oxides: Syntheses, Structures, and Characterizations of Centrosymmetric Bi2(SeO3)2(SeO4) and Bi2(TeO3)2(SeO4) and Noncentrosymmetric Bi(SeO3)(HSeO3)

    Inorganic Chemistry · 2013-03-18

    Eun Pyo Lee, Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  4. New Alkali-Metal Gallium Selenites, AGa(SeO3)2 (A = Li, Na, K, and Cs): Effect of Cation Size on the Framework Structures and Macroscopic Centricities

    Inorganic Chemistry · 2013-04-16

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  5. New Selenites: Hydrothermal Syntheses, Crystal Structures, and Characterization of Rb3HGa2(OH)2(SeO3)4, Rb3Ga5(SeO3)8(HSeO3)2·0.5H2O, and RbGa(SeO3)2·H2O

    Inorganic Chemistry · 2013-08-16

    Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  6. α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: New Quaternary Mixed Metal Oxides Composed of Only Second-Order Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2013-09-11

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  7. VSb(SeO3)4, First Selenite Containing V3+ Cation: Synthesis, Structure, Characterization, Magnetic Properties, and Calculations

    Inorganic Chemistry · 2013-11-21

    Yiseul Shin, Dong Woo Lee, Kwang‐Yong Choi, Hyun‐Joo Koo, Kang Min Ok

    Read original paper ↗ ·
  8. Noncentrosymmetric YVSe2O8 and Centrosymmetric YVTe2O8: Macroscopic Centricities Influenced by the Size of Lone Pair Cation Linkers

    Inorganic Chemistry · 2014-01-02

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  9. Noncentrosymmetric versus Centrosymmetric: Influence of the Na+ Substitution on Structural Transition and Second-Harmonic Generation Property

    Crystal Growth & Design · 2014-03-13

    Shujuan Han, Ying Wang, Shilie Pan, Xiaoyu Dong, Hongping Wu, Jian Wei Han, Yun Mo Yang, Hongwei Yu, Chunyan Bai

    Read original paper ↗ ·
  10. Variable Framework Structures and Centricities in Alkali Metal Yttrium Selenites, AY(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2014-04-22

    Seong‐eun Bang, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  11. Strong Second Harmonic Generation (SHG) Originating from Combined Second-Order Jahn–Teller (SOJT) Distortive Cations in a New Noncentrosymmetric Tellurite, InNb(TeO4)2

    Inorganic Chemistry · 2014-05-07

    Yeong Hun Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  12. Rich Structural Chemistry in Scandium Selenium/Tellurium Oxides: Mixed-Valent Selenite–Selenates, Sc2(SeO3)2(SeO4) and Sc2(TeO3)(SeO3)(SeO4), and Ternary Tellurite, Sc2(TeO3)3

    Inorganic Chemistry · 2014-06-11

    Seung Yoon Song, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  13. Cooperative Effects of Cation Size and Variable Coordination Modes of Te4+ on the Frameworks of New Alkali Metal Indium Tellurites, NaIn(TeO3)2, KIn(TeO3)2, RbInTe3O8, and CsInTe3O8

    Inorganic Chemistry · 2014-10-08

    Su‐whan Bae, Choong-Yeol Kim, Dong Woo Lee, Kang Min Ok

    Read original paper ↗ ·
  14. Synthesis and structural characterization of a new rubidium borosulfate, Rb5BS4O16

    Materials Research Bulletin · 2014-11-25

    Lingyun Dong, Shilie Pan, Ying Wang, Hongwei Yu, Xiaoxia Nina Lin, Shujuan Han

    Read original paper ↗ ·
  15. Modulation of Framework and Centricity: Cation Size Effect in New Quaternary Selenites, ASc(SeO3)2 (A = Na, K, Rb, and Cs)

    Inorganic Chemistry · 2015-04-27

    Seung Yoon Song, Kang Min Ok

    Read original paper ↗ ·
  16. Hydrothermal synthesis, structures and optical properties of A2Zn3(SeO3)4·XH2O (A=Li, Na, K; X=2 or 0)

    Journal of Solid State Chemistry · 2015-10-02

    Yunsheng Liu, Dajiang Mei, Jingli Xu, Yuandong Wu

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  17. Toward the Rational Design of Novel Noncentrosymmetric Materials: Factors Influencing the Framework Structures

    Accounts of Chemical Research · 2016-11-14

    Kang Min Ok

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  18. Ag 3 I[(MoO 3 ) 2 (IO 3 ) 2 ]: a new polar material synthesized from the structural modulation of molybdenyl iodate architectures by polarizable cation (Ag + ) and anion (I − )

    Dalton Transactions · 2017-01-01

    Chang‐Yu Meng, Pei Zhang, Rongfang Wang, Lei Geng

    Read original paper ↗ ·
  19. Alkali earth MO x ( x = 6, 7, 9, 12) polyhedra tuned cadmium selenites with different dimensions and diverse SeO 3 2− coordinations

    CrystEngComm · 2017-01-01

    Ying‐Jie Jia, Yi-Gang Chen, Xiao-Ni Yao, Xian‐Ming Zhang

    Read original paper ↗ ·
  20. Li13Mn(SeO3)8: Lithium-Rich Transition Metal Selenite Containing Jahn–Teller Distortive Cations

    Inorganic Chemistry · 2017-07-25

    Hongil Jo, Seung Yoon Song, Eunjeong Cho, Jongho So, Suheon Lee, Kwang‐Yong Choi, Kang Min Ok

    Read original paper ↗ ·
  21. New quaternary alkali metal cadmium selenites, A 2 Cd(SeO 3 ) 2 (A = K, Rb, and Cs) and Li 2 Cd 3 (SeO 3 ) 4

    Journal of Solid State Chemistry · 2017-09-14

    Minfeng Lü, Hongil Jo, Seung‐Jin Oh, Kang Min Ok

    Read original paper ↗ ·
  22. A cation size effect on the framework structures in ABi 2 SeO 3 F 5 (A = K and Rb): first examples of alkali metal bismuth selenite fluorides

    Dalton Transactions · 2018-01-01

    Shuangshuang Shi, Min Luo, Chensheng Lin, Ning Ye

    Read original paper ↗ ·
  23. Four alkali metal molybdates with two types of Mo–O chains, ABMo 3 O 10 (A = Li, B = Rb; A = Li, Na, K, B = Cs): synthesis, structure comparison and optical properties

    New Journal of Chemistry · 2018-01-01

    Shujuan Han, Bingbing Zhang, Tinghao Tong, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  24. Designing Deep‐UV Birefringent Crystals by Cation Regulation

    Chemistry - A European Journal · 2018-06-25

    Zhizhong Zhang, Ying Wang, Bingbing Zhang, Zhihua Yang, Shilie Pan

    Read original paper ↗ ·
  25. Hexagonal tungsten oxides with large bandgaps synthesized by a chemical substitution method

    Inorganic Chemistry Frontiers · 2020-01-01

    Geonju Park, Kang Min Ok

    Read original paper ↗ ·
  26. Unexpected aliovalent cation substitution between two NLO materials LiBa 3 Bi 6 (SeO 3 ) 7 F 11 and Ba 3 Bi 6.5 (SeO 3 ) 7 F 10.5 O 0.5

    Chemical Communications · 2021-01-01

    Shuangshuang Shi, Chensheng Lin, Dan Zhao, Min Luo, Liling Cao, Guang Peng, Ning Ye

    Read original paper ↗ ·
  27. Innovative and sustainable separation and recovery of valuable metals in spent CIGS materials

    Journal of Cleaner Production · 2022-03-21

    Die Hu, Baozhong Ma, Xiang Li, Yingwei Lv, Yongqiang Chen, Chengyan Wang

    Read original paper ↗ ·
  28. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

    Inorganic Chemistry · 2024-04-23

    Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu, Huaijin Zhang

    Read original paper ↗ ·