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RESEARCH PAPER · Chemistry of Materials · 2018

Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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Hierarchical Materials as Tailored Nuclear Waste Forms: A PerspectiveOriginalBreaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)25Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates21Versatile Uranyl Germanate Framework Hosting 12 Different Alkali Halide 1D Salt Inclusions32High-Pressure Synthesis, Structural, and Spectroscopic Studies of the Ni–U–O System15Flux crystal growth, structure, magnetic and optical properties of a family of alkali uranium(IV) phosphates10An Ultrafast Molecular‐Rotor‐Based Fluorescent Turn‐On Sensor for the Perrhenate Anion in Aqueous Solution40Selective separation and preconcentration of Th( iv ) using organo-functionalized, hierarchically porous silica monoliths44Overstepping Löwenstein’s Rule—A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties28A physics-based mesoscale phase-field model for predicting the uptake kinetics of radionuclides in hierarchical nuclear wasteform materials15Understanding the Polymorphism of A4[(UO2)3(PO4)2O2] (A = Alkali Metals) Uranyl Phosphate Framework Structures10Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family13NanMTh6F30: A Large Family of Quaternary Thorium Fluorides8Flux crystal growth of uranium( v ) containing oxyfluoride perovskites13Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides493d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials14Removing Cs within a continuous flow set-up by an ionic exchanger material transformable into a final waste form15Opportunities of Porous Organic Polymers for Radionuclide Sequestration141Sorption of Eu(III) on MXene-derived titanate structures: The effect of nano-confined space142Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption206A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability50Nanocrystals FAU-X monoliths as highly efficient microreactors for cesium capture in continuous flow22Targeted Synthesis of Uranium(IV) Thiosilicates9Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”97Heterometallic Metal–Organic Frameworks (MOFs): The Advent of Improving the Energy Landscape101Linking the multiscale porous structure of hexacyanoferrate-loaded silica monoliths to their hydrodynamic and cesium sorption properties18Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth13U1.33T4Al8Si2 (T = Ni, Co): Complex Uranium Silicides Grown from Aluminum/Gallium Flux Mixtures8Superwadeites: Elucidation of a Structural Family Related to the Wadeite Structure and Prediction of Cs2Ge5O116Sorption et transport réactif d'ions dans des monolithes de silice fonctionnalisés aux hexacyanoferrates pour le traitement d'effluents radioactifs0Sequestration of Radionuclides in Metal–Organic Frameworks from Density Functional Theory Calculations15Structural effects of calcination on Cs-exchanged copper hexacyanoferrate (Cs,K)2CuFe(CN)6 loaded on mesoporous silica particles6Implantation of low-energy Ni12+ ions to change structural and strength characteristics of ceramics based on SiC5New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]10Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 159A Solvent Free Approach for the Preparation of Silver Modified Mesoporous Silica for Iodine Entrapment6Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)23Pyrochlore glass‐ceramics fabricated via both sintering and hot isostatic pressing for minor actinide immobilization38Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)13Crystal structure of dicaesium strontium hexacyanidoferrate(II), Cs2Sr[Fe(CN)6], from laboratory X-ray powder data0Structure and stability of alkali gallates structurally reminiscent of hollandite5Expansion of the Na3MIII(Ln/An)6F30 Series: Incorporation of Plutonium into a Highly Robust and Stable Framework11Radionuclides from Nature to Nature: Recent Progress in Immobilization of High Level Nuclear Wastes in SYNROC17Exact Solutions for Investigating Thermal Response of Saturated Soil Induced by Temperature Change12Molten salt reactors and electrochemical reprocessing: synthesis and chemical durability of potential waste forms for metal and salt waste streams42Salt-flux synthesis, crystal structure and theoretical characterization of Rb0.74Ga6.62Ti0·38O110Densification of non-radioactive porous siliceous particles loaded with cesium potassium copper hexacyanoferrate by spark plasma sintering5Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids10Expanding the Chemistry of Salt-Inclusion Materials: Utilizing the Titanyl Ion as a Structure Directing Agent for the Targeted Synthesis of Salt-Inclusion Titanium Silicates14Optimizing Strategy for Enhancing the Stability and 99TcO4– Sequestration of Poly(ionic liquids)@MOFs Composites87Spatial Engineering Direct Cooperativity between Binding Sites for Uranium Sequestration87Covalency in Actinide Compounds78A dual intensity and lifetime based fluorescence sensor for perrhenate anion18A series of Rb 4 Ln 2 (P 2 S 6 )(PS 4 ) 2 (Ln = La, Ce, Pr, Nd, Sm, Gd) rare earth thiophosphates with two distinct thiophosphate units [P V S 4 ] 3− and [P IV 2 S 6 ] 4−16Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties78Heterometallic Actinide‐Containing Photoresponsive Metal‐Organic Frameworks: Dynamic and Static Tuning of Electronic Properties11Adsorption of iodine from aqueous solutions by aminosilane-grafted mesoporous alumina79Hydrothermal Synthesis and Structural Investigation of a Crystalline Uranyl Borosilicate3Effects of the zeolite concentration on the microstructure of high internal phase emulsions stabilized by surfactant-coated zeolite particles15High performance task-specific ionic liquid in uranium extraction endowed with negatively charged effect14Mild hydrothermal synthesis of potassium uranyl phosphates with layered and framework structures2Hot isostatic pressed pyrochlore glass‐ceramics: Revealing structure insides at the reaction interface9An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145A Density-Functional Theory Structural Database for Discovery of Novel Actinide Waste Forms7An1.33T4Al8Si2 (An = Ce, Th, U, Np; T = Ni, Co): Actinide Intermetallics with Disordered Gd1+xFe4Si10–y Structure Type Grown from Metal Flux1Behavior of mesoporous silica under 2 MeV electron beam irradiation6Study of Incorporating Cesium into Copper Hexacyanoferrate by Density Functional Theory Calculations18Synthetic uranium oxide hydrate materials: Current advances and future perspectives30Synthesis of hierarchical mesoporous Ln2Ti2O7 (Ln = Y, Tb–Yb) pyrochlores and uranyl sorption properties4Current advances on titanate glass-ceramic composite materials as waste forms for actinide immobilization: A technical review84Pore polarity engineering in hydrogen-bonded organic frameworks for enhanced iodine capture36Innovative Separations Research and Development Needs for Advanced Fuel Cycles9Crystal Growth of New Germanate Framework Structures: Impact of the Presence of Square Planar Copper Species and Mixed Ge/Mn Sites on the Overall Structures of Rb2Cu3Ge5O14, Cs2Cu3Ge5O14, Cs7Cu2Ge11O27F, and [(Cs6F)(Cs3AgF)][Ge12Mn2O32]3Investigation of Rare Earth-Containing Double Phosphates of the Type A3Ln(PO4)2 (Ln = Y, La, Pr, Nd, and Sm–Lu) as Potential Nuclear Waste Forms21Crystallization of A 3 Ln(BO 3 ) 2 (A = Na, K; Ln = Lanthanide) from a Boric Acid Containing Hydroxide Melt: Synthesis and Investigation of Lanthanide Borates as Potential Nuclear Waste Forms16Effects of High Gamma Doses on the Structural Stability of Metal–Organic Frameworks54Transuranium Sulfide via the Boron Chalcogen Mixture Method and Reversible Water Uptake in the NaCuTS3 Family21LnUO 4 ‐based glass–ceramic composites as waste forms for the immobilization of lanthanide‐bearing uranium wastes7All-Inorganic Open-Framework Chalcogenides, A3Ga5S9·xH2O (A = Rb and Cs), Exhibiting Ultrafast Uranyl Remediation and Illustrating a Novel Post-Synthetic Preparation of Open-Framework Oxychalcogenides11Rationally tailoring anion traps into electrospun nanofibers for highly efficient perrhenate/pertechnetate capture45Flux crystal growth of Ba 2 [(UO 2 ) 2 Ti 2 O 8 ]: Structures, spectroscopies and implications4Effect of charge and anisotropic diffusivity on ion exchange kinetics in nuclear waste form materials6Nanopockets with a Thermoresponsive Nitrate Ionic Liquid for Highly Efficient Uranium Extraction at High Acidity9Alpha-particle irradiation effects of Nd-doped Y3Fe5O12 ceramics6f‐block MOFs: A Pathway to Heterometallic Transuranics29f‐block MOFs: A Pathway to Heterometallic Transuranics1Binding of Radionuclides and Surrogate to 18-Crown-6 Ether by Density Functional Theory1Synthesis of hierarchical mesoporous cerium titanate brannerite and uranyl adsorption properties at pH 3.85Selective Crystallization of a Highly Radiation-Resistant Isonicotinic Acid-Based Metal–Organic Framework as a Primary Actinide Waste Form23Two-step synthesis of a macroporous LTA zeolite sorbent by supercritical CO2 coating and hydrothermal conversion: Implementation in fixed-bed nuclear wastewater treatment7Design and Application of Materials for Sequestration and Immobilization of 99Tc31Regulating defected zirconium metal–organic frameworks in ionic liquid for sewage treatment14Flux Crystal Growth of the Extended Structure Pu(V) Borate Na2(PuO2)(BO3)11A review of brannerite structured materials for nuclear waste management24Uranium(IV) and Thorium(IV) Coordination Polymers Based on Tritopic Carboxylic Acids2Role of BaTiO3 crystal surfaces on the electronic properties, charge separation and visible light–response of the most active (001) surface of LaAlO3: A hybrid density functional study6Three-Dimensional Structural Modelling and Characterization of Sodalite Material Network concerning the Irregularity Topological Indices26A multiparametric study on the behavior of mesoporous silica under electron irradiation2Exploring the influence of lanthanides on the structure and thermodynamic stability of SrLnTh(PO4)3 (Ln = La, Nd, Sm, Eu, and Gd)2Rb2Ln[Si2O6]F (Ln = Y, Eu–Lu): Flux Synthesis, Structure Determination, and DFT-Calculated Formation Enthalpies of a Series of Mixed-Anion Rare Earth Cyclosilicates2Predictive Phase Stability of Actinide-Bearing Hollandite Waste Forms from First-Principles Calculations2Exploring the Valence Diversity of Uranium by Flux Growth of Uranium Silicate under Inert Atmosphere6Volumetric lattice Boltzmann method for pore-scale mass diffusion-advection process in geopolymer porous structures7Phase field-volumetric lattice Boltzmann model of ion uptake in porous nuclear waste form materials under continuous flow2Unraveling the role of coordinated water in the capture of americium and toxic gases by an ultrastable uranyl phosphonate framework12Exploring Phase Transition and Structural Complexity in the Mixed Cation Uranium Oxide CaUNb2O82Flux Synthesis of Alkaline-Earth Lanthanide Borates as Potential Nuclear Waste Forms2Improvement of Single-Crystal Structures of Very Heavy Element Compounds by Refining Anomalous Dispersion Parameters3Molten Flux Synthesis of Plutonium (IV) Silicates K2PuSi2O7 and Rb2PuSi6O151Insight into γ-Irradiation-Induced Structure Evolution of Uranium(IV) Germanates as Crystalline Nuclear Waste Forms2Investigation of Magnesium-Potassium Phosphates as Potential Nuclear Waste Form for the Immobilization of Minor Actinides3Uranyl (VI) complexes from hydrazone based Schiff bases derived from the condensation of benzene-1,3-di- or benzene-1,3,5-tricarbohydrazide and hydroxyaromatic aldehydes1Energetics and kinetics of alkali ion exchange in analcime0Ionothermal Synthesis of Am 4 B 22 O 42 Cl 12 : A Chiral Cubic Americium Borate Cluster2A low-temperature, one-step synthesis for monazite can transform monazite into a readily usable advanced nuclear waste form17Mild Hydrothermal Crystal Growth of Two Luminescing Uranyl Phosphates Exhibiting an Autunite-Type Sheet Structure3Synthesis and characterization of rhenium chalcogenides for nuclear waste management1Investigation of Americium-Containing Phosphates, Silicates, Borates, Molybdates, and Fluorides Synthesized via High-Temperature Flux Crystal Growth6Electronic Structure, Covalency, and Magnetic Anisotropy in [AnCp3] (where An = Th‐Cf) Complexes: Insights from First Principle Calculations1Investigation of Bimetallic Am(III) and Nd(III) Tetrazolate Complexes Under Ambient and High-Pressure Conditions0Impact of Oxygen Vacancies on Structural Stability and Cs Immobilization in Titanate Hollandite0Mild Hydrothermal Synthesis, Crystal Structure, and Spectroscopic Analysis of a Highly Luminescent Uranyl Sulfate, K(UO 2 )SO 4 F1Impact of FePO4 on the sintering behavior of Th-monazite ceramics: Phase evolution and properties0Complexation Behavior of Uranyl Ion With Amide Functionalized Ionic Liquids: Synthesis, Complexation, and Spectroscopic Study0

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  1. Breaking a Paradigm: Observation of Magnetic Order in the Purple U(IV) Phosphite: U(HPO3)2

    Inorganic Chemistry · 2018-07-31

    Justin B. Felder, Mark D. Smith, Hans‐Conrad zur Loye

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  2. Complex Topologies from Simple Building Blocks: Uranium(IV) Thiophosphates

    Inorganic Chemistry · 2018-08-16

    Vladislav V. Klepov, Hans‐Conrad zur Loye

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  3. Versatile Uranyl Germanate Framework Hosting 12 Different Alkali Halide 1D Salt Inclusions

    Inorganic Chemistry · 2018-09-05

    Christian A. Juillerat, Emily E. Moore, Gregory W. Morrison, Mark D. Smith, Theodore M. Besmann, Hans‐Conrad zur Loye

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  4. High-Pressure Synthesis, Structural, and Spectroscopic Studies of the Ni–U–O System

    Inorganic Chemistry · 2018-10-24

    Gabriel L. Murphy, Philip Kegler, Yingjie Zhang, Zhaoming Zhang, Evgeny V. Alekseev, Martin D. de Jonge, Brendan J. Kennedy

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  5. Flux crystal growth, structure, magnetic and optical properties of a family of alkali uranium(IV) phosphates

    Journal of Solid State Chemistry · 2018-10-26

    Mohammad Usman, Gregory W. Morrison, Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  6. An Ultrafast Molecular‐Rotor‐Based Fluorescent Turn‐On Sensor for the Perrhenate Anion in Aqueous Solution

    Chemistry - A European Journal · 2018-11-23

    Akshat M. Desai, Prabhat Kumar Singh

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  7. Selective separation and preconcentration of Th( iv ) using organo-functionalized, hierarchically porous silica monoliths

    Journal of Materials Chemistry A · 2018-11-26

    Yimu Hu, Simon Giret, Rafael Meinusch, Jongho Han, Frédéric‐Georges Fontaine, Freddy Kleitz, Dominic Larivière

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  8. Overstepping Löwenstein’s Rule—A Route to Unique Aluminophosphate Frameworks with Three-Dimensional Salt-Inclusion and Ion-Exchange Properties

    Inorganic Chemistry · 2018-12-07

    Vladislav V. Klepov, Christian A. Juillerat, Evgeny V. Alekseev, Hans‐Conrad zur Loye

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  9. A physics-based mesoscale phase-field model for predicting the uptake kinetics of radionuclides in hierarchical nuclear wasteform materials

    Computational Materials Science · 2018-12-10

    Yulan Li, B.D. Zeidman, Shenyang Hu, Charles H. Henager, Theodore M. Besmann, Agnès Grandjean

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  10. Understanding the Polymorphism of A4[(UO2)3(PO4)2O2] (A = Alkali Metals) Uranyl Phosphate Framework Structures

    Crystal Growth & Design · 2018-12-13

    Vancho Kocevski, Christian A. Juillerat, Emily E. Moore, Hans‐Conrad zur Loye, Theodore M. Besmann

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  11. Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family

    Crystal Growth & Design · 2018-12-18

    Christian A. Juillerat, Hans‐Conrad zur Loye

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  12. NanMTh6F30: A Large Family of Quaternary Thorium Fluorides

    Crystal Growth & Design · 2018-12-31

    Vladislav V. Klepov, Gregory W. Morrison, Hans‐Conrad zur Loye

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  13. Flux crystal growth of uranium( v ) containing oxyfluoride perovskites

    Inorganic Chemistry Frontiers · 2019-01-01

    Christian A. Juillerat, Vancho Kocevski, Gregory W. Morrison, S. Karakalos, Deepak Patil, Scott T. Misture, Theodore M. Besmann, Hans‐Conrad zur Loye

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  14. Flux crystal growth: a versatile technique to reveal the crystal chemistry of complex uranium oxides

    Dalton Transactions · 2019-01-01

    Christian A. Juillerat, Vladislav V. Klepov, Gregory W. Morrison, Kristen A. Pace, Hans‐Conrad zur Loye

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  15. 3d-Metal Induced Magnetic Ordering on U(IV) Atoms as a Route toward U(IV) Magnetic Materials

    Journal of the American Chemical Society · 2019-02-13

    Vladislav V. Klepov, Kristen A. Pace, Stuart Calder, Justin B. Felder, Hans‐Conrad zur Loye

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  16. Removing Cs within a continuous flow set-up by an ionic exchanger material transformable into a final waste form

    Adsorption · 2019-03-01

    Clément Cabaud, Yves Barrè, Laurent de Windt, Simerjeet K. Gill, E. Dooryhée, Mícheál P. Moloney, Nicolas Massoni, Agnès Grandjean

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  17. Opportunities of Porous Organic Polymers for Radionuclide Sequestration

    Trends in Chemistry · 2019-03-06

    Qi Sun, Briana Aguila, Shengqian Ma

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  18. Sorption of Eu(III) on MXene-derived titanate structures: The effect of nano-confined space

    Chemical Engineering Journal · 2019-04-01

    Peng Zhang, Lin Wang, Li‐Yong Yuan, Jian‐Hui Lan, Zhifang Chai, Wei‐Qun Shi

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  19. Optimizing radionuclide sequestration in anion nanotraps with record pertechnetate sorption

    Nature Communications · 2019-04-09

    Qi Sun, Lin Hong Zhu, Briana Aguila, Praveen K. Thallapally, Chao Xu, Jing Chen, Shuao Wang, David O. Williams Rogers, Shengqian Ma

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  20. A Thorium Metal‐Organic Framework with Outstanding Thermal and Chemical Stability

    Chemistry - A European Journal · 2019-04-10

    Korey Prescott Carter, J. August Ridenour, Mark Kalaj, Christopher L. Cahill

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  21. Nanocrystals FAU-X monoliths as highly efficient microreactors for cesium capture in continuous flow

    Microporous and Mesoporous Materials · 2019-05-09

    Youcef Didi, Bilel Said, Matthieu Micolle, Thomas Cacciaguerra, Didier Cot, Amine Geneste, François Fajula, Anne Galarneau

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  22. Targeted Synthesis of Uranium(IV) Thiosilicates

    Inorganic Chemistry · 2019-06-10

    Vladislav V. Klepov, Mark D. Smith, Hans‐Conrad zur Loye

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  23. Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-Containing Metal–Organic Frameworks with “Structural Memory”

    Journal of the American Chemical Society · 2019-06-20

    Otega A. Ejegbavwo, Corey R. Martin, Oyindamola A. Olorunfemi, Gabrielle A. Leith, Richard T. Ly, Allison M. Rice, Ekaterina A. Dolgopolova, Mark D. Smith, S. Karakalos, Nancy R. Birkner, Brian A. Powell, Shubham Pandey, Robert J. Koch, Scott T. Misture, Hans‐Conrad zur Loye, Simon Robert Phillpot, Kyle S. Brinkman, Natalia B. Shustova

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  24. Heterometallic Metal–Organic Frameworks (MOFs): The Advent of Improving the Energy Landscape

    ACS Energy Letters · 2019-07-05

    Allison M. Rice, Gabrielle A. Leith, Otega A. Ejegbavwo, Ekaterina A. Dolgopolova, Natalia B. Shustova

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  25. Linking the multiscale porous structure of hexacyanoferrate-loaded silica monoliths to their hydrodynamic and cesium sorption properties

    Separation and Purification Technology · 2019-07-08

    Clément Cabaud, Yves Barrè, Laurent de Windt, Agnès Grandjean

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  26. Observation of the Same New Sheet Topology in Both the Layered Uranyl Oxide-Phosphate Cs11[(UO2)12(PO4)3O13] and the Layered Uranyl Oxyfluoride-Phosphate Rb11[(UO2)12(PO4)3O12F2] Prepared by Flux Crystal Growth

    Frontiers in Chemistry · 2019-08-21

    Christian A. Juillerat, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  27. U1.33T4Al8Si2 (T = Ni, Co): Complex Uranium Silicides Grown from Aluminum/Gallium Flux Mixtures

    Inorganic Chemistry · 2019-08-27

    A. Jayasinghe, You Lai, Ryan Baumbach, Susan E. Latturner

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  28. Superwadeites: Elucidation of a Structural Family Related to the Wadeite Structure and Prediction of Cs2Ge5O11

    Crystal Growth & Design · 2019-09-11

    Gregory W. Morrison, Vancho Kocevski, Scott T. Misture, Nicholas R. Spagnuolo, Adrian T. Hines, Theodore M. Besmann, Hans‐Conrad zur Loye

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  29. Sorption et transport réactif d'ions dans des monolithes de silice fonctionnalisés aux hexacyanoferrates pour le traitement d'effluents radioactifs

    Unknown journal · 2019-09-26

    Clément Cabaud

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  30. Sequestration of Radionuclides in Metal–Organic Frameworks from Density Functional Theory Calculations

    The Journal of Physical Chemistry C · 2019-10-14

    Shubham Pandey, Zhilin Jia, Brian J. Demaske, Otega A. Ejegbavwo, Wahyu Setyawan, Charles H. Henager, Natalia B. Shustova, Simon Robert Phillpot

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  31. Structural effects of calcination on Cs-exchanged copper hexacyanoferrate (Cs,K)2CuFe(CN)6 loaded on mesoporous silica particles

    Journal of Nuclear Materials · 2019-11-09

    Nicolas Massoni, Robert J. Koch, Audrey Hertz, Lionel Campayo, Mícheál P. Moloney, Scott T. Misture, Agnès Grandjean

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  32. Implantation of low-energy Ni12+ ions to change structural and strength characteristics of ceramics based on SiC

    Journal of Materials Science Materials in Electronics · 2019-12-19

    K. Tinishbaeva, Kayrat Kamalovich Kadyrzhanov, Artem Leonidovich Kozlovskiy, В.В. Углов, Maxim Vladimirovich Zdorovets

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  33. New germanate and mixed cobalt germanate salt inclusion materials: [(Rb 6 F)(Rb 4 F)][Ge 14 O 32 ] and [(Rb 6 F)(Rb 3.1 Co 0.9 F 0.96 )][Co 3.8 Ge 10.2 O 30 F 2 ]

    CrystEngComm · 2020-01-01

    Darren Carone, Mohammad Usman, Vladislav V. Klepov, Mark D. Smith, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  34. Targeting complex plutonium oxides by combining crystal chemical reasoning with density-functional theory calculations: the quaternary plutonium oxide Cs 2 PuSi 6 O 15

    Chemical Communications · 2020-01-01

    Kristen A. Pace, Vladislav V. Klepov, Matthew S. Christian, Gregory W. Morrison, Travis K. Deason, Ceren Kütahyalı Aslani, Theodore M. Besmann, David P. DiPrete, Jake Amoroso, Hans‐Conrad zur Loye

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  35. A Solvent Free Approach for the Preparation of Silver Modified Mesoporous Silica for Iodine Entrapment

    Journal of Inorganic and Organometallic Polymers and Materials · 2020-01-18

    Mícheál P. Moloney, Nicolas Massoni, Shani Egodawatte, Hans‐Conrad zur Loye, Agnès Grandjean

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  36. Nearly Identical but Not Isotypic: Influence of Lanthanide Contraction on Cs2NaLn(PS4)2 (Ln = La–Nd, Sm, and Gd–Ho)

    Inorganic Chemistry · 2020-01-22

    Vladislav V. Klepov, Kristen A. Pace, Logan S. Breton, Vancho Kocevski, Theodore M. Besmann, Hans‐Conrad zur Loye

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  37. Pyrochlore glass‐ceramics fabricated via both sintering and hot isostatic pressing for minor actinide immobilization

    Journal of the American Ceramic Society · 2020-03-19

    Yingjie Zhang, Zhaoming Zhang, Tao Wei, Linggen Kong, Young Jin Kim, Daniel J. Gregg

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  38. Crystal Growth of Alkali Uranyl Borates from Molten Salt Fluxes: Characterization and Ion Exchange Behavior of A2(UO2)B2O5 (A = Cs, Rb, K)

    Inorganic Chemistry · 2020-04-10

    Kristen A. Pace, Robert J. Koch, Mark D. Smith, Gregory W. Morrison, Vladislav V. Klepov, Theodore M. Besmann, Scott T. Misture, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  39. Crystal structure of dicaesium strontium hexacyanidoferrate(II), Cs2Sr[Fe(CN)6], from laboratory X-ray powder data

    Acta Crystallographica Section E Crystallographic Communications · 2020-05-22

    Nicolas Massoni, Mícheál P. Moloney, Agnès Grandjean, Scott T. Misture, Hans‐Conrad zur Loye

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  40. Structure and stability of alkali gallates structurally reminiscent of hollandite

    Journal of the American Ceramic Society · 2020-06-22

    Christian A. Juillerat, Vancho Kocevski, Vladislav V. Klepov, Jake Amoroso, Theodore M. Besmann, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  41. Expansion of the Na3MIII(Ln/An)6F30 Series: Incorporation of Plutonium into a Highly Robust and Stable Framework

    Chemistry - A European Journal · 2020-07-10

    Kristen A. Pace, Vladislav V. Klepov, Travis K. Deason, Mark D. Smith, Gyanendra B. Ayer, David P. DiPrete, Jake Amoroso, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  42. Radionuclides from Nature to Nature: Recent Progress in Immobilization of High Level Nuclear Wastes in SYNROC

    Journal of Inorganic Materials · 2020-07-14

    Tao Duan, Yi Ding, Shilin Luo, ZHANG Shengtai, Jian Liu

    Read original paper ↗ ·

  43. Exact Solutions for Investigating Thermal Response of Saturated Soil Induced by Temperature Change

    International Journal of Geomechanics · 2020-07-31

    Jiajun Niu, Xiukai Wang, Shilin Gong, Daosheng Ling

    Read original paper ↗ ·

  44. Molten salt reactors and electrochemical reprocessing: synthesis and chemical durability of potential waste forms for metal and salt waste streams

    International Materials Reviews · 2020-08-10

    Krista L. Carlson, Levi Gardner, Jeremy T. Moon, Brian Joseph Riley, Jake Amoroso, Dev Chidambaram

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  47. Flux Growth of Uranyl Titanates: Rare Examples of TiO4 Tetrahedra and TiO5 Square Bipyramids

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  49. Optimizing Strategy for Enhancing the Stability and 99TcO4– Sequestration of Poly(ionic liquids)@MOFs Composites

    ACS Central Science · 2020-11-30

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  50. Spatial Engineering Direct Cooperativity between Binding Sites for Uranium Sequestration

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