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RESEARCH PAPER · Chemical Science · 2021

[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitution

Q. Huang, Chun‐Li Hu, Bing‐Ping Yang, Zhi Gang Fang, Yuan Hua Lin, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

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[GaF(H 2 O)][IO 3 F]: a promising NLO material obtained by anisotropic polycation substitutionOriginalBa 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond7CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions22Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate24From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement26HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups36Explorations of New SHG Materials in Mercury Iodate Sulfate System**9General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates15NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps12Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response44A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups19MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains16ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps22High-Tc Quadratic Nonlinear Optical and Dielectric Switchings in Fe-Based Plastic Crystalline Ferroelectric20M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates26[M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology202-Chloroethylamine·trifluoromethanesulfonate combined with 18-crown-6: a ferroelectric with excellent dielectric switching properties10Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response4Recent advances in F-containing iodate nonlinear optical materials6K2(H2O)WO3F2: A new nonlinear optical material with remarkable second-harmonic generation response and enhanced laser damage threshold9CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination8A review on the advancements in the characterization of the high-pressure properties of iodates44A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions15A survey of stereoactive oxysalts for linear and nonlinear optical applications40LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution20Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence6NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy8Fluorination strategy toward chemical and functional modification65Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain2From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates13Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies10From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity11Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy5SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap8Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)4Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy4Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions1Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials0From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap1From [C(NH2)3]2[Sn2(C2O4)3]·2H2O to [C(NH2)3]4[Sn(C2O4)2]2·H2O: Uneven-substitution-activated polar stannous oxalate with balanced bandgap and birefringence0A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics0Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration0Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration0

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42 direct citing papers saved.

  1. Ba 2 [WO 3 F(IO 3 )][WO 3 F 2 ]: the first polar fluorinated tungsten iodate featuring a direct W–O–I bond

    Dalton Transactions · 2022-01-01

    Ying Hou, Hongyi Li, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

    Read original paper ↗ ·

  2. CaCe(IO 3 ) 3 (IO 3 F)F: a promising nonlinear optical material containing both IO 3 − and IO 3 F 2− anions

    Inorganic Chemistry Frontiers · 2022-01-01

    Nan Ma, Chun‐Li Hu, Jin Chen, Zhi Gang Fang, Yu Huang, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  3. Cs 2 VOF 4 (IO 2 F 2 ): Rationally designing a noncentrosymmetric early-transition-metal fluoroiodate

    Journal of Materials Chemistry C · 2022-01-01

    Mengmeng Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  4. From Pb(H 2 C 3 N 3 O 3 )(OH) to Pb(H 2 C 3 N 3 O 3 )F: Homovalent Anion Substitution-Induced Band Gap Enlargement and Birefringence Enhancement

    Inorganic Chemistry · 2022-01-11

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Yilin Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  5. HgTeO2F(OH): A Nonlinear Optical Oxyfluoride Constructed of Active [TeO2F(OH)]2– Pyramids and V-Shaped [HgO2]2– Groups

    Inorganic Chemistry · 2022-01-14

    Ru‐Ling Tang, Mei Yan, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  6. Explorations of New SHG Materials in Mercury Iodate Sulfate System**

    Chemistry - A European Journal · 2022-02-14

    Yilin Li, Mengya Ji, Chun‐Li Hu, Jin Chen, Bingxuan Li, Yuan Hua Lin, Jiang‐Gao Mao

    Read original paper ↗ ·

  7. General relationship between the band-gap energy and iodine-oxygen bond distance in metal iodates

    Physical Review Materials · 2022-04-28

    Akun Liang, Robin Turnbull, Plácida Rodríguez-Hernández, Alfonso Muñoz, M. Jasmin, Lan-Ting Shi, Daniel Errandonea

    Read original paper ↗ ·

  8. NH4IO2F2 and (NH4)3(IO2F2)3·H2O: A Series of Ammonium-Containing Fluoroiodates with Wide Band Gaps

    Inorganic Chemistry · 2022-07-21

    Jianlong Huang, Fengjiao Guo, Zhiyong Guo, Jianbang Chen, Bin Dai, Feng Yu

    Read original paper ↗ ·

  9. Design of a new ultraviolet nonlinear optical material KNO3SO3NH3 exhibiting an unexpected strong second harmonic generation response

    Materials Today Physics · 2022-09-19

    Haotian Tian, Chensheng Lin, Xin Lei Zhao, Shenghao Fang, Han Li, Chao Wang, Ning Ye, Min Luo

    Read original paper ↗ ·

  10. A new birefringent material, HfF2(IO3)2, with a large birefringence and improved overall performances achieved by the integration of functional groups

    Scripta Materialia · 2022-10-10

    Yu Huang, Zhi Gang Fang, Bing‐Ping Yang, Xueying Zhang, Jiang‐Gao Mao

    Read original paper ↗ ·

  11. MIO 3 F (M = Co and Ni): Magnetic Iodate Fluorides with Zigzag Chains

    Inorganic Chemistry · 2022-10-26

    Hang Liu, Yanhong Wang, Ya-Dong Zhou, Shuang Li, Yaling Dou, Tao Wang, Hongcheng Lu

    Read original paper ↗ ·

  12. ZrF2(IO3)2 and RbGaF3(IO3): Two Promising Birefringent Crystals Featuring 1D Metal-Fluoride Cationic Chains and Wide Bandgaps

    Inorganic Chemistry · 2022-10-26

    Jin Chen, Ke‐Zhao Du

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  13. High-Tc Quadratic Nonlinear Optical and Dielectric Switchings in Fe-Based Plastic Crystalline Ferroelectric

    Inorganic Chemistry · 2022-12-02

    Ting‐Ting Ying, Yu‐Hui Tan, Yun‐Zhi Tang, Xiao‐Wei Fan, Fangxin Wang, Ming‐Yang Wan, Juan Liao, Yan‐Le Huang

    Read original paper ↗ ·

  14. M(NH2SO3)2·xH2O (M = Ca, Pb, x = 0, 1, 4): Effect of Hydrogen Bonding on Structural Transformations and Second Harmonic Generation of Metal Sulfamates

    Inorganic Chemistry · 2022-12-12

    Danyang Dou, Bingjie Cai, Bingbing Zhang, Ying Wang

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  15. [M(OH) 2 ] 3 (IO 3 )(SeO 4 )·H 2 O (M = Ga and In): metal iodate–selenate nonlinear optical materials with a hexagonal tungsten oxide-type topology

    Inorganic Chemistry Frontiers · 2023-01-01

    Qianqian Chen, Chun‐Li Hu, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  16. 2-Chloroethylamine·trifluoromethanesulfonate combined with 18-crown-6: a ferroelectric with excellent dielectric switching properties

    Dalton Transactions · 2023-01-01

    Ning Song, Ting‐Ting Ying, Yu‐Hui Tan, Yun‐Zhi Tang, Juan Liao, Lijuan Wang, Fang-Xin Wang, Ming‐Yang Wan

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  17. Ga(IO 3 ) 3 : a mid-IR nonlinear optical iodate with balanced performance between band gap and second harmonic generation response

    Journal of Materials Chemistry C · 2023-01-01

    Dandan Wang, Xinyuan Zhang, Pifu Gong, Zheshuai Lin, Zhanggui Hu, Yicheng Wu

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  18. Recent advances in F-containing iodate nonlinear optical materials

    Chinese Journal of Structural Chemistry · 2023-01-01

    Dong Gao, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  19. K2(H2O)WO3F2: A new nonlinear optical material with remarkable second-harmonic generation response and enhanced laser damage threshold

    Journal of Alloys and Compounds · 2023-02-14

    Hong‐Xin Tang, Ruibiao Fu, Zuju Ma, Xintao Wu

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  20. CsHfF4(IO3): A Hafnium Iodate Exhibiting a Strong Second-Harmonic-Generation Effect and a Wide Band Gap Achieved by Mixed-Ligand Acentric Coordination

    Inorganic Chemistry · 2023-02-15

    Yu Huang, Bingxuan Li, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  21. A review on the advancements in the characterization of the high-pressure properties of iodates

    Progress in Materials Science · 2023-03-01

    Akun Liang, Robin Turnbull, Daniel Errandonea

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  22. A selenite containing unusual [Ga2F(Se2O5)4(HSeO3)2]5- clusters with the polarization ‘lighted’ by F− anions

    Materials Today Physics · 2023-06-01

    Jingru Zhang, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

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  23. A survey of stereoactive oxysalts for linear and nonlinear optical applications

    Materials Today Physics · 2023-08-12

    Pengfei Li, Jiang‐Gao Mao, Fang Kong

    Read original paper ↗ ·

  24. LiGa(IO3)4: An Excellent NLO Material with Unprecedented 2D [Ga(IO3)4]∞− Layer Synthesized by Aliovalent Substitution

    Small · 2023-09-07

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  25. Optically Anisotropic Mixed-Metal Fluoroiodate Ba2[GaF5(IO3F)] with a Wide Optical Transparent Window and a Moderate Birefringence

    Inorganic Chemistry · 2023-10-17

    Yuhang Wang, Fu-Ying Li, Dong‐Xue Jiao, Qi Wei, Li Wei, Guo‐Yu Yang

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  26. NaMoO 3 (IO 3 )(H 2 O): water molecule introduction induces strong second harmonic generation response, widened band gap and large anisotropy

    Dalton Transactions · 2023-12-06

    Yi Shui, Zhengli Liang, Zhenhua Li, Jiahao Wan, Lehui Liu, Xingxing Jiang, Zheshuai Lin, Hongming Liu

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  27. Fluorination strategy toward chemical and functional modification

    Fundamental Research · 2023-12-19

    Haotian Qiu, Shilie Pan, Miriding Mutailipu

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  28. Ba 2 Ga 2 F 6 (IO 3 )(PO 4 ): the first fluoride-containing iodate-phosphate with a 1D [Ga 2 F 6 (IO 3 )(PO 4 )] 4− helix chain

    Dalton Transactions · 2024-01-01

    Miao‐Bin Xu, Jiajia Li, Huai‐Yu Wu, Nan Ma, Ning Yu, Mo-Fan Zhuo, Jin Chen, Ke‐Zhao Du

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  29. From NaGa(IO3)3F to NaGa(IO3)2F2 and NaGa(IO3)4: The Effects of Chemical Substitution between F– Anions and IO3– Groups on the Structures and Properties of Gallium Iodates

    Inorganic Chemistry · 2024-01-01

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  30. Pb 2 Ga 3 F 6 (SeO 3 ) 2 X 3 ·2H 2 O (X = Cl, Br): two new HTO-type members exhibiting large NLO effects mediated by ionic mixing and substitution strategies

    Journal of Materials Chemistry C · 2024-01-01

    Lili Liu, Junbo Wang, Bingchen Xiao, Xunchi Li, Yaoqing Chu, Tongqing Sun, P. Shiv Halasyamani

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  31. From CaBaM2F12 to K2BaM2F12 (M = Zr, Hf): Heterovalent Cation-Substitution-Induced Symmetry Break and Nonlinear-Optical Activity

    Inorganic Chemistry · 2024-06-04

    Mei Yan, Ru‐Ling Tang, Wen‐Dong Yao, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  32. Breaking Symmetry for SHG Response: Lanthanide Acetate Crystals via Water Molecule Regulation Strategy

    Inorganic Chemistry · 2024-10-24

    Yaolong Zhu, Yong Tao, Can Yang, Yuwei Kang, Xuefei Wang, Jie Gou, Yi Xiong, Qi Wu

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  33. SbO(OH)2(IO3): The First Polar Sb5+‐Iodate with a Strong Second‐Harmonic Generation Response and a Wide Bandgap

    Small · 2024-10-27

    Mengya Ji, Yilin Li, Chun‐Li Hu, Jin Chen, Bingxuan Li, Jiang‐Gao Mao

    Read original paper ↗ ·

  34. Achieving balanced UV SHG responses, optical band gaps and birefringence in rare earth compounds Ln(IO 3 )(SO 4 )·3H 2 O (Ln = Y, Gd, Er, Ho, Dy, Eu)

    Dalton Transactions · 2025-01-01

    Shihua Ma, Lei Geng, Baozhu Zhu, Changyu Meng

    Read original paper ↗ ·

  35. Designing infrared nonlinear optical crystals, Sr 2 MgSn 2 OS 6 and Sr 2 SnGa 2 OS 6 , with hybrid anionic frameworks via a double substitution strategy

    Materials Chemistry Frontiers · 2025-01-01

    Zhen Qian, Deman Kong, Hongping Wu, Hongwei Yu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  36. Ba2CrIO3F6: a magnetic alkaline-earth chromium fluoroiodate with ferromagnetic exchange interactions

    Journal of Solid State Chemistry · 2025-12-24

    Shuaikun Li, Yanhong Wang, Haibo Li, Hang Liu, Yun Lv, Hongcheng Lu

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  37. Isovalent cation substitution strategy for enhancing nonlinear optical properties of iodate-selenate materials

    Journal of Alloys and Compounds · 2025-12-31

    Yinglei Han, Tongqing Sun, Hongde Liu, Dahuai Zheng, Shiguo Liu, Yongfa Kong, Jingjun Xu

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  38. From Ba[Sn(IO 3 ) 6 ] to Ba[Sn(IO 3 ) 4 F 2 ]: fluoride-ion-driven enhancement of birefringence and band gap

    Inorganic Chemistry Frontiers · 2026-01-01

    Xue-Ying Zhang, Peng-Fei Chen, Bing‐Ping Yang, Jiang‐Gao Mao

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  39. From [C(NH2)3]2[Sn2(C2O4)3]·2H2O to [C(NH2)3]4[Sn(C2O4)2]2·H2O: Uneven-substitution-activated polar stannous oxalate with balanced bandgap and birefringence

    Journal of Molecular Structure · 2026-01-25

    Yin-Jie Peng, Xin-Ting Zhu, P. L. Li, Zhi Fang, Meihong Duan

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  40. A Pyrazinamide–Iodic Acid Cocrystal Exhibiting Strong Second Harmonic Generation for Nonlinear Optics

    Advanced Optical Materials · 2026-08-31

    M. Duan, Chun‐Li Hu, Jiang‐Gao Mao, Bing‐Ping Yang

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  41. Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration

    Angewandte Chemie · 2026-09-11

    Ru‐Ling Tang, Bing-Wei Miao, Ling Wang, Zheng-Yu Yang, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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  42. Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration

    Angewandte Chemie International Edition · 2026-09-11

    Ru‐Ling Tang, Bing-Wei Miao, Ling Wang, Zheng-Yu Yang, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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