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RESEARCH PAPER · CrystEngComm · 2022

Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halide

Sergey N. Volkov, Dmitri O. Charkin, M. Yu. Arsent’ev, Sergey M. Aksenov, Lev S. Manelis, Maria Georgievna Krzhizhanovskaya, O. Yu. Sinel’shchikova, В. Л. Уголков, Alexey V. Povolotskiy, Vladimir Vladimirovich Shilovskikh, Andrey A. Antonov, Р. С. Бубнова

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Where the extraordinaries meet: a cascade of isosymmetrical superionic phase transitions and negative thermal expansion in a novel silver salt-inclusion borate halideOriginalAg 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity13Flux-assisted polytypism in the [Na 2 Cl]GaQ 2 heterolayered salt-inclusion chalcogenide family3The study of mineral behavior at low and high temperatures and their properties using a combination of different methods has not become routine yet1Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review16A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I9Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families17The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>0Synthesis, Characterization and Optical Properties of Two Novel Metal Borates1The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>6When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family3Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers5Crystal Chemistry of Silver Borates with Salt Inclusion Structure2Tunable negative and low thermal expansion in magnetic calcite-type Fe 1− x Cr x BO 3 ( x = 0.0, 0.14, 1.0) borates: a comprehensive in situ study1The First Silver Lead Borate, AgPb[B5O9]0On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding0

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  1. Ag 4 B 7 O 12 X (X = Cl, Br, I) Heptaborate Family: Comprehensive Crystal Chemistry, Thermal Stability Trends, Topology, and Vibrational Anharmonicity

    Inorganic Chemistry · 2022-12-21

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Lev S. Manelis, A. M. Banaru, Alexey V. Povolotskiy, Valentina A. Yukhno, M. Yu. Arsent’ev, Yevgeny E. Savchenko, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Р. С. Бубнова, Sergey M. Aksenov

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  2. Flux-assisted polytypism in the [Na 2 Cl]GaQ 2 heterolayered salt-inclusion chalcogenide family

    CrystEngComm · 2023-01-01

    Anna A. Berseneva, Vladislav V. Klepov, Hunter B. Tisdale, Hans‐Conrad zur Loye

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  3. The study of mineral behavior at low and high temperatures and their properties using a combination of different methods has not become routine yet

    Acta Crystallographica Section B Structural Science Crystal Engineering and Materials · 2023-04-12

    Sergey M. Aksenov

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  4. Gram–Charlier approach for anharmonic atomic displacements in inorganic solids: A review

    Crystallography Reviews · 2023-07-03

    Sergey N. Volkov, Dmitri O. Charkin, Vera A. Firsova, Sergey M. Aksenov, Р. С. Бубнова

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  5. A novel contribution to the M3B6O10X hexaborate family: The new silver compound Ag3B6O10Br and thermal behavior of Ag3B6O10(NO3) and Na3B6O10I

    Solid State Sciences · 2023-10-04

    Sergey N. Volkov, Dmitri O. Charkin, Vadim E. Kireev, В. Л. Уголков, Maria Georgievna Krzhizhanovskaya, Nikita Sergeyevich Tsvetov, Yulia A. Vaitieva, Sergey M. Aksenov, Р. С. Бубнова

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  6. Preparation of novel silver borates by soft hydrothermal synthesis in sealed tubes: New representatives of larderellite and veatchite families

    Solid State Sciences · 2023-12-15

    Sergey N. Volkov, Sergey M. Aksenov, Dmitri O. Charkin, A. M. Banaru, Daria A. Banaru, Yulia A. Vaitieva, Maria Georgievna Krzhizhanovskaya, N. A. Yamnova, Vadim E. Kireev, Alevtina N. Gosteva, Nikita Sergeyevich Tsvetov, Yevgeny E. Savchenko, Р. С. Бубнова

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  7. The Further Development of the Borate Nitrate Family: Synthesis and Structural Characterization of Ag4(B3o6)(No3) with Unique Isolated B9o18 Clusters, 9b:6δ3□:3(<2δ□>–)<3□>

    SSRN Electronic Journal · 2024-01-01

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Maxim Yu. Arsent apos ev, Maria Georgievna Krzhizhanovskaya, Valeriy L. Ugolkov, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  8. Synthesis, Characterization and Optical Properties of Two Novel Metal Borates

    ChemistrySelect · 2024-04-11

    Menghan Zhou, Hui Yang, Zhifen Guo, Cuixia Xu, Xiaomin Gu, Yuan Hua Lin

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  9. The further development of the borate nitrate family: Synthesis and characterization of Ag12(B9O18)(NO3)3 with unique isolated B9O18 clusters, 9B:6Δ3□:3(<2Δ□>–)<3□>

    Journal of Crystal Growth · 2024-07-31

    Sergey N. Volkov, Dmitri O. Charkin, Ivan A. Marsiy, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, M. Yu. Arsent’ev, Maria Georgievna Krzhizhanovskaya, В. Л. Уголков, Yevgeny E. Savchenko, Vadim E. Kireev, Sergey M. Aksenov, Р. С. Бубнова

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  10. When size matters: Na17B24O42I5 vs. Na3B4O7I, the iodide-bearing metal halide-deficient representative of the acentric salt inclusion Na3B4O7X family

    Inorganic Chemistry Communications · 2024-08-31

    Sergey N. Volkov, Dmitri O. Charkin, Maria Georgievna Krzhizhanovskaya, А.М. Горянский, Daria A. Banaru, Alexey V. Povolotskiy, Alevtina N. Gosteva, Sergey Yu. Stefanovich, M. Yu. Arsent’ev, В. Л. Уголков, Yevgeny E. Savchenko, Eduard V. Topalov, Sergey M. Aksenov

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  11. Expanding silver fluorooxoborate crystal chemistry: Ag 2 B 5 O 8 F with 3D double interpenetrating frameworks and Ag 3 B 5 O 8 F 2 with 2D layers

    Dalton Transactions · 2025-01-01

    Sergey N. Volkov, Xia Yang, Vadim E. Kireev, A. M. Banaru, Shujuan Han, Alevtina N. Gosteva, M. Yu. Arsent’ev, Dmitri O. Charkin, Alexey V. Povolotskiy, Yevgeny E. Savchenko, Maria Georgievna Krzhizhanovskaya, Stepan A. Vorobiev, Yulia A. Vaitieva, Sergey M. Aksenov, Fangfang Zhang

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  12. Crystal Chemistry of Silver Borates with Salt Inclusion Structure

    Crystallography Reports · 2025-04-01

    S. N. Volkov, Dmitri O. Charkin, Sergey M. Aksenov, A. M. Banaru, Yu.O. Kopylova, Р. С. Бубнова

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  13. Tunable negative and low thermal expansion in magnetic calcite-type Fe 1− x Cr x BO 3 ( x = 0.0, 0.14, 1.0) borates: a comprehensive in situ study

    Journal of Materials Chemistry C · 2026-01-01

    Y.P. Biryukov, Almaz L. Zinnatullin, A.P. Shablinskii, Yulia Sergeevna Gokhfeld, Margarita S. Avdontceva, Mikhail A. Cherosov, Natalia V. Kazak, Maria Georgievna Krzhizhanovskaya, Maxim D. Kuznetsov, Valeriy L. Ugolkov, Sergey M. Zharkov, Galina M. Zeer, Valery V. Rudenko, Р. С. Бубнова, Farit G. Vagizov, С. К. Филатов

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  14. The First Silver Lead Borate, AgPb[B5O9]

    Journal of Chemical Crystallography · 2026-07-30

    V. E. Kireev, D. O. Charkin, Yu.O. Kopylova, A. N. Gosteva, M. Yu. Arsent’ev, Kompanchenko A.A., M.G. Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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  15. On the border between layered and framework motifs: Ag2[B8O12(OH)2], a novel silver borate with corrugated open-framework layers and unusual hydrogen bonding

    Journal of Solid State Chemistry · 2026-08-05

    A. M. Banaru, Yu.A. Vaitieva, A. N. Gosteva, M. Yu. Arsent’ev, A. A. Kompanchenko, Y. E. Savchenko, Maria Georgievna Krzhizhanovskaya, S. N. Volkov, Sergey M. Aksenov

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