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RESEARCH PAPER · Angewandte Chemie · 2018

Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials

Hongwei Yu, Nathan Z. Koocher, James M. Rondinelli, P. Shiv Halasyamani

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Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) MaterialsOriginalTwo new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method6Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure87CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure432β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH3A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation14An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses224An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses42Nanostructured Borate Halides for Optical Second Harmonic Generation at Surfaces7Rational Design of the Metal‐Free KBe 2 BO 3 F 2 ⋅(KBBF) Family Member C(NH 2 ) 3 SO 3 F with Ultraviolet Optical Nonlinearity201Rational Design of the Metal‐Free KBe2BO3F2⋅(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity31CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties142CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties29Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups75Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups22Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity62KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response10Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate212Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate22Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification89Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification9Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl2Designing a novel perovskite-type KCd(NH 2 SO 3 ) 3 with deep-ultraviolet transparency and strong second-harmonic generation response2

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  1. Two new mixed metal borates with the large birefringence in borates system confirmed by a disordered crystal optical calculation method

    Journal of Alloys and Compounds · 2018-09-01

    Xueyan Zhang, Shichao Cheng, Ming Wen, Hongyi Li, Jun Zhang

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  2. Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations

    Chemistry - A European Journal · 2018-09-19

    Yanna Chen, Min Zhang, Cong Hu, Hongping Wu, Zhihua Yang, Shilie Pan

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  3. CsSbF 2 SO 4 : An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO 4 (KTP)‐type Structure

    Angewandte Chemie · 2019-02-26

    Xuehua Dong, Ling Huang, Cuifang Hu, Hongmei Zeng, Zhien Lin, Xin Wang, Kang Min Ok, Guohong Zou

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  4. CsSbF2SO4: An Excellent Ultraviolet Nonlinear Optical Sulfate with a KTiOPO4 (KTP)‐type Structure

    Angewandte Chemie International Edition · 2019-02-26

    Xuehua Dong, Ling Huang, Cuifang Hu, Hongmei Zeng, Zhien Lin, Xin Wang, Kang Min Ok, Guohong Zou

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  5. β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence

    Chemistry - A European Journal · 2019-06-18

    Shujuan Han, Chunmei Huang, Abudukadi Tudi, Shuaishuai Hu, Zhihua Yang, Shilie Pan

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  6. Structure and Properties of the Non‐Centrosymmetric Manganese(II) Borate Mn5(BO3)3OH

    European Journal of Inorganic Chemistry · 2019-08-16

    Viktoria Falkowski, Alexander Zeugner, Lkhamsuren Bayarjargal, Andreas Saxer, Michael Ruck, Hubert Huppertz

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  7. A Promising Fluorooxoborate Framework with Flexibile Capability for Diverse Cations to Enhance the Second Harmonic Generation

    Chemistry - A European Journal · 2020-01-16

    Shichao Cheng, Miriding Mutailipu, Zhihua Yang, Shilie Pan

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  8. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie International Edition · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

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  9. An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses

    Angewandte Chemie · 2020-02-14

    Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao, Zheshuai Lin, Junhua Luo, Maochun Hong

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  10. Nanostructured Borate Halides for Optical Second Harmonic Generation at Surfaces

    European Journal of Inorganic Chemistry · 2020-06-09

    Deming Tan, Benjamin Kirbus, Lukas M. Eng, Michael Ruck

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  11. Rational Design of the Metal‐Free KBe 2 BO 3 F 2 ⋅(KBBF) Family Member C(NH 2 ) 3 SO 3 F with Ultraviolet Optical Nonlinearity

    Angewandte Chemie International Edition · 2020-06-14

    Min Luo, Chensheng Lin, Donghong Lin, Ning Ye

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  12. Rational Design of the Metal‐Free KBe2BO3F2⋅(KBBF) Family Member C(NH2)3SO3F with Ultraviolet Optical Nonlinearity

    Angewandte Chemie · 2020-06-15

    Min Luo, Chensheng Lin, Donghong Lin, Ning Ye

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  13. CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties

    Angewandte Chemie International Edition · 2020-07-17

    Jinjie Zhou, Youquan Liu, Hongping Wu, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  14. CsZn2BO3X2 (X2=F2, Cl2, and FCl): A Series of Beryllium‐Free Deep‐Ultraviolet Nonlinear‐Optical Crystals with Excellent Properties

    Angewandte Chemie · 2020-07-17

    Jinjie Zhou, Youquan Liu, Hongping Wu, Hongwei Yu, Zheshuai Lin, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  15. Cs 3 Pb 2 (CH 3 COO) 2 X 5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie International Edition · 2020-10-14

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

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  16. Cs3Pb2(CH3COO)2X5 (X=I, Br): Halides with Strong Second‐Harmonic Generation Response Induced by Acetate Groups

    Angewandte Chemie · 2020-10-15

    Qirui Shui, Hong‐Xin Tang, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xintao Wu

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  17. Sb6O7(SO4)2: A Promising Ultraviolet Nonlinear Optical Material with an Enhanced Second‐Harmonic‐Generation Response Activated by SbIII Lone‐Pair Stereoactivity

    Chemistry - A European Journal · 2020-12-23

    Qi Wei, Chao He, Kui Wang, Xiao‐Fang Duan, Xing‐Tao An, Jinhua Li, Guo‐Ming Wang

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  18. KCs2[Pb2Br5(HCOO)2]: A Polar 3D Lead‐Bromide Framework Exhibiting Strong Second‐Harmonic Generation Response

    Chemistry - A European Journal · 2021-07-14

    Ziqi Zhou, Qirui Shui, Ruibiao Fu, Yuan‐Bin Fang, Zuju Ma, Xin‐Tao Wu

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  19. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie International Edition · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  20. Sn2PO4I: An Excellent Birefringent Material with Giant Optical Anisotropy in Non π‐Conjugated Phosphate

    Angewandte Chemie · 2021-09-15

    Jingyu Guo, Abudukadi Tudi, Shujuan Han, Zhihua Yang, Shilie Pan

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  21. Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification

    Angewandte Chemie International Edition · 2021-10-11

    Chao Wu, Xingxing Jiang, Lin Lin, Wenyan Dan, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  22. Strong SHG Responses in a Beryllium‐Free Deep‐UV‐Transparent Hydroxyborate via Covalent Bond Modification

    Angewandte Chemie · 2021-10-11

    Chao Wu, Xingxing Jiang, Lin Lin, Wenyan Dan, Zheshuai Lin, Zhipeng Huang, Mark Graeme Humphrey, Chi Zhang

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  23. Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl

    CrystEngComm · 2024-01-01

    Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Chen Xu, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun

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  24. Designing a novel perovskite-type KCd(NH 2 SO 3 ) 3 with deep-ultraviolet transparency and strong second-harmonic generation response

    Inorganic Chemistry Frontiers · 2025-01-01

    Yujie Fan, Li Sheng Zhong, Haotian Tian, Chensheng Lin, Lingli Wu, Tao Yan, Min Luo

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