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RESEARCH PAPER · Coordination Chemistry Reviews · 2015

Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materials

Ying Wang, Shilie Pan

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Recent development of metal borate halides: Crystal chemistry and application in second-order NLO materialsOriginalNa 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands12Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains8Evaluation of f-element borate chemistry76Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels109Deep Ultraviolet Nonlinear Optical Materials644K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure43DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals27Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation381Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation129Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates23Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates31Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications29Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units33AZn2BO3X2(A = K, Rb, NH4; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures178Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method106Recent achievements on middle and far-infrared second-order nonlinear optical materials433[Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers7Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks4A new method for the preparation of a [Sn 2 (H 2 PO 2 ) 3 ]Br SHG-active polar crystal via surfactant-induced strategy12A series of pentanary inorganic supramolecular sulfides (A 3 X)[MB 12 (MS 4 ) 3 ] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B 12 S 12 clusters54Experimental and ab initio studies of two UV nonlinear optical materials15M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers11Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds8New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 164The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances104The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges16Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters56Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 639Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F42[O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra2Birefringence of the new fluoride borates Ba2Na3[B3O6]2F and Ba7(BO3)4−F2+3 in the Na, Ba, B//O, F quaternary reciprocal system4Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold51Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts4(H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates12Growth and Optical Properties of LixNa1–xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure35Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals16Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion64Na4Ca[B4O5(OH)4]3·14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2− Cluster Units8Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes44Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials5An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units56Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F1233Na2(H2en)[B5O8(OH)]2[B3O4(OH)]2 and Na3(HCOO)[B5O8(OH)]: Two Borates Co‐Templated by Inorganic Cations and Organic Compounds20Polyborate Anions Partnered with Large Nonmetal Cations: Triborate(1–), Pentaborate(1–) and Heptaborate(2–) Salts18Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)26Synthesis and characterization of polyborates templated by cationic copper(II) complexes: Structural (XRD), spectroscopic, thermal (TGA/DSC) and magnetic properties15M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates16Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se137CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units184CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units895A new mixed alkali metal borate: LiCs[B5O8(OH)]·H2O11New Compressed Chalcopyrite-like Li2BaMIVQ4 (MIV = Ge, Sn; Q = S, Se): Promising Infrared Nonlinear Optical Materials245Synthesis, Structure, and Properties of Nonlinear Optical Crystal Na2SiF622Three Mixed-Alkaline Borates: Na2M2B20O32 (M = Rb, Cs) with Two Interpenetrating Three-Dimensional B-O Networks and Li4Cs4B40O64 with Fundamental Building Block B40O7730Transition-metal complexes with oxidoborates. Synthesis and XRD characterization of [(H3NCH2CH2NH2)Zn{κ3O,O′,O′′-B12O18(OH)6-κ1O′′′}Zn(en)(NH2CH2CH2NH3)]·8H2O (en=1,2-diaminoethane): a neutral bimetallic zwiterionic polyborate system containing the ‘isolated’ dodecaborate(6−) anion9Centrosymmetric (Hdima)2[Ge5B3O15(OH)] and Noncentrosymmetric Na4Ga3B4O12(OH): Solvothermal/Surfactant-Thermal Synthesis of Open-Framework Borogermanate and Galloborate34Divergent Structural Chemistry of Uranyl Borates Obtained from Solid State and Hydrothermal Conditions19Effect of Li and NH4 doping on the crystal perfection, second harmonic generation efficiency and laser damage threshold of potassium pentaborate crystals11A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property5Crystal Structure of Electroceramics0Preparation of large-size graphene oxide-like with hydroxyl groups and its optoelectronic properties8Experimental and theoretical studies on the NLO properties of two quaternary non-centrosymmetric chalcogenides: BaAg 2 GeS 4 and BaAg 2 SnS 468Synthesis and Study of the First Zeolitic Uranium Borate22From a Metastable Layer to a Stable Ring: A Kinetic Study for Transformation Reactions of Li2Mo3TeO12 to Polyoxometalates12RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures19Density functional theory-based study of the magnetic and optical properties of PbMO3 (M = Cr, Fe) using the modified BeckeJohnson mBJ functional26Ba 2 ZnSc(BO 3 ) 3 and Ba 4 Zn 5 Sc 2 (BO 3 ) 8 : first examples of borates in the Zn–Sc–B–O system featuring special structure configurations15Ba 3 B 10 O 17 Br 2 : a new barium borate halide with B–O layered structure4BaBOF 3 : a new aurivillius-like borate containing two types of F atoms32BaLiZn 3 (BO 3 ) 3 : a new member of the KBe 2 BO 3 F 2 family possessing dense BO 3 triangles and the smallest interlayer distance16Cation-tuned synthesis of the A 2 SO 4 ·SbF 3 (A = Na + , NH 4 + , K + , Rb + ) family with nonlinear optical properties78Four new quaternary chalcogenides A 2 Ba 7 Sn 4 Q 16 (A = Li, Na; Q = S, Se): syntheses, crystal structures determination, nonlinear optical performances investigation26Iodocuprate-containing ionic liquids as promoters for green propulsion60Photoluminescent carbon dots based on a rare 3D inorganic–organic hybrid cadmium borate crystal10Remarkable multimember-ring configurations in a new family of Na 7 M II Sb 5 S 12 (M II = Zn, Cd, Hg) exhibiting various three-dimensional tunnel structures25Structural insights into T 2 -cluster-containing chalcogenides with vertex-, edge- and face-sharing connection modes of NaQ 6 ligands: Na 3 ZnM III Q 4 (M III = In, Ga; Q = S, Se)13The first investigation of europium silicate melilite for second-order nonlinear optical application: experimental and theoretical studies29Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials191Cation‐Tuned Synthesis of Fluorooxoborates: Towards Optimal Deep‐Ultraviolet Nonlinear Optical Materials714Linking 1D Transition-Metal Coordination Polymers and Different Inorganic Boron Oxides To Construct a Series of 3D Inorganic–Organic Hybrid Borates42Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures10Crystal structure of cesium beryllophosphate, Be3Cs2P4O140Nature of the Color of Borates with “Anti-Zeolite” Structure19Effect of Element Substitution on Structural Transformation and Optical Performances in I2BaMIVQ4 (I = Li, Na, Cu, and Ag; MIV = Si, Ge, and Sn; Q = S and Se)63Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials237Pb2BO3I: A Borate Iodide with the Largest Second‐Harmonic Generation (SHG) Response in the KBe2BO3F2 (KBBF) Family of Nonlinear Optical (NLO) Materials24Synthesis, structure characterization, photoluminescence properties and TD–DFT calculations for two new borates3Recent advances in ultraviolet and deep-ultraviolet second-order nonlinear optical crystals257Deep-ultraviolet nonlinear optical materials: Development trend and innovative exploration16The role of cations in second-order nonlinear optical materials based on π-conjugated [BO 3 ] 3− groups195Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics494Polar Fluorooxoborate, NaB4O6F: A Promising Material for Ionic Conduction and Nonlinear Optics67A strategy for optical properties investigation in ABe 2 BO 3 F 2 (A=K, Rb, Cs) using finite field methods12Effect of pressure on the elastic properties and optoelectronic behavior of Zn 4 B 6 O 13 : First-principles investigation8SnI 4 ⋅(S 8 ) 2 : A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal184SnI4⋅(S8)2: A Novel Adduct‐Type Infrared Second‐Order Nonlinear Optical Crystal45NH4Be2BO3F2 and γ‐Be2BO3F: Overcoming the Layering Habit in KBe2BO3F2 for the Next‐Generation Deep‐Ultraviolet Nonlinear Optical Materials280NH4Be2BO3F2 and γ‐Be2BO3F: Overcoming the Layering Habit in KBe2BO3F2 for the Next‐Generation Deep‐Ultraviolet Nonlinear Optical Materials68Li3.366Mg0.317B2O5: The first pyroborate in the Li2O-MgO-B2O3 system1From LiB3O5 to NaRbB6O9F2: Fluorine‐Directed Evolution of Structural Chemistry33Fluorooxoborates: Ushering in a New Era of Deep Ultraviolet Nonlinear Optical Materials102Second-order nonlinear optical crystals with mixed anions250Adduct-Type IR Nonlinear-Optical Crystal SbI 3 ·(S 8 ) 3 with a Large Second-Harmonic Generation and a High Laser-Induced Damage Threshold59Mg 3 B 7 O 13 Cl: A New Quasi‐Phase Matching Crystal in the Deep‐Ultraviolet Region56Centrosymmetric (NH4)2SbCl(SO4)2 and Non-centrosymmetric (NH4)SbCl2(SO4): Synergistic Effect of Hydrogen-Bonding Interactions and Lone-Pair Cations on the Framework Structures and Macroscopic Centricities89Li2BaSc(BO3)2F and LiBa2Pb(BO3)2F with Layered Structures featuring Special Li−O/F Configurations11Synthesis and Characterization by a Single-Crystal XRD Study of [H3O]4[Cu7(NH3)2(H2O)4{B24O39(OH)12}]·13H2O: An Unusual [{(H2O)2(NH3)Cu}2{B2O3(OH)2}2Cu]2+ Trimetallic Bis(dihydroxytrioxidodiborate) Chain Supported by a [{Cu4O}{B20O32(OH)8}]6− Cluster11Synthesis, Structure, and Properties of the Non-Centrosymmeteric Compound LiNaRbB5O8(OH)23Three-Dimensional Printing of Nonlinear Optical Lenses16Cu2EuMQ4 (M = Si, Ge; Q = S, Se): Syntheses, structure study and physical properties determination26Structure–Property Relationship and Systematic Study of a Series of Terpyridine Based Nonlinear Optical Compounds: DFT Computation of Interactive Design14A Langbeinite-Type Yttrium Phosphate LiCs2Y2(PO4)336Crystal structure of sodium caesium zinc phosphate, NaCsZnP2O71Two Lanthanide Borate Chlorides LnB4O6(OH)2Cl (Ln = La, Ce) with Wide Ultraviolet Transmission Windows and Large Second-Harmonic Generation Responses25A review on the development of infrared nonlinear optical materials with triangular anionic groups38Exploration of the deep-ultraviolet nonlinear optical materials in the derivatives of KBe2BO3F27Improved photo-dechlorination at polar photocatalysts K 3 B 6 O 10 X (X = Cl, Br) by halogen atoms-modulated polarization9Li 2 Na 2 [B 12 O 19 (OH) 2 ]: a new open framework borate with a pcu-type net constructed from large cyclic dodeca-oxoboron units8Li 2 ZnGeS 4 : a promising diamond-like infrared nonlinear optical material with high laser damage threshold and outstanding second-harmonic generation response43Pb 10 O 4 (BO 3 ) 3 I 3 : a new noncentrosymmetric oxyborate iodide synthesized by the straightforward hydrothermal method6Sr[B(OH) 4 ](IO 3 ) and Li 4 Sr 5 [B 12 O 22 (OH) 4 ](IO 3 ) 2 : two unprecedented metal borate-iodates showing a subtle balance of enlarged band gap and birefringence34Structural modulation induced by M IIIA metals in Ba 3 MQ 4 X (M = Al, Ga, In; Q = S, Se; X = Cl, Br): an experimental and computational analysis7Two alkali calcium borates exhibiting second harmonic generation and deep-UV cutoff edges3BaV2O6·H2O: A nonlinear optical crystal with a large bandgap7Li2CsB7O10(OH)4: A Deep-Ultraviolet Nonlinear-Optical Mixed-Alkaline Borate Constructed by Unusual Heptaborate Anions98Abrupt Structural Transformation in Asymmetric ABPO4F (A = K, Rb, Cs)21K 6 ACaSc 2 (B 5 O 10 ) 3 (A = Li, Na, Li 0.7 Na 0.3 ): Nonlinear-Optical Materials with Short UV Cutoff Edges37Optical and Magnetic Properties of Cu-Containing Borates with “Antizeolite” Structure11Quantum chemical calculations, structural, spectral and nonlinear optical investigations of a novel crystal N,N ′-diphenylguanidinium 3,5-dichlorobenzoate24Zeolitic Open-Framework Borates with Noncentrosymmetric Structures and Nonlinear Optical Properties24Targeting the Next Generation of Deep-Ultraviolet Nonlinear Optical Materials: Expanding from Borates to Borate Fluorides to Fluorooxoborates450The Solid State Structure of [TMEDAH2][B5O6(OH)4]24The first barium lead oxychloride Ba27Pb8O8Cl54 with new isolated [Pb4O4] clusters3Rational Design and Synthesis of a Deep-Ultraviolet Nonlinear Optical Fluorinated Orthophosphate: BaZn(PO4)F16Structure–Property Correlation Studies of Potassium 4,4′-Bis(dinitromethyl)-3,3′-azofurazanate: A Noncentrosymmetric Primary Explosive14Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide188Large Second Harmonic Generation (SHG) Effect and High Laser‐Induced Damage Threshold (LIDT) Observed Coexisting in Gallium Selenide48LiGaP 2 O 7 : A Potential UV Nonlinear-Optical Crystal14KBiCl2SO4: The First Bismuth Chloride Sulfate Being Second-Order Nonlinear Optical Active44β‐CsB9O14: A Triple‐Layered Borate with Edge‐Sharing BO4 Tetrahedra Exhibiting a Short Cutoff Edge and a Large Birefringence30Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO 3 /BO 3 F Ratio in Layers99Prediction of Fluorooxoborates with Colossal Second Harmonic Generation (SHG) Coefficients and Extremely Wide Band Gaps: Towards Modulating Properties by Tuning the BO3/BO3F Ratio in Layers24Rb7SrY2(B5O10)3: A Rare-Earth Pentaborate with Moderate Second-Harmonic Response and Interesting Phase-Matching Behavior29Research and Development of Zincoborates: Crystal Growth, Structural Chemistry and Physicochemical Properties20Facile Growth of an Ultraviolet Hydroisocyanurate Crystal with Strong Nonlinearity and a Wide Phase-Matching Region from π-Conjugated (HC3N3O3)2– Groups45A Comprehensive Topological Analysis on a New Bromine-Chalcone with Potential Nonlinear Optical Properties7Cation Modulation on the Crystal Structure and Band Gap of Fluorooxoborates A3B3O3F6 (A = Alkali and Mixed Alkali Metal)17Designing excellent mid-infrared nonlinear optical materials with fluorooxo-functional group of d0 transition metal oxyfluorides63Copper(I) π-coordination compounds with allyl derivatives of disubstituted pseudothiohydantoin: synthesis, structure investigation and nonlinear optical features10The tunable luminescent property and wide band gap in three 1D hybrid templated borates containing different metallic ions and oxoboron clusters7

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  1. Na 9 Sb(Ge 2 Q 6 ) 2 (Q = S, Se): two new antimony( iii ) quaternary chalcogenides with ethane-like [Ge 2 Q 6 ] 6− ligands

    RSC Advances · 2016-01-01

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  2. Nonlinear optical response mechanism of noncentrosymmetric lead borate Pb 6 [B 4 O 7 (OH) 2 ] 3 with three crystallographically independent [B 4 O 7 (OH) 2 ] 4− chains

    RSC Advances · 2016-01-01

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  3. Evaluation of f-element borate chemistry

    Coordination Chemistry Reviews · 2016-03-19

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  4. Deep‐Ultraviolet Nonlinear Optics in a Borate Framework with 21‐Ring Channels

    Chemistry - A European Journal · 2016-06-01

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  5. Deep Ultraviolet Nonlinear Optical Materials

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  6. K5Ba10(BO3)8F: A New Potassium Barium Borate Fluoride with a Perovskite-Like Structure

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  7. DFT Based Theoretical Study about the Contributions of Fluorine to Nonlinear Optical Properties in Borate Fluoride Crystals

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  8. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

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  9. Pb2BO3Cl: A Tailor‐Made Polar Lead Borate Chloride with Very Strong Second Harmonic Generation

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  10. Influence of Synthetic Conditions on Chemistry and Structural Properties of Alkaline Earth Uranyl Borates

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    Yucheng Hao, Vladislav V. Klepov, Gabriel L. Murphy, Giuseppe Modolo, Dirk Bosbach, Thomas E. Albrecht‐Schmitt, Brendan J. Kennedy, Shuao Wang, Evgeny V. Alekseev

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  11. Effects of the Orientation of [B5O11]7– Fundamental Building Blocks on Layered Structures Based on the Pentaborates

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  12. Predicting Global Minimum in Complex Beryllium Borate System for Deep-ultraviolet Functional Optical Applications

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  13. Ba n+2 Zn n (BO 3 ) n (B 2 O 5 )F n (n = 1, 2): new members of the zincoborate fluoride series with two kinds of isolated B–O units

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  14. AZn2BO3X2(A = K, Rb, NH4; X = Cl, Br): New Members of KBBF Family Exhibiting Large SHG Response and the Enhancement of Layer Interaction by Modified Structures

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  15. Na2B6O9F2: A Fluoroborate with Short Cutoff Edge and Deep-Ultraviolet Birefringent Property Prepared by an Open High-Temperature Solution Method

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  16. Recent achievements on middle and far-infrared second-order nonlinear optical materials

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  17. [Zn(dap)3][Zn(dap)B5O8(OH)2]2: A Novel Organic–Inorganic Hybrid Chain-Like Zincoborate Made of [B5O8(OH)2]3− Clusters and [Zn(dap)]2+ Linkers

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  18. Na7[Ga2B13O24(OH)4]: A Luminescent Sodium Gallium Borate Containing Two Different Types of Oxoboron Framework Building Blocks

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  19. A new method for the preparation of a [Sn 2 (H 2 PO 2 ) 3 ]Br SHG-active polar crystal via surfactant-induced strategy

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  20. A series of pentanary inorganic supramolecular sulfides (A 3 X)[MB 12 (MS 4 ) 3 ] (A = K, Cs; X = Cl, Br, I; M = Ga, In, Gd) featuring B 12 S 12 clusters

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  22. M 3 V 2 B 10 O 23 (M = Ca, Sr): two new vanadoborates with [V 2 B 10 O 23 ] ∞ double layers

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  23. Na 6 Si 3 S 8 O: the first example of a sulfide silicate exhibiting unusual tri-polymerized [Si 3 S 8 O] 6− units without S–O bonds

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  24. New lead( ii ) borates in the PbO/PbF 2 /H 3 BO 3 ternary phase diagram: syntheses and structures of β-Pb 6 B 10 O 21 and Pb 4 B 8 O 16

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  25. The first quaternary diamond-like semiconductor with 10-membered LiS 4 rings exhibiting excellent nonlinear optical performances

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  26. The structural diversity of halogen-centered secondary building units: two new mixed-metal borate halides with deep-ultraviolet cut-off edges

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  27. Two deep-ultraviolet nonlinear optical alkaline-earth metal borates based on different types of oxoboron clusters

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  28. Two excellent phase-matchable infrared nonlinear optical materials based on 3D diamond-like frameworks: RbGaSn 2 Se 6 and RbInSn 2 Se 6

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  29. Top-Seeded Solution Crystal Growth and Linear and Nonlinear Optical Properties of Ba 4 B 11 O 20 F

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  30. [O2Pb3]2(BO3)Br: An Oxidoborate Oxide Bromide with the ∞1[O2Pb3] Double Chains Based on Edge‐sharing OPb4 Tetrahedra

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  31. Birefringence of the new fluoride borates Ba2Na3[B3O6]2F and Ba7(BO3)4−F2+3 in the Na, Ba, B//O, F quaternary reciprocal system

    Materials Research Bulletin · 2017-03-15

    Tatyana B. Bekker, Vitaliy Nikolaevich Vedenyapin, Avag Gurgenovich Khamoyan

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  32. Li3VO4: A Promising Mid-Infrared Nonlinear Optical Material with Large Laser Damage Threshold

    Crystal Growth & Design · 2017-03-30

    Zhaohui Chen, Zhizhong Zhang, Xiaoyu Dong, Yunjing Shi, Yaqin Liu, Qun Jing

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  33. Synthesis, XRD Studies and NLO Properties of [p-H2NC6H4CH2NH3][B5O6(OH)4]·1/2H2O and NLO Properties of Some Related Pentaborate(1−) Salts

    Journal of Cluster Science · 2017-04-01

    Michael A. Beckett, Simon John Coles, Peter Neil Horton, Charlotte L. Jones, Kerstin Krueger

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  34. (H 3 O)Ca 2 Zn 3.5 (PO 4 ) 4 and Ba 2 Cd 3 (PO 4 ) 2 (HPO 4 ) 2 : Syntheses, crystal structures and characterizations of two mixed metal phosphates

    Journal of Solid State Chemistry · 2017-04-08

    Tong-Ying Chang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  35. Growth and Optical Properties of LixNa1–xBa12(BO3)7F4 Fluoride Borates with “Antizeolite” Structure

    Inorganic Chemistry · 2017-04-10

    Tatyana B. Bekker, Sergey V. Rashchenko, V. P. Solntsev, Alexander Yèlisseyev, Alexander A. Kragzhda, V. V. Bakakin, Yuriy V. Seryotkin, Alexander E. Kokh, К. А. Кох, Artem B. Kuznetsov

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  36. Comparative Interrelationship of the Structural, Nonlinear-Optical and Other Acentric Properties for Oxide, Borate and Carbonate Crystals

    Crystals · 2017-04-12

    Boris I. Kidyarov

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  37. Li2HgMS4 (M = Si, Ge, Sn): New Quaternary Diamond-Like Semiconductors for Infrared Laser Frequency Conversion

    Crystals · 2017-04-12

    Kui Wu, Shilie Pan

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  38. Na4Ca[B4O5(OH)4]3·14H2O: An Acentric Supramolecular Framework Borate Based on [B4O5(OH)4]2− Cluster Units

    Journal of Cluster Science · 2017-04-20

    Chong‐An Chen, Qi Wei, Bai‐Feng Yang, Guo‐Yu Yang

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  39. Extending Unique 1D Borate Chains to 3D Frameworks by Introducing Metallic Nodes

    Chemistry - A European Journal · 2017-04-24

    Qi Wei, Shijia Sun, Jie Zhang, Guo‐Yu Yang

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  40. Two Barium Gold Iodates: Syntheses, Structures, and Properties of Polar BaAu(IO3)5 and Nonpolar HBa4Au(IO3)12 Materials

    Inorganic Chemistry · 2017-06-02

    Bing‐Ping Yang, Chun‐Li Hu, Fei‐Fei Mao, Xiang Xu, Jiang‐Gao Mao

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  41. An Ultraviolet Nonlinear Optic Borate with 13-Ring Channels Constructed from Different Building Units

    Inorganic Chemistry · 2017-06-07

    Er-Rong Wang, Jianhao Huang, Sujuan Yu, You‐Zhao Lan, Jian‐Wen Cheng, Guo‐Yu Yang

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  42. Finding the Next Deep-Ultraviolet Nonlinear Optical Material: NH4B4O6F

    Journal of the American Chemical Society · 2017-07-20

    Guoqiang Q. Shi, Ying Wang, Fangfang Zhang, Bingbing Zhang, Zhihua Yang, Xueling Hou, Shilie Pan, Kenneth Reinhard Poeppelmeier

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  43. Na2(H2en)[B5O8(OH)]2[B3O4(OH)]2 and Na3(HCOO)[B5O8(OH)]: Two Borates Co‐Templated by Inorganic Cations and Organic Compounds

    European Journal of Inorganic Chemistry · 2017-07-20

    Qi Wei, Chao He, Li Quan Sun, Xing‐Tao An, Jie Zhang, Guo‐Yu Yang

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  44. Polyborate Anions Partnered with Large Nonmetal Cations: Triborate(1–), Pentaborate(1–) and Heptaborate(2–) Salts

    European Journal of Inorganic Chemistry · 2017-07-21

    Michael A. Beckett, Simon John Coles, Peter Neil Horton, Charlotte L. Jones

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  45. Structural Insights into Borates with an Anion‐Templated Open‐Framework Configuration: Asymmetric K2BaB16O26 versus Centrosymmetric K3CsB20O32 and Na2M2NB18O30 (M=Rb, Cs; N=Ba, Pb)

    Chemistry - A European Journal · 2017-07-21

    Miriding Mutailipu, Min Zhang, Xin Su, Zhihua Yang, Yanna Chen, Shilie Pan

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  46. Synthesis and characterization of polyborates templated by cationic copper(II) complexes: Structural (XRD), spectroscopic, thermal (TGA/DSC) and magnetic properties

    Polyhedron · 2017-07-26

    Mohammed A. Altahan, Michael A. Beckett, Simon John Coles, Peter Neil Horton

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  47. M(IO3)(HPO4)(H2O) (M = Sc, Fe, Ga, In): Introduction of Phosphate Anions into Metal Iodates

    Crystal Growth & Design · 2017-08-16

    Tong-Ying Chang, Bing‐Ping Yang, Chun‐Li Hu, Dong Yan, Jiang‐Gao Mao

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  48. Synthesis and characterization of two lead-containing metal chalcogenides: Ba5Pb2Sn3S13 and Ba6PbSn3Se13

    Journal of Solid State Chemistry · 2017-08-16

    Ailijiang Abudurusuli, Hanqin Ding, Kui Wu

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  49. CsB 4 O 6 F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie · 2017-09-12

    Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  50. CsB4O6F: A Congruent‐Melting Deep‐Ultraviolet Nonlinear Optical Material by Combining Superior Functional Units

    Angewandte Chemie International Edition · 2017-09-12

    Xuefei Wang, Ying Wang, Bingbing Zhang, Fangfang Zhang, Zhihua Yang, Shilie Pan

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